Self-organizing layers from complex molecular anions

Warneke, Jonas; McBriarty, Martin E.; Riechers, Shawn L.; China, Swarup; Engelhard, Mark H.; Apra, Edoardo; Young, Robert P.; Washton, Nancy M.; Jenne, Carsten; Johnson, Grant E.; Laskin, Julia

doi:10.1038/s41467-018-04228-2

Title: Self-organizing layers from complex molecular anions

Journal Article · Mon May 14 00:00:00 EDT 2018 · Nature Communications

DOI:https://doi.org/10.1038/s41467-018-04228-2· OSTI ID:1438251

^[1];

^[1]; China, Swarup ^[2];

^[2];

^[3]; Johnson, Grant E. ^[1]; Laskin, Julia ^[4]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Sciences Division
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
Bergische Univ. Wuppertal, Wuppertal (Germany). Fakultat fur Mathematik und Naturwissenschaften, Anorganische Chemie
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Sciences Division; Purdue Univ., West Lafayette, IN (United States). Dept. of Chemistry

The formation of traditional ionic materials occurs principally via joint accumulation of both anions and cations. Here in this paper, we describe a previously unreported phenomenon by which macroscopic liquid-like thin layers with tunable self-organization properties form through accumulation of stable complex ions of one polarity on surfaces. Using a series of highly stable molecular anions we demonstrate a strong influence of the internal charge distribution of the molecular ions, which is usually shielded by counterions, on the properties of the layers. Detailed characterization reveals that the intrinsically unstable layers of anions on surfaces are stabilized by simultaneous accumulation of neutral molecules from the background environment. Different phases, self-organization mechanisms and optical properties are observed depending on the molecular properties of the deposited anions, the underlying surface and the coadsorbed neutral molecules. This demonstrates rational control of the macroscopic properties (morphology and size of the formed structures) of the newly discovered anion-based layers.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; USDOE Office of Science (SC), Biological and Environmental Research (BER); Alexander von Humboldt Foundation

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1438251

Report Number(s):: PNNL-SA-128240; PII: 4228

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 27 works

Citation information provided by
Web of Science

References (80)

Processing of giant graphene molecules by soft-landing mass spectrometry Räder, Hans Joachim; Rouhanipour, Ali; Talarico, Anna Maria Nature Materials, Vol. 5, Issue 4, p. 276-280 https://doi.org/10.1038/nmat1597	journal	March 2006
Control of chemical reactions and synthesis by low-energy electrons Böhler, Esther; Warneke, Jonas; Swiderek, Petra Chemical Society Reviews, Vol. 42, Issue 24 https://doi.org/10.1039/c3cs60180c	journal	January 2013
Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin Assaf, Khaleel I.; Ural, Merve S.; Pan, Fangfang Angewandte Chemie, Vol. 127, Issue 23 https://doi.org/10.1002/ange.201412485	journal	May 2015
Gas-assisted focused electron beam and ion beam processing and fabrication Utke, Ivo; Hoffmann, Patrik; Melngailis, John Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 26, Issue 4 https://doi.org/10.1116/1.2955728	journal	January 2008
Pressure Dependence of the Contact Angle Wu, Jiyu; Farouk, T.; Ward, C. A. The Journal of Physical Chemistry B, Vol. 111, Issue 22 https://doi.org/10.1021/jp071372y	journal	June 2007
On the Oxidation of the Three-Dimensional Aromatics [B ₁₂ X ₁₂ ] ²⁻ (X=F, Cl, Br, I) Boeré, René T.; Derendorf, Janis; Jenne, Carsten Chemistry - A European Journal, Vol. 20, Issue 15 https://doi.org/10.1002/chem.201304405	journal	March 2014
Interface Dipoles Arising from Self-Assembled Monolayers on Gold: UV−Photoemission Studies of Alkanethiols and Partially Fluorinated Alkanethiols Alloway, Dana M.; Hofmann, Michael; Smith, Darrin L. The Journal of Physical Chemistry B, Vol. 107, Issue 42 https://doi.org/10.1021/jp034665+	journal	September 2003
Catalysis by clusters with precise numbers of atoms Tyo, Eric C.; Vajda, Stefan Nature Nanotechnology, Vol. 10, Issue 7 https://doi.org/10.1038/nnano.2015.140	journal	July 2015
Wetting and spreading Bonn, Daniel; Eggers, Jens; Indekeu, Joseph Reviews of Modern Physics, Vol. 81, Issue 2 https://doi.org/10.1103/RevModPhys.81.739	journal	May 2009
Fundamental Aspects of Catalysis on Supported Metal Clusters Heiz, U.; Bullock, E. L. ChemInform, Vol. 35, Issue 29 https://doi.org/10.1002/chin.200429290	journal	July 2004
Dewetting Patterns and Molecular Forces: A Reconciliation Herminghaus, S.; Jacobs, K.; Seemann, R. The American Physical Society https://doi.org/10.17877/de290r-12640	text	January 2001
Helical Peptide Arrays on Self-Assembled Monolayer Surfaces through Soft and Reactive Landing of Mass-Selected Ions Wang, Peng; Laskin, Julia Angewandte Chemie International Edition, Vol. 47, Issue 35, p. 6678-6680 https://doi.org/10.1002/anie.200801366	journal	August 2008
Anisotropic spinodal dewetting as a route to self-assembly of patterned surfaces Higgins, A. M.; Jones, R. A. L. Nature, Vol. 404, Issue 6777 https://doi.org/10.1038/35006597	journal	March 2000
Applications of dewetting in micro and nanotechnology Gentili, Denis; Foschi, Giulia; Valle, Francesco Chemical Society Reviews, Vol. 41, Issue 12 https://doi.org/10.1039/c2cs35040h	journal	January 2012
Functional Liquid-Crystalline Assemblies: Self-Organized Soft Materials Kato, Takashi; Mizoshita, Norihiro; Kishimoto, Kenji ChemInform, Vol. 37, Issue 15 https://doi.org/10.1002/chin.200615236	journal	April 2006
Charge Retention by Gold Clusters on Surfaces Prepared Using Soft Landing of Mass Selected Ions Johnson, Grant E.; Priest, Thomas; Laskin, Julia ACS Nano, Vol. 6, Issue 1 https://doi.org/10.1021/nn2039565	journal	December 2011
Microwave-Assisted Iodination: Synthesis of Heavily Iodinated 10-Vertex and 12-Vertex Boron Clusters Juhasz, Marcus A.; Matheson, Graham R.; Chang, Paul S. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 46, Issue 4 https://doi.org/10.1080/15533174.2014.988819	journal	July 2015
Self-Assembly at All Scales Whitesides, George M.; Grzybowski, Bartosz Science, Vol. 295, Issue 5564, p. 2418-2421 https://doi.org/10.1126/science.1070821	journal	March 2002
Preparing Protein Microarrays by Soft-Landing of Mass-Selected Ions Ouyang, Z. Science, Vol. 301, Issue 5638 https://doi.org/10.1126/science.1088776	journal	September 2003
A combined discrete/continuum solvation model: Application to glycine Bandyopadhyay, Pradipta; Gordon, Mark S. The Journal of Chemical Physics, Vol. 113, Issue 3 https://doi.org/10.1063/1.481889	journal	July 2000
In situ Studies of Soft- and Reactive Landing of Mass-Selected Ions Using Infrared Reflection Absorption Spectroscopy Hu, Qichi; Wang, Peng; Gassman, Paul L. Analytical Chemistry, Vol. 81, Issue 17 https://doi.org/10.1021/ac901149s	journal	September 2009
Dewetting of conducting polymer inkjet droplets on patterned surfaces Wang, J. Z.; Zheng, Z. H.; Li, H. W. Nature Materials, Vol. 3, Issue 3, p. 171-176 https://doi.org/10.1038/nmat1073	journal	February 2004
Bombardment induced ion transport—Part II. Experimental potassium ion conductivities in borosilicate glass Menezes, P. V.; Martin, J.; Schäfer, M. Physical Chemistry Chemical Physics, Vol. 13, Issue 45 https://doi.org/10.1039/c1cp21216h	journal	January 2011
Cluster–surface interaction: From soft landing to implantation Popok, Vladimir N.; Barke, Ingo; Campbell, Eleanor E. B. Surface Science Reports, Vol. 66, Issue 10 https://doi.org/10.1016/j.surfrep.2011.05.002	journal	October 2011
A hydrodynamically optimized nano-electrospray ionization source and vacuum interface Pauly, M.; Sroka, M.; Reiss, J. The Analyst, Vol. 139, Issue 8 https://doi.org/10.1039/c3an01836a	journal	January 2014
Nanospray desorption electrospray ionization: an ambient method for liquid-extraction surface sampling in mass spectrometry Roach, Patrick J.; Laskin, Julia; Laskin, Alexander The Analyst, Vol. 135, Issue 9 https://doi.org/10.1039/c0an00312c	journal	January 2010
Chemistry of Boranes. IX. Halogenation of B ₁₀ H ₁₀ ^-2 and B ₁₂ H ₁₂ ^-2 Knoth, W. H.; Miller, H. C.; Sauer, J. C. Inorganic Chemistry, Vol. 3, Issue 2 https://doi.org/10.1021/ic50012a002	journal	February 1964
Plasticizer contamination from vacuum system o-rings in a quadrupole ion trap mass spectrometer Verge, Kent M.; Agnes, George R. Journal of the American Society for Mass Spectrometry, Vol. 13, Issue 8 https://doi.org/10.1016/s1044-0305(02)00386-0	journal	August 2002
Synthesis and characterization of synthetically useful salts of the weakly-coordinating dianion [B12Cl12]2− Geis, Vanessa; Guttsche, Kristin; Knapp, Carsten Dalton Transactions, Issue 15 https://doi.org/10.1039/b821030f	journal	January 2009
NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations Valiev, M. Mendeley https://doi.org/10.17632/76233tt7cn.1	dataset	January 2019
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au₈ Clusters on MgO Yoon, Bokwon; Häkkinen, Hannu; Landman, Uzi Science, Vol. 307, Issue 5708, p. 403-407 https://doi.org/10.1126/science.1104168	journal	January 2005
Active Conformation Control of Unfolded Proteins by Hyperthermal Collision with a Metal Surface Rinke, Gordon; Rauschenbach, Stephan; Harnau, Ludger Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl502122j	journal	September 2014
NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations Valiev, M.; Bylaska, E. J.; Govind, N. Computer Physics Communications, Vol. 181, Issue 9, p. 1477-1489 https://doi.org/10.1016/j.cpc.2010.04.018	journal	September 2010
Atomically precise (catalytic) particles synthesized by a novel cluster deposition instrument Yin, C.; Tyo, E.; Kuchta, K. The Journal of Chemical Physics, Vol. 140, Issue 17, Article No. 174201 https://doi.org/10.1063/1.4871799	journal	May 2014
A soft-landing experiment on organometallic cluster ions: infrared spectroscopy of V(benzene)2 in Ar matrix Judai, Ken; Sera, Kentaro; Amatsutsumi, Shin-ichi Chemical Physics Letters, Vol. 334, Issue 4-6 https://doi.org/10.1016/s0009-2614(00)01450-0	journal	February 2001
Engineering atomic and molecular nanostructures at surfaces Barth, Johannes V.; Costantini, Giovanni; Kern, Klaus Nature, Vol. 437, Issue 7059 https://doi.org/10.1038/nature04166	journal	September 2005
Activating technology of SnO2 layers by metal particles from ultrathin metal films Mizsei, J. Sensors and Actuators B: Chemical, Vol. 16, Issue 1-3 https://doi.org/10.1016/0925-4005(93)85204-n	journal	October 1993
Fundamental aspects of catalysis on supported metal clusters Heiz, U.; Bullock, E. L. Journal of Materials Chemistry, Vol. 14, Issue 4 https://doi.org/10.1039/b313560h	journal	January 2004
Functional Liquid-Crystalline Assemblies: Self-Organized Soft Materials Kato, Takashi; Mizoshita, Norihiro; Kishimoto, Kenji Angewandte Chemie International Edition, Vol. 45, Issue 1 https://doi.org/10.1002/anie.200501384	journal	January 2006
Hard and Soft Acids and Bases Pearson, Ralph G. Journal of the American Chemical Society, Vol. 85, Issue 22 https://doi.org/10.1021/ja00905a001	journal	November 1963
Interaction of B ₁₂ F ₁₂ ^2– with All- cis 1,2,3,4,5,6 Hexafluorocyclohexane in the Gas Phase Lecours, Michael J.; Marta, Rick A.; Steinmetz, Vincent The Journal of Physical Chemistry Letters, Vol. 8, Issue 1 https://doi.org/10.1021/acs.jpclett.6b02629	journal	December 2016
Coverage-Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-Selected Ions Johnson, Grant E.; Priest, Thomas; Laskin, Julia The Journal of Physical Chemistry C, Vol. 116, Issue 47, p. 24977-24986 https://doi.org/10.1021/jp308795r	journal	November 2012
Nanofluidics: what is it and what can we expect from it? Eijkel, Jan C. T.; Berg, Albert van den Microfluidics and Nanofluidics, Vol. 1, Issue 3 https://doi.org/10.1007/s10404-004-0012-9	journal	April 2005
A Close Look at Proteins: Submolecular Resolution of Two- and Three-Dimensionally Folded Cytochrome c at Surfaces Deng, Zhitao; Thontasen, Nicha; Malinowski, Nikola Nano Letters, Vol. 12, Issue 5 https://doi.org/10.1021/nl3005385	journal	April 2012
Anomalous Coarsening Driven by Reversible Charge Transfer at Metal–Organic Interfaces Della Pia, Ada; Riello, Massimo; Floris, Andrea ACS Nano, Vol. 8, Issue 12 https://doi.org/10.1021/nn505063w	journal	November 2014
Surface Chemistry for Molecular Layer Deposition of Organic and Hybrid Organic−Inorganic Polymers George, Steven M.; Yoon, Byunghoon; Dameron, Arrelaine A. Accounts of Chemical Research, Vol. 42, Issue 4 https://doi.org/10.1021/ar800105q	journal	April 2009
Mass-Selective Soft-Landing of Protein Assemblies with Controlled Landing Energies Mikhailov, Victor A.; Mize, Todd H.; Benesch, Justin L. P. Analytical Chemistry, Vol. 86, Issue 16 https://doi.org/10.1021/ac5018327	journal	July 2014
Direct Perfluorination of K ₂ B ₁₂ H ₁₂ in Acetonitrile Occurs at the Gas Bubble−Solution Interface and Is Inhibited by HF. Experimental and DFT Study of Inhibition by Protic Acids and Soft, Polarizable Anions Peryshkov, Dmitry V.; Popov, Alexey A.; Strauss, Steven H. Journal of the American Chemical Society, Vol. 131, Issue 51 https://doi.org/10.1021/ja9069437	journal	December 2009
Electrowetting: from basics to applications Mugele, Frieder; Baret, Jean-Christophe Journal of Physics: Condensed Matter, Vol. 17, Issue 28 https://doi.org/10.1088/0953-8984/17/28/r01	journal	July 2005
Dewetting Patterns and Molecular Forces: A Reconciliation Seemann, R.; Herminghaus, S.; Jacobs, K. Physical Review Letters, Vol. 86, Issue 24 https://doi.org/10.1103/PhysRevLett.86.5534	journal	June 2001
Influence of Cluster–Support Interactions on Reactivity of Size-Selected Nb _x O _y Clusters Nakayama, Miki; Xue, Meng; An, Wei The Journal of Physical Chemistry C, Vol. 119, Issue 26 https://doi.org/10.1021/acs.jpcc.5b00691	journal	April 2015
Soft landing of ions as a means of surface modification Franchetti, V.; Solka, B. H.; Baitinger, W. E. International Journal of Mass Spectrometry and Ion Physics, Vol. 23, Issue 1 https://doi.org/10.1016/0020-7381(77)80004-1	journal	January 1977
Controlling the Charge State and Redox Properties of Supported Polyoxometalates via Soft Landing of Mass-Selected Ions Gunaratne, K. Don D.; Johnson, Grant E.; Andersen, Amity The Journal of Physical Chemistry C, Vol. 118, Issue 48 https://doi.org/10.1021/jp505050m	journal	October 2014
Solid-State Dewetting of Thin Films Thompson, Carl V. Annual Review of Materials Research, Vol. 42, Issue 1 https://doi.org/10.1146/annurev-matsci-070511-155048	journal	August 2012
Helical Peptide Arrays on Self-Assembled Monolayer Surfaces through Soft and Reactive Landing of Mass-Selected Ions Wang, Peng; Laskin, Julia Angewandte Chemie, Vol. 120, Issue 35 https://doi.org/10.1002/ange.200801366	journal	August 2008
Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets Warneke, Jonas; Jenne, Carsten; Bernarding, Johannes Chemical Communications, Vol. 52, Issue 37 https://doi.org/10.1039/c6cc01233g	journal	January 2016
Electronic Structure Controls Reactivity of Size-Selected Pd Clusters Adsorbed on TiO2 Surfaces Kaden, W. E.; Wu, T.; Kunkel, W. A. Science, Vol. 326, Issue 5954 https://doi.org/10.1126/science.1180297	journal	November 2009
Determination of the mode and efficacy of the cross-linking of guar by borate using MAS ¹¹ B NMR of borate cross-linked guar in combination with solution ¹¹ B NMR of model systems Bishop, Maximilienne; Shahid, Naureen; Yang, Jianzhong Dalton Trans., Issue 17 https://doi.org/10.1039/B406952H	journal	January 2004
Bombardment induced ion transport – part IV: ionic conductivity of ultra-thin polyelectrolyte multilayer films Wesp, Veronika; Hermann, Matthias; Schäfer, Martin Physical Chemistry Chemical Physics, Vol. 18, Issue 6 https://doi.org/10.1039/C5CP04004C	journal	January 2016
Electronic Structure and Stability of [B ₁₂ X ₁₂ ] ^2– (X = F–At): A Combined Photoelectron Spectroscopic and Theoretical Study Warneke, Jonas; Hou, Gao-Lei; Aprà, Edoardo Journal of the American Chemical Society, Vol. 139, Issue 41 https://doi.org/10.1021/jacs.7b08598	journal	October 2017
Charge retention of soft-landed phosphotungstate Keggin anions on self-assembled monolayers Gunaratne, K. Don D.; Prabhakaran, Venkateshkumar; Andersen, Amity Physical Chemistry Chemical Physics, Vol. 18, Issue 13 https://doi.org/10.1039/C5CP06954H	journal	January 2016
Long-range repulsive interaction between TTF molecules on a metal surface induced by charge transfer Fernandez-Torrente, I.; Monturet, S.; Franke, K. J. arXiv https://doi.org/10.48550/arxiv.0707.1045	text	January 2007
Soft- and reactive landing of ions onto surfaces: Concepts and applications: CONCEPTS AND APPLICATIONS Johnson, Grant E.; Gunaratne, Don; Laskin, Julia Mass Spectrometry Reviews, Vol. 35, Issue 3 https://doi.org/10.1002/mas.21451	journal	April 2015
Synthesis, Crystal Structure, and Reactivity of the Strong Methylating Agent Me2B12Cl12 Bolli, Christoph; Derendorf, Janis; Keßler, Mathias Angewandte Chemie International Edition, Vol. 49, Issue 20 https://doi.org/10.1002/anie.200906627	journal	April 2010
Investigations on the E/Z-isomerism of neonicotinoids Schindler, Michael Journal of Computer-Aided Molecular Design, Vol. 35, Issue 4 https://doi.org/10.1007/s10822-020-00326-w	journal	July 2020
Electrospray Ion Beam Deposition: Soft-Landing and Fragmentation of Functional Molecules at Solid Surfaces Rauschenbach, Stephan; Vogelgesang, Ralf; Malinowski, N. ACS Nano, Vol. 3, Issue 10 https://doi.org/10.1021/nn900022p	journal	September 2009
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy Weigend, Florian; Ahlrichs, Reinhart Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305 https://doi.org/10.1039/b508541a	journal	January 2005
Theory of Metal Surfaces: Induced Surface Charge and Image Potential Lang, N. D.; Kohn, W. Physical Review B, Vol. 7, Issue 8 https://doi.org/10.1103/PhysRevB.7.3541	journal	April 1973
Toward reliable density functional methods without adjustable parameters: The PBE0 model Adamo, Carlo; Barone, Vincenzo The Journal of Chemical Physics, Vol. 110, Issue 13 https://doi.org/10.1063/1.478522	journal	April 1999
Long-Range Repulsive Interaction between Molecules on a Metal Surface Induced by Charge Transfer Fernandez-Torrente, I.; Monturet, S.; Franke, K. J. Physical Review Letters, Vol. 99, Issue 17 https://doi.org/10.1103/PhysRevLett.99.176103	journal	October 2007
Design and performance of a high-flux electrospray ionization source for ion soft landing Gunaratne, K. Don D.; Prabhakaran, Venkateshkumar; Ibrahim, Yehia M. The Analyst, Vol. 140, Issue 9 https://doi.org/10.1039/C5AN00220F	journal	January 2015
Thin Film Instability Induced by Long-Range Forces Reiter, Günter; Sharma, Ashutosh; Casoli, Alain Langmuir, Vol. 15, Issue 7 https://doi.org/10.1021/la981470y	journal	March 1999
Soft Landing of Complex Molecules on Surfaces Johnson, Grant E.; Hu, Qichi; Laskin, Julia Annual Review of Analytical Chemistry, Vol. 4, Issue 1, p. 83-104 https://doi.org/10.1146/annurev-anchem-061010-114028	journal	July 2011
Toward Self-Organization and Complex Matter Lehn, J. -M. Science, Vol. 295, Issue 5564 https://doi.org/10.1126/science.1071063	journal	March 2002
Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin Assaf, Khaleel I.; Ural, Merve S.; Pan, Fangfang Angewandte Chemie International Edition, Vol. 54, Issue 23 https://doi.org/10.1002/anie.201412485	journal	May 2015
Catalysis Applications of Size-Selected Cluster Deposition Vajda, Stefan; White, Michael G. ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b01816	journal	November 2015
Templated dewetting: designing entirely self-organized platforms for photocatalysis Altomare, Marco; Nguyen, Nhat Truong; Schmuki, Patrik Chemical Science, Vol. 7, Issue 12 https://doi.org/10.1039/c6sc02555b	journal	January 2016
Structure and electronic properties of CH3- and CF3-terminated alkanethiol monolayers on Au(): a scanning tunneling microscopy, surface X-ray and helium scattering study Pflaum, J.; Bracco, G.; Schreiber, F. Surface Science, Vol. 498, Issue 1-2 https://doi.org/10.1016/s0039-6028(01)01495-9	journal	February 2002
Rational design of efficient electrode–electrolyte interfaces for solid-state energy storage using ion soft landing Prabhakaran, Venkateshkumar; Mehdi, B. Layla; Ditto, Jeffrey J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11399	journal	April 2016
Note: Proof of principle of a new type of cluster beam source with potential for scale-up Palmer, R. E.; Cao, L.; Yin, F. Review of Scientific Instruments, Vol. 87, Issue 4 https://doi.org/10.1063/1.4947229	journal	April 2016

Cited By (12)

Rational design of an argon-binding superelectrophilic anion Mayer, Martin; van Lessen, Valentin; Rohdenburg, Markus Proceedings of the National Academy of Sciences, Vol. 116, Issue 17 https://doi.org/10.1073/pnas.1820812116	journal	April 2019
Properties of perhalogenated { closo -B ₁₀ } and { closo -B ₁₁ } multiply charged anions and a critical comparison with { closo -B ₁₂ } in the gas and the condensed phase Warneke, Jonas; Konieczka, Szymon Z.; Hou, Gao-Lei Physical Chemistry Chemical Physics, Vol. 21, Issue 11 https://doi.org/10.1039/c8cp05313h	journal	January 2019
Von isolierten Ionen zu mehrschichtigen funktionellen Materialien durch sanfte Landung von Ionen Laskin, Julia; Johnson, Grant E.; Warneke, Jonas Angewandte Chemie, Vol. 130, Issue 50 https://doi.org/10.1002/ange.201712296	journal	November 2018
First steps towards a stable neon compound: observation and bonding analysis of [B 12 (CN) 11 Ne] − Mayer, Martin; Rohdenburg, Markus; van Lessen, Valentin Royal Society of Chemistry https://doi.org/10.48350/150589	text	January 2020
First steps towards a stable neon compound: observation and bonding analysis of [B ₁₂ (CN) ₁₁ Ne] ⁻ Mayer, Martin; Rohdenburg, Markus; van Lessen, Valentin Chemical Communications, Vol. 56, Issue 33 https://doi.org/10.1039/d0cc01423k	journal	January 2020
Top-down synthesis of polyoxometalate-like sub-nanometer molybdenum-oxo clusters as high-performance electrocatalysts Liu, Rongji; Cao, Kecheng; Clark, Adam H. Chemical Science, Vol. 11, Issue 4 https://doi.org/10.1039/c9sc05469c	journal	January 2020
From Isolated Ions to Multilayer Functional Materials Using Ion Soft Landing Laskin, Julia; Johnson, Grant E.; Warneke, Jonas Angewandte Chemie International Edition, Vol. 57, Issue 50 https://doi.org/10.1002/anie.201712296	journal	November 2018
The Chaotropic Effect as an Assembly Motif in Chemistry Assaf, Khaleel I.; Nau, Werner M. Angewandte Chemie International Edition, Vol. 57, Issue 43 https://doi.org/10.1002/anie.201804597	journal	September 2018
Der chaotrope Effekt als Aufbaumotiv in der Chemie Assaf, Khaleel I.; Nau, Werner M. Angewandte Chemie, Vol. 130, Issue 43 https://doi.org/10.1002/ange.201804597	journal	September 2018
Top-down synthesis of polyoxometalate-like sub-nanometer molybdenum-oxo clusters as high-performance electrocatalysts Liu, Rongji; Cao, Kecheng; Clark, Adam H. Karlsruhe https://doi.org/10.5445/ir/1000106007	text	January 2020
Non-equilibrium adatom thermal state enables rapid additive nanomanufacturing Henry, Matthew R.; Kim, Songkil; Fedorov, Andrei G. Physical Chemistry Chemical Physics, Vol. 21, Issue 20 https://doi.org/10.1039/c9cp01478k	journal	January 2019
Rational design of an argon-binding superelectrophilic anion Mayer, Martin; Van Lessen, Valentin; Rohdenburg, Markus National Academy of Sciences NAS https://doi.org/10.7892/boris.138392	text	January 2019

Similar Records

Self-organizing layers from complex molecular anions

Journal Article · Mon May 14 00:00:00 EDT 2018 · Nature Communications · OSTI ID:1438251

Warneke, Jonas; McBriarty, Martin E.; Riechers, Shawn L.; +8 more

Hydrogen Bonding Inside Anionic Polymeric Brush Layer: Machine Learning-Driven Exploration of the Relative Roles of the Polymer Steric Effect, Charging, and Type of Screening Counterions

Journal Article · Sat Feb 10 00:00:00 EST 2024 · Macromolecules · OSTI ID:1438251

Bera, Arka; Akash, Tanmay Sarkar; Ishraaq, Raashiq; +2 more

Physical basis for materials synthesis using biomineralization

Technical Report · Tue May 16 00:00:00 EDT 2000 · OSTI ID:1438251

De Yoreo, J; Orme, C; Dove, P; +1 more

Related Subjects

36 MATERIALS SCIENCE

Title: Self-organizing layers from complex molecular anions

Citation Formats

References (80)

Cited By (12)

Similar Records

Related Subjects