Solvent-dependent conductance decay constants in single cluster junctions

Choi, Bonnie; Capozzi, Brian; Ahn, Seokhoon; Turkiewicz, Ari; Lovat, Giacomo; Nuckolls, Colin; Steigerwald, Michael L.; Venkataraman, Latha; Roy, Xavier

doi:10.1039/c5sc02595h

Title: Solvent-dependent conductance decay constants in single cluster junctions

Journal Article · Mon Jan 11 00:00:00 EST 2016 · Chemical Science

DOI:https://doi.org/10.1039/c5sc02595h· OSTI ID:1439057

Choi, Bonnie ^[1]; Capozzi, Brian ^[1]; Ahn, Seokhoon ^[2]; Turkiewicz, Ari ^[1]; Lovat, Giacomo ^[1]; Nuckolls, Colin ^[1]; Steigerwald, Michael L. ^[1]; Venkataraman, Latha ^[1]; Roy, Xavier ^[1]

Columbia Univ., New York, NY (United States)
Korea Institute of Science and Technology, Wanju (Korea)

We study single cluster electrical transport in a series of metal chalcogenide molecular clusters using scanning tunneling microscope-based break-junction measurements.

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Research Organization:: Columbia Univ., New York, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-01ER15264

OSTI ID:: 1439057

Journal Information:: Chemical Science, Vol. 7, Issue 4; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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References (29)

Effect of Anchoring Groups on Single-Molecule Conductance: Comparative Study of Thiol-, Amine-, and Carboxylic-Acid-Terminated Molecules Chen, Fang; Li, Xiulan; Hihath, Joshua Journal of the American Chemical Society, Vol. 128, Issue 49 https://doi.org/10.1021/ja065864k	journal	December 2006
Coulomb blockade and the Kondo effect in single-atom transistors Park, Jiwoong; Pasupathy, Abhay N.; Goldsmith, Jonas I. Nature, Vol. 417, Issue 6890 https://doi.org/10.1038/nature00791	journal	June 2002
Cluster Synthesis via Ligand-Arrested Solid Growth: Triethylphosphine-Capped Fragments of Binary Metal Chalcogenides Crawford, Nathan R. M.; Hee, Allan G.; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 124, Issue 50 https://doi.org/10.1021/ja027862f	journal	December 2002
Electron Transport in Molecular Wire Junctions Nitzan, A. Science, Vol. 300, Issue 5624 https://doi.org/10.1126/science.1081572	journal	May 2003
A molecular wire incorporating a robust hexanuclear platinum cluster Leary, Edmund; Van Zalinge, Harm; Higgins, Simon J. Physical Chemistry Chemical Physics, Vol. 11, Issue 25 https://doi.org/10.1039/b817424e	journal	January 2009
Measurement of Single-Molecule Resistance by Repeated Formation of Molecular Junctions Xu, B. Science, Vol. 301, Issue 5637 https://doi.org/10.1126/science.1087481	journal	August 2003
Effect of the environment on the electrical conductance of the single benzene-1,4-diamine molecule junction Nakashima, Shigeto; Takahashi, Yuuta; Kiguchi, Manabu Beilstein Journal of Nanotechnology, Vol. 2 https://doi.org/10.3762/bjnano.2.83	journal	January 2011
Electronics using hybrid-molecular and mono-molecular devices Joachim, C.; Gimzewski, J. K.; Aviram, A. Nature, Vol. 408, Issue 6812, p. 541-548 https://doi.org/10.1038/35046000	journal	November 2000
Importance of Direct Metal−π Coupling in Electronic Transport Through Conjugated Single-Molecule Junctions Meisner, Jeffrey S.; Ahn, Seokhoon; Aradhya, Sriharsha V. Journal of the American Chemical Society, Vol. 134, Issue 50 https://doi.org/10.1021/ja308626m	journal	December 2012
Electrical Conductance of Molecular Junctions by a Robust Statistical Analysis González, M. Teresa; Wu, Songmei; Huber, Roman Nano Letters, Vol. 6, Issue 10 https://doi.org/10.1021/nl061581e	journal	October 2006
Quantum Soldering of Individual Quantum Dots Roy, Xavier; Schenck, Christine L.; Ahn, Seokhoon Angewandte Chemie International Edition, Vol. 51, Issue 50 https://doi.org/10.1002/anie.201206301	journal	November 2012
Electrical Resistance of Long Conjugated Molecular Wires Ho Choi, S.; Kim, B.; Frisbie, C. D. Science, Vol. 320, Issue 5882 https://doi.org/10.1126/science.1156538	journal	June 2008
Single-molecule conductance determinations on HS(CH ₂ ) ₄ O(CH ₂ ) ₄ SH and HS(CH ₂ ) ₂ O(CH ₂ ) ₂ O(CH ₂ ) ₂ SH, and comparison with alkanedithiols of the same length Scullion, Lisa E.; Leary, Edmund; Higgins, Simon J. Journal of Physics: Condensed Matter, Vol. 24, Issue 16 https://doi.org/10.1088/0953-8984/24/16/164211	journal	March 2012
Oligoyne Single Molecule Wires Wang, Changsheng; Batsanov, Andrei S.; Bryce, Martin R. Journal of the American Chemical Society, Vol. 131, Issue 43 https://doi.org/10.1021/ja9061129	journal	November 2009
The use of phosphine chalcogenides in the preparation of cobalt chalcogenides Stuczynski, S. M.; Kwon, Y. -U.; Steigerwald, M. L. Journal of Organometallic Chemistry, Vol. 449, Issue 1-2 https://doi.org/10.1016/0022-328X(93)80120-Z	journal	May 1993
A Single-Molecule Potentiometer Meisner, Jeffrey S.; Kamenetska, Masha; Krikorian, Markrete Nano Letters, Vol. 11, Issue 4 https://doi.org/10.1021/nl104411f	journal	April 2011
Electrical Conductance of Oligothiophene Molecular Wires Yamada, Ryo; Kumazawa, Hiroaki; Noutoshi, Tomoharu Nano Letters, Vol. 8, Issue 4 https://doi.org/10.1021/nl0732023	journal	April 2008
Conductance of Single Alkanedithiols: Conduction Mechanism and Effect of Molecule−Electrode Contacts Li, Xiulan; He, Jin; Hihath, Joshua Journal of the American Chemical Society, Vol. 128, Issue 6 https://doi.org/10.1021/ja057316x	journal	February 2006
Atomically Wired Molecular Junctions: Connecting a Single Organic Molecule by Chains of Metal Atoms Yelin, Tamar; Vardimon, Ran; Kuritz, Natalia Nano Letters, Vol. 13, Issue 5 https://doi.org/10.1021/nl304702z	journal	April 2013
Influence of Binding Groups on Molecular Junction Formation Arroyo, Carlos R.; Leary, Edmund; Castellanos-Gómez, Andrés Journal of the American Chemical Society, Vol. 133, Issue 36 https://doi.org/10.1021/ja201861k	journal	September 2011
Environmental Control of Single-Molecule Junction Transport Fatemi, V.; Kamenetska, M.; Neaton, J. B. Nano Letters, Vol. 11, Issue 5 https://doi.org/10.1021/nl200324e	journal	May 2011
Identifying Diversity in Nanoscale Electrical Break Junctions Martín, Santiago; Grace, Iain; Bryce, Martin R. Journal of the American Chemical Society, Vol. 132, Issue 26 https://doi.org/10.1021/ja103327f	journal	July 2010
Understanding quantum interference in coherent molecular conduction Solomon, Gemma C.; Andrews, David Q.; Hansen, Thorsten The Journal of Chemical Physics, Vol. 129, Issue 5 https://doi.org/10.1063/1.2958275	journal	August 2008
E LECTRON T RANSMISSION T HROUGH M OLECULES AND M OLECULAR I NTERFACES Nitzan, Abraham Annual Review of Physical Chemistry, Vol. 52, Issue 1 https://doi.org/10.1146/annurev.physchem.52.1.681	journal	October 2001
Contact Chemistry and Single-Molecule Conductance: A Comparison of Phosphines, Methyl Sulfides, and Amines Park, Young S.; Whalley, Adam C.; Kamenetska, Maria Journal of the American Chemical Society, Vol. 129, Issue 51 https://doi.org/10.1021/ja0773857	journal	December 2007
Conductance of Single Cobalt Chalcogenide Cluster Junctions Boardman, Brycelyn M.; Widawsky, Jonathan R.; Park, Young S. Journal of the American Chemical Society, Vol. 133, Issue 22 https://doi.org/10.1021/ja201334s	journal	June 2011
Quantum Soldering of Individual Quantum Dots Roy, Xavier; Schenck, Christine L.; Ahn, Seokhoon Angewandte Chemie, Vol. 124, Issue 50 https://doi.org/10.1002/ange.201206301	journal	November 2012
Ab Initio and Theoretical Study on Electron Transport through Polyene Junctions in between Carbon Nanotube Leads of Various Cuts Chen, Yiing-Rei; Lin, Ming-Kuan; Chan, Dun-Hao Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-63363-3	journal	May 2020
Electrical conductance of molecular junctions by a robust statistical analysis González, M. Teresa; Wu, Songmei; Huber, Roman arXiv https://doi.org/10.48550/arxiv.cond-mat/0610303	text	January 2006

Cited By (6)

Light‐Driven Reversible Intermolecular Proton Transfer at Single‐Molecule Junctions Cai, Shuning; Deng, Wenting; Huang, Feifei Angewandte Chemie, Vol. 131, Issue 12 https://doi.org/10.1002/ange.201813137	journal	February 2019
Light‐Driven Reversible Intermolecular Proton Transfer at Single‐Molecule Junctions Cai, Shuning; Deng, Wenting; Huang, Feifei Angewandte Chemie International Edition, Vol. 58, Issue 12 https://doi.org/10.1002/anie.201813137	journal	March 2019
Room-temperature current blockade in atomically defined single-cluster junctions Lovat, Giacomo; Choi, Bonnie; Paley, Daniel W. Nature Nanotechnology, Vol. 12, Issue 11 https://doi.org/10.1038/nnano.2017.156	journal	August 2017
Insulated molecular wires: inhibiting orthogonal contacts in metal complex based molecular junctions Al-Owaedi, Oday A.; Bock, Sören; Milan, David C. Nanoscale, Vol. 9, Issue 28 https://doi.org/10.1039/c7nr01829k	journal	January 2017
Understanding the charge transport properties of redox active metal–organic conjugated wires Bu, Donglei; Xiong, Yingqi; Tan, Ying Ning Chemical Science, Vol. 9, Issue 14 https://doi.org/10.1039/c7sc04727d	journal	January 2018
Beyond Marcus theory and the Landauer-Büttiker approach in molecular junctions: A unified framework Sowa, Jakub K.; Mol, Jan A.; Briggs, G. Andrew D. The Journal of Chemical Physics, Vol. 149, Issue 15 https://doi.org/10.1063/1.5049537	journal	October 2018

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