Redox flow batteries having multiple electroactive elements

Wang, Wei; Li, Liyu; Yang, Zhenguo; Nie, Zimin

Title: Redox flow batteries having multiple electroactive elements

Patent · Tue May 01 00:00:00 EDT 2018

OSTI ID:1437259

Wang, Wei; Li, Liyu; Yang, Zhenguo; Nie, Zimin

Introducing multiple redox reactions with a suitable voltage range can improve the energy density of redox flow battery (RFB) systems. One example includes RFB systems utilizing multiple redox pairs in the positive half cell, the negative half cell, or in both. Such RFB systems can have a negative electrolyte, a positive electrolyte, and a membrane between the negative electrolyte and the positive electrolyte, in which at least two electrochemically active elements exist in the negative electrolyte, the positive electrolyte, or both.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 9,960,443

Application Number:: 13/246,444

OSTI ID:: 1437259

Resource Relation:: Patent File Date: 2011 Sep 27

Country of Publication:: United States

Language:: English

References (34)

Novel Vanadium Halide Redox Flow Battery Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100291420 US Patent Document 12/843521; 20100291420	patent-application	November 2010
Effects of additives on the stability of electrolytes for all-vanadium redox flow batteries Zhang, Jianlu; Li, Liyu; Nie, Zimin Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1215-1221 https://doi.org/10.1007/s10800-011-0312-1	journal	June 2011
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9123931 US Patent Document 9,123,931	patent	September 2015
Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries Kazacos, Maria Skyllas; Kazacos, Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6562514 US Patent Document 6,562,514	patent	May 2003
Redox Flow Batteries Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140234753 US Patent Document 14/261262; 20140234753	patent-application	August 2014
Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method Tanaka, Yasuyuki; Mita, Muneo; Horikawa, Ken https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6872376 US Patent Document 6,872,376	patent	March 2005
Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries Kazacos, George Christopher; Kazacos, Nicholas Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080292964 US Patent Document 11/917989; 20080292964	patent-application	November 2008
System Dongle Parakulam, Gopalakrishnan R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120040216 US Patent Document 12/855059; 20120040216	patent-application	February 2012
A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-Scale Energy Storage Li, Liyu; Kim, Soowhan; Wang, Wei Advanced Energy Materials, Vol. 1, Issue 3, p. 394-400 https://doi.org/10.1002/aenm.201100008	journal	March 2011
Flow Battery Systems Wilson, Gregory J.; Hanson, Kyle M. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120052347 US Patent Document 12/868489; 20120052347	patent-application	March 2012
Electrically rechargeable REDOX flow cell Thaller, Lawrence H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3996064 US Patent Document 3,996,064	patent	December 1976
Novel vanadium chloride/polyhalide redox flow battery Skyllas-Kazacos, Maria Journal of Power Sources, Vol. 124, Issue 1, p. 299-302 https://doi.org/10.1016/S0378-7753(03)00621-9	journal	October 2003
Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method Giner, Jose D.; Stark, Herbert https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4469760 US Patent Document 4,469,760	patent	September 1984
Novel vanadium halide redox flow battery Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholasl https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060183016 US Patent Document 10/548555; 20060183016	patent-application	August 2006
Metal halide redox flow battery Skyllas-Kazacos, Maria; Kazacos, Michael; Mousa, Asem https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050244707 US Patent Document 10/512417; 20050244707	patent-application	November 2005
Electrolyte for Redox Flow Battery and Redox Flow Battery Sekine, Ryojun; Dong, Yongrong; Kubata, Michiru https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150221969 US Patent Document 14/422792; 20150221969	patent-application	August 2015
Redox Flow Battery Based on Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150380757 US Patent Document 14/815037; 20150380757	patent	December 2015
All-vanadium redox battery Skyllas-Kazacos, Maria; Rychick, Miron; Robins, Robert R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4786567 US Patent Document 4,786,567	patent	November 1988
Investigation of the V(V)/V(IV) system for use in the positive half-cell of a redox battery Sum, E.; Rychcik, M.; Skyllas-kazacos, M. Journal of Power Sources, Vol. 16, Issue 2, p. 85-95 https://doi.org/10.1016/0378-7753(85)80082-3	journal	October 1985
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions Kazacos, Michael; Kazacos, Maria Skyllas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030143456 US Patent Document 10/226751; 20030143456	patent-application	July 2003
Redox Flow Battery System for Distributed Energy Storage Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110045332 US Patent Document 12/883511; 20110045332	patent-application	February 2011
Method for Storing Electrical Energy in Ionic Liquids Noack, Jens; Tubke, Jens; Pinkwart, Karsten https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120115069 US Patent Application 13/201813; 20120115069	patent-application	May 2012
Fe-V redox flow batteries Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8771856 US Patent Document 8,771,856	patent	July 2014
Vanadium/polyhalide redox flow battery Skyllas-Kazacos, Maria https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7320844 US Patent Document 7,320,844	patent	January 2008
Instrumented fluid-surfaced electrode Deane, Geoffrey F.; Ferren, Bran; Gates, William https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110027629 US Patent Document 12/803122; 20110027629	patent-application	February 2011
Redox Flow Batteries Based On Supporting Solutions Containing Chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140199607 US Patent Application 14/105823; 20140199607	patent-application	July 2014
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8628880 US Patent Document 8,628,880	patent	January 2014
Redox Flow Cell Rebalancing Keshavarz, Majid; Karuppaiah, Chockkalingam; Zu, Ge https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110086247 US Patent Document 12/790573; 20110086247	patent-application	April 2011
High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions Kazacos, Michael; Kazacos, Maria Skyllas https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7078123 US Patent Document 7,078,123	patent	July 2006
A study of the V(II)/V(III) redox couple for redox flow cell applications Sum, E.; Skyllas-Kazacos, M. Journal of Power Sources, Vol. 15, Issue 2-3, p. 179-190 https://doi.org/10.1016/0378-7753(85)80071-9	journal	June 1985
Electrolytes for redox flow batteries Nagashima, Ikuo; Fukui, Jun; Gotoh, Hidenori https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4814241 US Patent Document 4,814,241	patent	March 1989
Redox flow batteries based on supporting solutions containing chloride Li, Liyu; Kim, Soowhan; Yang, Zhenguo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9077011 US Patent Document 9,077,011	patent	July 2015
Redox Fuel Cell Boeke, Jan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3540933 US Patent Document 3,540,933	patent	November 1970
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011

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