High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction

Liu, Kewei; Zhang, Changlin; Sun, Yuandong; Zhang, Guanghui; Shen, Xiaochen; Zou, Feng; Zhang, Haichang; Wu, Zhenwei; Wegener, Evan C.; Taubert, Clinton J.; Miller, Jeffrey T.; Peng, Zhenmeng; Zhu, Yu

doi:10.1021/acsnano.7b04646

High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction

Journal Article · Wed Dec 06 00:00:00 EST 2017 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.7b04646· OSTI ID:1438846

Liu, Kewei ^[1]; ^[2]; Sun, Yuandong ^[1]; Zhang, Guanghui ^[3]; Shen, Xiaochen ^[1]; Zou, Feng ^[1]; Zhang, Haichang ^[1]; Wu, Zhenwei ^[3]; Wegener, Evan C. ^[3]; Taubert, Clinton J. ^[1]; Miller, Jeffrey T. ^[3]; ^[1]; ^[1]

Univ. of Akron, OH (United States)
Univ. of Akron, OH (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Joint Center for Artificial Photosynthesis
Purdue Univ., West Lafayette, IN (United States). School of Chemical Engineering

Oxygen evolution reaction (OER) is a pivotal process in many energy conversion and storage techniques, such as water splitting, regenerative fuel cells, and rechargeable metal-air batteries. The synthesis of stable, efficient, non-noble metal-based electrocatalysts for OER has been a long-standing challenge. In this work, a facile and scalable method to synthesize hollow and conductive iron–cobalt phosphide (Fe–Co–P) alloy nanostructures using an Fe–Co metal organic complex as a precursor is described. The Fe–Co–P alloy exhibits excellent OER activity with a specific current density of 10 mA/cm² being achieved at an overpotential as low as 252 mV. The current density at 1.5 V (vs reversible hydrogen electrode) of the Fe–Co–P catalyst is 30.7 mA/cm², which is more than 3 orders of magnitude greater than that obtained with state-of-the-art Fe–Co oxide catalysts. Our mechanistic experiments and theoretical analysis suggest that the electrochemical-induced high-valent iron stabilizes the cobalt in a low-valent state, leading to the simultaneous enhancement of activity and stability of the OER catalyst.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (US). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1438846

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 1 Vol. 12; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Journal Article · Tue Jun 26 20:00:00 EDT 2018 · Angewandte Chemie · OSTI ID:1457468

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Materials
Metals
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hollow sphere
oxygen evolution reaction
self-assembly

High-Performance Transition Metal Phosphide Alloy Catalyst for Oxygen Evolution Reaction

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