Hydrodeoxygenation of phenolic compounds to cycloalkanes over supported nickel phosphides

Yu, Zhiquan; Wang, Anjie; Liu, Shan; Yao, Yunlong; Sun, Zhichao; Li, Xiang; Liu, Yingya; Wang, Yao; Camaioni, Donald M.; Lercher, Johannes A.

doi:10.1016/j.cattod.2018.05.012

Hydrodeoxygenation of phenolic compounds to cycloalkanes over supported nickel phosphides

Journal Article · Mon May 07 00:00:00 EDT 2018 · Catalysis Today

DOI:https://doi.org/10.1016/j.cattod.2018.05.012· OSTI ID:1437025

Yu, Zhiquan ^[1]; Wang, Anjie ^[1]; Liu, Shan ^[1]; Yao, Yunlong ^[1]; Sun, Zhichao ^[1]; Li, Xiang ^[1]; Liu, Yingya ^[1]; Wang, Yao ^[1]; Camaioni, Donald M. ^[2]; Lercher, Johannes A. ^[2]

Dalian Univ. of Technology, Dalian (China)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

SiO₂, HZSM-5 and Al₂O₃ were used to support nickel phosphides to prepare hydrodeoxygenation (HDO) catalysts. The nickel loading was kept at 20 wt% while the Ni/P molar ratio was varied among 3, 2, and 1 in the preparation by incipient wetness impregnation. XRD characterization revealed that Ni₃P, Ni₁₂P₅, and Ni₂P as the major crystal phases were obtained at Ni/P ratio of 3, 2, and 1, respectively, on SiO₂ and HZSM-5. When Al₂O₃ was used as the support, nickel metal rather than nickel phosphides was generated. Among SiO₂-supported nickel phosphides, Ni₃P exhibited highest hydrogenation activity and catalytic performance in phenol HDO. Ni₃P/HZSM-5 showed the high catalytic performance in HDO of phenol as well as catechol and o-cresol, with Ni₃P as the hydrogenation site and the acid sites in HZSM-5 zeolite as the dehydration site. In conclusion, the strong acidity in HZSM-5 also facilitated the isomerization of cycloalkanes at elevated temperatures.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1437025

Alternate ID(s):: OSTI ID: 1492704

Journal Information:: Catalysis Today, Journal Name: Catalysis Today Vol. 319; ISSN 0920-5861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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