An Ideal Molecular Sieve for Acetylene Removal from Ethylene with Record Selectivity and Productivity

Li, Bin; Cui, Xili; O'Nolan, Daniel; Wen, Hui-Min; Jiang, Mengdie; Krishna, Rajamani; Wu, Hui; Lin, Rui-Biao; Chen, Yu-Sheng; Yuan, Daqiang; Xing, Huabin; Zhou, Wei; Ren, Qilong; Qian, Guodong; Zaworotko, Michael J.; Chen, Banglin

doi:10.1002/adma.201704210

Title: An Ideal Molecular Sieve for Acetylene Removal from Ethylene with Record Selectivity and Productivity

Journal Article · Fri Nov 10 00:00:00 EST 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201704210· OSTI ID:1437455

Li, Bin ^[1]; Cui, Xili ^[2]; O'Nolan, Daniel ^[3]; Wen, Hui-Min ^[4]; Jiang, Mengdie ^[2]; Krishna, Rajamani ^[5]; Wu, Hui ^[6]; Lin, Rui-Biao ^[4]; Chen, Yu-Sheng ^[7]; Yuan, Daqiang ^[8]; Xing, Huabin ^[2]; Zhou, Wei ^[6]; Ren, Qilong ^[2]; Qian, Guodong ^[1]; Zaworotko, Michael J. ^[3];

^[9]

Zhejiang Univ., Hangzhou (China). State Key Lab. of Silicon Materials. Cyrus Tang Center for Sensor Materials and Applications. School of Materials Science and Engineering
Zhejiang Univ., Hangzhou (China). Key Lab. of Biomass Chemical Engineering of Ministry of Education. College of Chemical and Biological Engineering
Univ. of Limerick (Ireland). Bernal Inst. Dept. of Chemical Sciences
Univ. of Texas at San Antonio, TX (United States). Dept. of Chemistry
Univ. of Amsterdam (Netherlands). Van't Hoff Inst. for Molecular Sciences
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). NIST Center for Neutron Research
Univ. of Chicago, Argonne, IL (United States). ChemMatCARS. Center for Advanced Radiation Sources
Chinese Academy of Sciences (CAS), Fuzhou (China). State Key Lab. of Structure Chemistry. Fujian Inst. of Research on the Structure of Matter
Zhejiang Univ., Hangzhou (China). State Key Lab. of Silicon Materials. Cyrus Tang Center for Sensor Materials and Applications. School of Materials Science and Engineering; Univ. of Texas at San Antonio, TX (United States). Dept. of Chemistry

Realization of ideal molecular sieves, in which the larger gas molecules are completely blocked without sacrificing high adsorption capacities of the preferred smaller gas molecules, can significantly reduce energy costs for gas separation and purification and thus facilitate a possible technological transformation from the traditional energy-intensive cryogenic distillation to the energy-efficient, adsorbent-based separation and purification in the future. Although extensive research endeavors are pursued to target ideal molecular sieves among diverse porous materials, over the past several decades, ideal molecular sieves for the separation and purification of light hydrocarbons are rarely realized. Herein, an ideal porous material, SIFSIX-14-Cu-i (also termed as UTSA-200), is reported with ultrafine tuning of pore size (3.4 Å) to effectively block ethylene (C₂H₄) molecules but to take up a record-high amount of acetylene (C₂H₂, 58 cm³ cm^-3 under 0.01 bar and 298 K). The material therefore sets up new benchmarks for both the adsorption capacity and selectivity, and thus provides a record purification capacity for the removal of trace C₂H₂ from C₂H₄ with 1.18 mmol g^-1 C₂H₂ uptake capacity from a 1/99 C₂H₂/C₂H₄ mixture to produce 99.9999% pure C₂H₄ (much higher than the acceptable purity of 99.996% for polymer-grade C₂H₄), as demonstrated by experimental breakthrough curves.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC)

OSTI ID:: 1437455

Journal Information:: Advanced Materials, Vol. 29, Issue 47; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 222 works

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Current Status of Microporous Metal–Organic Frameworks for Hydrocarbon Separations Pei, Jiyan; Shao, Kai; Zhang, Ling Topics in Current Chemistry, Vol. 377, Issue 6 https://doi.org/10.1007/s41061-019-0257-0	journal	October 2019

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