Organic non-aqueous cation-based redox flow batteries

Zhang, Lu; Huang, Jinhua; Burrell, Anthony

Organic non-aqueous cation-based redox flow batteries

Patent · Tue May 08 04:00:00 EDT 2018

OSTI ID:1440539

Zhang, Lu; Huang, Jinhua; Burrell, Anthony

The present invention provides a non-aqueous redox flow battery comprising a negative electrode immersed in a non-aqueous liquid negative electrolyte, a positive electrode immersed in a non-aqueous liquid positive electrolyte, and a cation-permeable separator (e.g., a porous membrane, film, sheet, or panel) between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise an electrolyte salt (e.g., a lithium or sodium salt), a transition-metal free redox reactant, and optionally an electrochemically stable organic solvent. Each redox reactant is selected from an organic compound comprising a conjugated unsaturated moiety, a boron cluster compound, and a combination thereof. The organic redox reactant of the positive electrolyte comprises a tetrafluorohydroquinone ether compound or a tetrafluorocatechol ether compound.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UChicago Argonne, LLC (Argonne, IL)

Patent Number(s):: 9,966,625

Application Number:: 14/476,202

OSTI ID:: 1440539

Country of Publication:: United States

Language:: English

References (30)

Redox shuttles for safer lithium-ion batteries Chen, Zonghai; Qin, Yan; Amine, Khalil Electrochimica Acta, Vol. 54, Issue 24, p. 5605-5613 https://doi.org/10.1016/j.electacta.2009.05.017	journal	October 2009
Electrochemical Properties of an All-Organic Redox Flow Battery Using 2,2,6,6-Tetramethyl-1-Piperidinyloxy and N-Methylphthalimide Li, Zhen; Li, Sha; Liu, Suqin Electrochemical and Solid-State Letters, Vol. 14, Issue 12, p. A171-A173 https://doi.org/10.1149/2.012112esl	journal	January 2011
Conjugated dicarboxylate anodes for Li-ion batteries Armand, M.; Grugeon, S.; Vezin, H. Nature Materials, Vol. 8, Issue 2, p. 120-125 https://doi.org/10.1038/nmat2372	journal	January 2009
Redox flow batteries a review Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P. Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1137-1164 https://doi.org/10.1007/s10800-011-0348-2	journal	September 2011
Non-aqueous chromium acetylacetonate electrolyte for redox flow batteries Liu, Qinghua; Shinkle, Aaron A.; Li, Yongdan Electrochemistry Communications, Vol. 12, Issue 11, p. 1634-1637 https://doi.org/10.1016/j.elecom.2010.09.013	journal	November 2010
Integrating Renewable Electricity on the Grid Crabtree, George; Misewich, Jim; Ambrosio, Ron AIP Conference Proceedings, Vol. 1401, Issue 1, Article No. 387 https://doi.org/10.1063/1.3653865	journal	January 2011
Electrochemical Overcharge Protection of Rechargeable Lithium Batteries Behl, Wishvender K.; Chin, Der‐Tau Journal of The Electrochemical Society, Vol. 135, Issue 1, p. 16-21 https://doi.org/10.1149/1.2095545	journal	January 1988
Novel Quinoxaline-Based Organic Sensitizers for Dye-Sensitized Solar Cells Chang, Dong Wook; Lee, Hyo Joong; Kim, Jong H. Organic Letters, Vol. 13, Issue 15, p. 3880-3883 https://doi.org/10.1021/ol2012378	journal	August 2011
Non-aqueous manganese acetylacetonate electrolyte for redox flow batteries Sleightholme, Alice E. S.; Shinkle, Aaron A.; Liu, Qinghua Journal of Power Sources, Vol. 196, Issue 13, p. 5742-5745 https://doi.org/10.1016/j.jpowsour.2011.02.020	journal	July 2011
Non-aqueous vanadium acetylacetonate electrolyte for redox flow batteries Liu, Qinghua; Sleightholme, Alice E. S.; Shinkle, Aaron A. Electrochemistry Communications, Vol. 11, Issue 12, p. 2312-2315 https://doi.org/10.1016/j.elecom.2009.10.006	journal	December 2009
Evaluation of electrolytes for redox flow battery applications Chakrabarti, M. H.; Dryfe, R. A. W.; Roberts, E. P. L. Electrochimica Acta, Vol. 52, Issue 5, p. 2189-2195 https://doi.org/10.1016/j.electacta.2006.08.052	journal	January 2007
Electrochemical characterization of lithium 4,4′-tolane-dicarboxylate for use as a negative electrode in Li-ion batteries Walker, Wesley; Grugeon, Sylvie; Vezin, Hervé J. Mater. Chem., Vol. 21, Issue 5 https://doi.org/10.1039/C0JM03458D	journal	January 2011
Semi-Solid Lithium Rechargeable Flow Battery Duduta, Mihai; Ho, Bryan; Wood, Vanessa C. Advanced Energy Materials, Vol. 1, Issue 4, p. 511-516 https://doi.org/10.1002/aenm.201100152	journal	May 2011
An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery Brushett, Fikile R.; Vaughey, John T.; Jansen, Andrew N. Advanced Energy Materials, Vol. 2, Issue 11, p. 1390-1396 https://doi.org/10.1002/aenm.201200322	journal	June 2012
Ethoxycarbonyl-Based Organic Electrode for Li-Batteries Walker, Wesley; Grugeon, Sylvie; Mentre, Olivier Journal of the American Chemical Society, Vol. 132, Issue 18, p. 6517-6523 https://doi.org/10.1021/ja1012849	journal	May 2010
n-Butylferrocene for Overcharge Protection of Secondary Lithium Batteries Abraham, K. M.; Pasquariello, D. M.; Willstaedt, E. B. Journal of The Electrochemical Society, Vol. 137, Issue 6, p. 1856-1857 https://doi.org/10.1149/1.2086817	journal	January 1990
A new redox flow battery using Fe/V redox couples in chloride supporting electrolyte Wang, Wei; Kim, Soowhan; Chen, Baowei Energy & Environmental Science, Vol. 4, Issue 10, p. 4068-4073 https://doi.org/10.1039/C0EE00765J	journal	January 2011
Lithium Borate Cluster Salts as Redox Shuttles for Overcharge Protection of Lithium-Ion Cells Chen, Zonghai; Liu, Jun; Jansen, A. N. Electrochemical and Solid-State Letters, Vol. 13, Issue 4, p. A39-A42 https://doi.org/10.1149/1.3299251	journal	January 2010
Studies of Aromatic Redox Shuttle Additives for LiFePO₄-Based Li-Ion Cells Buhrmester, Claudia; Chen, Jun; Moshurchak, Lee Journal of The Electrochemical Society, Vol. 152, Issue 12, p. A2390-A2399 https://doi.org/10.1149/1.2098265	journal	January 2005
Electrochemical Overcharge Protection of Rechargeable Lithium Batteries: II . Effect of Lithium Iodide‐Iodine Additives on the Behavior of Lithium Electrode in LiAsF₆ Tetrahydrofuran Solutions Behl, Wishvender K.; Chin, Der‐Tau Journal of The Electrochemical Society, Vol. 135, Issue 1, p. 21-25 https://doi.org/10.1149/1.2095558	journal	January 1988
Redox flow cells for energy conversion Ponce de Leon, C.; Frias-Ferrer, A.; Gonzalez-Garcia, J. Journal of Power Sources, Vol. 160, Issue 1, p. 716-732 https://doi.org/10.1016/j.jpowsour.2006.02.095	journal	September 2006
Electrochemical investigation of uranium β-diketonates for all-uranium redox flow battery Yamamura, Tomoo; Shiokawa, Yoshinobu; Yamana, Hajimu Electrochimica Acta, Vol. 48, Issue 1, p. 43-50 https://doi.org/10.1016/S0013-4686(02)00546-7	journal	November 2002
A rechargeable redox battery utilizing ruthenium complexes with non-aqueous organic electrolyte Matsuda, Y.; Tanaka, K.; Okada, M. Journal of Applied Electrochemistry, Vol. 18, Issue 6, p. 909-914 https://doi.org/10.1007/BF01016050	journal	November 1988
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
High-performance Lithium Secondary Batteries Using Cathode Active Materials of Triquinoxalinylenes Exhibiting Six Electron Migration Matsunaga, Takayuki; Kubota, Takayuki; Sugimoto, Toyonari Chemistry Letters, Vol. 40, Issue 7, p. 750-752 https://doi.org/10.1246/cl.2011.750	journal	July 2011
Development of metal-based electrodes for non-aqueous redox flow batteries Kim, Jae-Hun; Kim, Ki Jae; Park, Min-Sik Electrochemistry Communications, Vol. 13, Issue 9, p. 997-1000 https://doi.org/10.1016/j.elecom.2011.06.022	journal	September 2011
Low band-gap polymers based on quinoxaline derivatives and fused thiophene as donor materials for high efficiency bulk-heterojunction photovoltaic cells Lee, Jang-Yong; Shin, Won-Suk; Haw, Jung-Rim Journal of Materials Chemistry, Vol. 19, Issue 28, p. 4938-4945 https://doi.org/10.1039/B823536H	journal	January 2009
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011
High-Potential Redox Shuttle for Use in Lithium-Ion Batteries Moshurchak, L. M.; Lamanna, W. M.; Bulinski, Mike Journal of The Electrochemical Society, Vol. 156, Issue 4, p. A309-A312 https://doi.org/10.1149/1.3077578	journal	January 2009
Energy storage for the electricity grid : benefits and market potential assessment guide : a study for the DOE Energy Storage Systems Program. Eyer, James M.; Corey, Garth P. https://doi.org/10.2172/1031895 SAND2010-0815	report	February 2010

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