In situ Stripline Electrochemical NMR for Batteries

Sorte, Eric Glenn; Banek, Nathan A.; Wagner, Michael J.; Alam, Todd M.; Tong, YuYe Jay

doi:10.1002/celc.201800434

Title: In situ Stripline Electrochemical NMR for Batteries

Journal Article · Mon Jun 11 00:00:00 EDT 2018 · ChemElectroChem

DOI:https://doi.org/10.1002/celc.201800434· OSTI ID:1444078

Sorte, Eric Glenn ^[1]; Banek, Nathan A. ^[2]; Wagner, Michael J. ^[2]; Alam, Todd M. ^[3]; Tong, YuYe Jay ^[4]

Georgetown Univ., Washington, D.C. (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
George Washington Univ., Washington, DC (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Georgetown Univ., Washington, D.C. (United States)

Abstract Some long‐outstanding technical challenges exist that continue to be of hindrance to fully harnessing the unique investigative advantages of nuclear magnetic resonance (NMR) spectroscopy in the in situ investigation of rechargeable battery chemistry. For instance, the conducting materials and circuitry necessary for an operational battery always deteriorate the coil‐based NMR sensitivity when placed inside the coil, and the shape mismatch between them leads to low sample filling factors and even higher detection limits. We report, herein, a novel and successful adaptation of stripline NMR detection that integrates seamlessly NMR detection with the construction of an electrochemical device in general, or a battery in particular, which leads to an in situ electrochemical NMR technique with much higher detection sensitivity, higher sample filling factor, and which is particularly suitable for mass‐limited samples.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1444078

Alternate ID(s):: OSTI ID: 1456287

Report Number(s):: SAND-2018-3447J; 663959; TRN: US1900966

Journal Information:: ChemElectroChem, Vol. 5, Issue 17; ISSN 2196-0216

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

Citation information provided by
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