From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media

Jiao, Long; Wan, Gang; Zhang, Rui; Zhou, Hua; Yu, Shu‐Hong; Jiang, Hai‐Long

doi:10.1002/ange.201803262

From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media

Journal Article · Tue Jun 12 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201803262· OSTI ID:1441233

Jiao, Long ^[1]; Wan, Gang ^[2]; Zhang, Rui ^[1]; Zhou, Hua ^[3]; Yu, Shu‐Hong ^[1]; ^[1]

Hefei National Laboratory for Physical Sciences at the Microscale CAS Key Laboratory of Soft Matter Chemistry Collaborative Innovation Center of Suzhou Nano Science and Technology Department of Chemistry University of Science and Technology of China Hefei Anhui 230026 P. R. China
Materials Science Division Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA, University of Chinese Academy of Sciences Beijing 100049 P. R. China, X-ray Science Division Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA
X-ray Science Division Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA

Abstract

It remains highly desired but a great challenge to achieve atomically dispersed metals in high loadings for efficient catalysis. Now porphyrinic metal–organic frameworks (MOFs) have been synthesized based on a novel mixed‐ligand strategy to afford high‐content (1.76 wt %) single‐atom (SA) iron‐implanted N‐doped porous carbon (Fe _SA ‐N‐C) via pyrolysis. Thanks to the single‐atom Fe sites, hierarchical pores, oriented mesochannels and high conductivity, the optimized Fe _SA ‐N‐C exhibits excellent oxygen reduction activity and stability, surpassing almost all non‐noble‐metal catalysts and state‐of‐the‐art Pt/C, in both alkaline and more challenging acidic media. More far‐reaching, this MOF‐based mixed‐ligand strategy opens a novel avenue to the precise fabrication of efficient single‐atom catalysts.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1441233

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 28 Vol. 130; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (52)

From Bimetallic Metal-Organic Framework to Porous Carbon: High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis Chen, Yu-Zhen; Wang, Chengming; Wu, Zhen-Yu Advanced Materials, Vol. 27, Issue 34 https://doi.org/10.1002/adma.201502315	journal	July 2015
Emerging Multifunctional Metal-Organic Framework Materials Li, Bin; Wen, Hui-Min; Cui, Yuanjing Advanced Materials, Vol. 28, Issue 40 https://doi.org/10.1002/adma.201601133	journal	July 2016
Nanoarchitectured Design of Porous Materials and Nanocomposites from Metal-Organic Frameworks Kaneti, Yusuf Valentino; Tang, Jing; Salunkhe, Rahul R. Advanced Materials, Vol. 29, Issue 12 https://doi.org/10.1002/adma.201604898	journal	December 2016
Single-Atom Catalysts: Emerging Multifunctional Materials in Heterogeneous Catalysis Zhang, Huabin; Liu, Guigao; Shi, Li Advanced Energy Materials, Vol. 8, Issue 1 https://doi.org/10.1002/aenm.201701343	journal	September 2017
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie, Vol. 124, Issue 41, p. 10453-10456 https://doi.org/10.1002/ange.201204475	journal	August 2012
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie, Vol. 128, Issue 36 https://doi.org/10.1002/ange.201604802	journal	August 2016
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction Chen, Yuanjun; Ji, Shufang; Wang, Yanggang Angewandte Chemie, Vol. 129, Issue 24 https://doi.org/10.1002/ange.201702473	journal	April 2017
Einzelatom-Elektrokatalysatoren Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong Angewandte Chemie, Vol. 129, Issue 45 https://doi.org/10.1002/ange.201703864	journal	October 2017
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204475	journal	August 2012
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604802	journal	August 2016
Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction Chen, Yuanjun; Ji, Shufang; Wang, Yanggang Angewandte Chemie International Edition, Vol. 56, Issue 24 https://doi.org/10.1002/anie.201702473	journal	April 2017
Single-Atom Electrocatalysts Zhu, Chengzhou; Fu, Shaofang; Shi, Qiurong Angewandte Chemie International Edition, Vol. 56, Issue 45 https://doi.org/10.1002/anie.201703864	journal	October 2017
Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V. Chemistry - A European Journal, Vol. 17, Issue 7 https://doi.org/10.1002/chem.201003080	journal	January 2011
Electrocatalysts Derived from Metal-Organic Frameworks for Oxygen Reduction and Evolution Reactions in Aqueous Media Qian, Yuhong; Khan, Inayat Ali; Zhao, Dan Small, Vol. 13, Issue 37 https://doi.org/10.1002/smll.201701143	journal	July 2017
Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction Gupta, S.; Tryk, D.; Bae, I. Journal of Applied Electrochemistry, Vol. 19, Issue 1, p. 19-27 https://doi.org/10.1007/BF01039385	journal	January 1989
A review of Fe–N/C and Co–N/C catalysts for the oxygen reduction reaction Bezerra, Cicero W.B.; Zhang, Lei; Lee, Kunchan Electrochimica Acta, Vol. 53, Issue 15, p. 4937-4951 https://doi.org/10.1016/j.electacta.2008.02.012	journal	June 2008
Single cobalt sites in mesoporous N-doped carbon matrix for selective catalytic hydrogenation of nitroarenes Sun, Xiaohui; Olivos-Suarez, Alma I.; Osadchii, Dmitrii Journal of Catalysis, Vol. 357 https://doi.org/10.1016/j.jcat.2017.10.030	journal	January 2018
Enhanced oxygen reduction performance by novel pyridine substituent groups of iron (II) phthalocyanine with graphene composite Cui, Lili; Lv, Guojun; He, Xingquan Journal of Power Sources, Vol. 282 https://doi.org/10.1016/j.jpowsour.2015.02.031	journal	May 2015
Surface functionalization of ZIF-8 with ammonium ferric citrate toward high exposure of Fe-N active sites for efficient oxygen and carbon dioxide electroreduction Ye, Yifan; Cai, Fan; Li, Haobo Nano Energy, Vol. 38 https://doi.org/10.1016/j.nanoen.2017.05.042	journal	August 2017
Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications Islamoglu, Timur; Goswami, Subhadip; Li, Zhanyong Accounts of Chemical Research, Vol. 50, Issue 4 https://doi.org/10.1021/acs.accounts.6b00577	journal	February 2017
Transformation of Metal–Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights Lee, Kyung Joo; Lee, Jae Hwa; Jeoung, Sungeun Accounts of Chemical Research, Vol. 50, Issue 11 https://doi.org/10.1021/acs.accounts.7b00259	journal	October 2017
Heteroatom-Doped Graphitic Carbon Catalysts for Efficient Electrocatalysis of Oxygen Reduction Reaction Zhang, Jintao; Dai, Liming ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b01563	journal	November 2015
Development of MOF-Derived Carbon-Based Nanomaterials for Efficient Catalysis Shen, Kui; Chen, Xiaodong; Chen, Junying ACS Catalysis, Vol. 6, Issue 9 https://doi.org/10.1021/acscatal.6b01222	journal	August 2016
Catalysis by Supported Single Metal Atoms Liu, Jingyue ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b01534	journal	November 2016
Metal–Organic-Framework-Derived Fe-N/C Electrocatalyst with Five-Coordinated Fe-N _x Sites for Advanced Oxygen Reduction in Acid Media Lai, Qingxue; Zheng, Lirong; Liang, Yanyu ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b02966	journal	February 2017
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks Morris, William; Volosskiy, Boris; Demir, Selcuk Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445 https://doi.org/10.1021/ic300825s	journal	June 2012
Biomimetic Catalysis of a Porous Iron-Based Metal–Metalloporphyrin Framework Chen, Yao; Hoang, Tran; Ma, Shengqian Inorganic Chemistry, Vol. 51, Issue 23 https://doi.org/10.1021/ic301923x	journal	November 2012
Metal-Organic Framework as a Template for Porous Carbon Synthesis Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki Journal of the American Chemical Society, Vol. 130, Issue 16 https://doi.org/10.1021/ja7106146	journal	April 2008
New Heterometallic Zirconium Metalloporphyrin Frameworks and Their Heteroatom-Activated High-Surface-Area Carbon Derivatives Lin, Qipu; Bu, Xianhui; Kong, Aiguo Journal of the American Chemical Society, Vol. 137, Issue 6 https://doi.org/10.1021/jacs.5b00076	journal	February 2015
In Situ Coupling of Strung Co ₄ N and Intertwined N–C Fibers toward Free-Standing Bifunctional Cathode for Robust, Efficient, and Flexible Zn–Air Batteries Meng, Fanlu; Zhong, Haixia; Bao, Di Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05046	journal	August 2016
A General Approach to Preferential Formation of Active Fe–N _x Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction Sa, Young Jin; Seo, Dong-Jun; Woo, Jinwoo Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b09470	journal	November 2016
Molecule-Level g-C ₃ N ₄ Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions Zheng, Yao; Jiao, Yan; Zhu, Yihan Journal of the American Chemical Society, Vol. 139, Issue 9 https://doi.org/10.1021/jacs.6b13100	journal	February 2017
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu Journal of the American Chemical Society, Vol. 139, Issue 40 https://doi.org/10.1021/jacs.7b06514	journal	September 2017
N-doped carbon nanotubes containing a high concentration of single iron atoms for efficient oxygen reduction Li, Jin-Cheng; Yang, Zhi-Qing; Tang, Dai-Ming NPG Asia Materials, Vol. 10, Issue 1 https://doi.org/10.1038/am.2017.212	journal	January 2018
Metal–organic frameworks as selectivity regulators for hydrogenation reactions Zhao, Meiting; Yuan, Kuo; Wang, Yun Nature, Vol. 539, Issue 7627 https://doi.org/10.1038/nature19763	journal	October 2016
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis Fan, Lili; Liu, Peng Fei; Yan, Xuecheng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10667	journal	February 2016
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms16100	journal	July 2017
Hierarchically porous carbons with optimized nitrogen doping as highly active electrocatalysts for oxygen reduction Liang, Hai-Wei; Zhuang, Xiaodong; Brüller, Sebastian Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5973	journal	September 2014
Atomic cobalt on nitrogen-doped graphene for hydrogen generation Fei, Huilong; Dong, Juncai; Arellano-Jiménez, M. Josefina Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9668	journal	October 2015
A metal–organic framework-derived bifunctional oxygen electrocatalyst Xia, Bao Yu; Yan, Ya; Li, Nan Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.6	journal	January 2016
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Metal–Organic Frameworks (MOFs) Zhou, Hong-Cai “Joe”; Kitagawa, Susumu Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS90059F	journal	January 2014
A metal–organic framework route to in situ encapsulation of Co@Co ₃ O ₄ @C core@bishell nanoparticles into a highly ordered porous carbon matrix for oxygen reduction Xia, Wei; Zou, Ruqiang; An, Li Energy & Environmental Science, Vol. 8, Issue 2 https://doi.org/10.1039/C4EE02281E	journal	January 2015
Towards high-efficiency nanoelectrocatalysts for oxygen reduction through engineering advanced carbon nanomaterials Zhou, Ming; Wang, Hsing-Lin; Guo, Shaojun Chemical Society Reviews, Vol. 45, Issue 5 https://doi.org/10.1039/C5CS00414D	journal	January 2016
Metal–organic framework-based CoP/reduced graphene oxide: high-performance bifunctional electrocatalyst for overall water splitting Jiao, Long; Zhou, Yu-Xiao; Jiang, Hai-Long Chemical Science, Vol. 7, Issue 3 https://doi.org/10.1039/C5SC04425A	journal	January 2016
Construction of a cobalt-embedded nitrogen-doped carbon material with the desired porosity derived from the confined growth of MOFs within graphene aerogels as a superior catalyst towards HER and ORR Zhu, Zhen; Yang, Yan; Guan, Yue Journal of Materials Chemistry A, Vol. 4, Issue 40 https://doi.org/10.1039/C6TA05196K	journal	January 2016
Out-of-plane Fe ^II –N ₄ moiety modified Fe–N co-doped porous carbons as high-performance electrocatalysts for the oxygen reduction reaction Qian, Zhongjie; Hu, Zhaowen; Zhang, Zhengping Catalysis Science & Technology, Vol. 7, Issue 18 https://doi.org/10.1039/C7CY01290J	journal	January 2017
Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges Wu, Hao Bin; Lou, Xiong Wen (David) Science Advances, Vol. 3, Issue 12 https://doi.org/10.1126/sciadv.aap9252	journal	December 2017
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric Science, Vol. 324, Issue 5923, p. 71-74 https://doi.org/10.1126/science.1170051	journal	April 2009
Photochemical route for synthesizing atomically dispersed palladium catalysts Liu, P.; Zhao, Y.; Qin, R. Science, Vol. 352, Issue 6287 https://doi.org/10.1126/science.aaf5251	journal	May 2016

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