Investigation of α-MnO2 Tunneled Structures as Model Cation Hosts for Energy Storage

Housel, Lisa M.; Wang, Lei; Abraham, Alyson; Huang, Jianping; Renderos, Genesis D.; Quilty, Calvin D.; Brady, Alexander B.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

doi:10.1021/acs.accounts.7b00478

Investigation of α-MnO₂ Tunneled Structures as Model Cation Hosts for Energy Storage

Journal Article · Mon Feb 19 00:00:00 EST 2018 · Accounts of Chemical Research

DOI:https://doi.org/10.1021/acs.accounts.7b00478· OSTI ID:1438326

Housel, Lisa M. ^[1]; ^[1]; Abraham, Alyson ^[1]; Huang, Jianping ^[1]; Renderos, Genesis D. ^[1]; Quilty, Calvin D. ^[1]; Brady, Alexander B. ^[1]; ^[2]; ^[1]; ^[2]

Stony Brook Univ., Stony Brook, NY (United States)
Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Future advances in energy storage systems rely on identification of appropriate target materials and deliberate synthesis of the target materials with control of their physiochemical properties in order to disentangling the contributions of distinct properties to the functional electrochemistry. Furthermore, this goal demands systematic inquiry using model materials that provide the opportunity for significant synthetic versatility and control. Ideally, a material family that enables direct manipulation of characteristics including composition, defects and crystallite size while remaining within the defined structural framework would be necessary. Accomplishing this through direct synthetic methods is desirable to minimize the complicating effects of secondary processing.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1438326

Report Number(s):: BNL--205690-2018-JAAM

Journal Information:: Accounts of Chemical Research, Journal Name: Accounts of Chemical Research Journal Issue: 3 Vol. 51; ISSN 0001-4842

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Incorporating Pb²⁺ Templates into the Crystalline Structure of MnO₂ Catalyst Supported on Monolith: Applications in H₂O₂ Decomposition Hasanpour, Fatemeh; Saien, Javad ACS Omega, Vol. 4, Issue 15 https://doi.org/10.1021/acsomega.9b02565	journal	September 2019
K ⁺ pre-intercalated manganese dioxide with enhanced Zn ²⁺ diffusion for high rate and durable aqueous zinc-ion batteries Liu, Guoxue; Huang, Huawen; Bi, Ran Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta08049j	journal	January 2019
Tunable nanomechanical performance regimes in ceramic nanowires Maksud, Mahjabin; Barua, Mathius; Shikder, Md Ruhul Amin Nanotechnology, Vol. 30, Issue 47 https://doi.org/10.1088/1361-6528/ab3dcf	journal	September 2019
Solid electrolyte interphases for high-energy aqueous aluminum electrochemical cells Zhao, Qing; Zachman, Michael J.; Al Sadat, Wajdi I. Science Advances, Vol. 4, Issue 11 https://doi.org/10.1126/sciadv.aau8131	journal	November 2018
Silver-Containing α-MnO ₂ Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO ₂ Batteries Wang, Lei; Wu, Qiyuan; Abraham, Alyson Journal of The Electrochemical Society, Vol. 166, Issue 15 https://doi.org/10.1149/2.0101915jes	journal	January 2019
Capacity Retention for (De)lithiation of Silver Containing α-MnO ₂ : Impact of Structural Distortion and Transition Metal Dissolution Huang, Jianping; Housel, Lisa M.; Quilty, Calvin D. Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0371811jes	journal	January 2018

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