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Title: Integrated rheology model: Explosive Composition B-3

Journal Article · · Journal of Energetic Materials

Composition B-3 (Comp B-3) is a high explosive formulation composed of 60/40wt% RDX (1,3,5-trinitroperhydro-1,3,5-triazine) /TNT (2,4,6 trinitrotoluene). Above approximately 78°C this formulation partially melts to form a multiphase system with solid RDX particles in a molten TNT matrix. This multiphase system presents a number of phenomena that influence its apparent viscosity. In an earlier study explosive Composition B-3 (Comp B-3, 60/40wt% RDX/TNT) was examined for evidence of yield stress using a non-isothermal falling ball viscometer and a yield stress model was proposed in this paper. An integrated viscosity model suitable for use in computational fluid dynamics (CFD) simulations is developed to capture the transition from a heterogeneous solid to a Bingham viscoplastic fluid. This viscosity model is used to simulate the motion of imbedded spheres falling through molten Comp B-3. Finally, comparison of the simulations to physical tests show agreement between the positions predicted by the model and the measured locations of the spheres as a function of temperature between 90C and 165C.

Research Organization:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC52-06NA25396
OSTI ID:
1441324
Report Number(s):
LA-UR-17-31436
Journal Information:
Journal of Energetic Materials, Vol. 36, Issue 4; ISSN 0737-0652
Publisher:
Taylor & FrancisCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

References (11)

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Application of the Peng–Robinson Equation of State to Energetic Materials RDX and TNT: Pure Components, Liquid Mixtures, and Solid Mixtures journal February 2016
Flows of Materials with Yield journal July 1987
Rheology of concentrated disperse systems and minimum energy dissipation principle: I. Viscosity-concentration relationship journal January 1977
Yield stress and maximum packing fraction of concentrated suspensions journal January 1995
Rheology studies of NTO–TNT based melt-cast dispersions and influence of particle–dispersant interactions journal March 2015
Molten Composition B Viscosity at Elevated Temperature journal March 2016
Viscosity and Density of the Liquid System TNT‐Picric Acid and Four Related Pure Materials journal December 1956
Non-Newtonian fluids with a yield stress journal September 2005
Measuring the Flow Properties of Yield Stress Fluids journal January 1992

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Short communication: Estimation of yield stress/viscosity of molten octol journal May 2018

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