Novel colloidal materials from functionalized polyoxometalates
Journal Article
·
· Inorganic Chemistry Communications
- Illinois Inst. of Technology, Chicago, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials; Univ. of Chicago, IL (United States). Inst. for Molecular Engineering
Here, novel colloidal materials were prepared for the first time from the organo-functionalized Anderson structure polyoxometalate species [NaVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]Cl·H2O and the mixed-addenda Keggin structure polyoxometalate, K4(PVW11O40). The materials were characterized by SEM, TGA, FTIR and UV-vis spectroscopy. The colloidal materials are readily separated from suspension in the form of redistributable micrometer-scale monoliths, which may be considered a type of POM heterogenation. The monoliths are insoluble in low polarity media and lower aliphatic alcohols and readily form thin-films (δ < 100 um) by solvent casting.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1438587
- Journal Information:
- Inorganic Chemistry Communications, Vol. 84, Issue C; ISSN 1387-7003
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 2 works
Citation information provided by
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