Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium

Ziebel, Michael E.; Darago, Lucy E.; Long, Jeffrey R.

doi:10.1021/jacs.7b13510

Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium

Journal Article · Mon Feb 12 23:00:00 EST 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b13510· OSTI ID:1436795

Ziebel, Michael E. ^[1]; Darago, Lucy E. ^[1]; ^[2]

Department of Chemistry, University of California, Berkeley, California 94720, United States
Department of Chemistry, University of California, Berkeley, California 94720, United States; Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720, United States; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

Abstract not provided

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: National Science Foundation (NSF)

OSTI ID:: 1436795

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 8 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: ENGLISH

References (87)

The pervasive chemistry of metal–organic frameworks Long, Jeffrey R.; Yaghi, Omar M. Chemical Society Reviews, Vol. 38, Issue 5, p. 1213-1214 https://doi.org/10.1039/b903811f	journal	January 2009
A Room-Temperature Molecular/Organic-Based Magnet Manriquez, J. M.; Yee, G. T.; Mclean, R. S. Science, Vol. 252, Issue 5011 https://doi.org/10.1126/science.252.5011.1415	journal	June 1991
Coordination isomers of biological iron transport compounds. V. The preparation and chirality of the chromium(III) enterobactin complex and model tris(catechol)chromium(III) analogues Isied, Stephan S.; Kuo, Gilbert; Raymond, Kenneth N. Journal of the American Chemical Society, Vol. 98, Issue 7 https://doi.org/10.1021/ja00423a021	journal	March 1976
Efros-Shklovskii variable-range hopping in reduced graphene oxide sheets of varying carbon s p 2 fraction Joung, Daeha; Khondaker, Saiful I. Physical Review B, Vol. 86, Issue 23 https://doi.org/10.1103/PhysRevB.86.235423	journal	December 2012
Optical properties of the radical cation tetrathiafulvalenium (TT F + ) in its mixed-valence and monovalence halide salts Torrance, J. B.; Scott, B. A.; Welber, B. Physical Review B, Vol. 19, Issue 2 https://doi.org/10.1103/PhysRevB.19.730	journal	January 1979
Tetraoxolene radical stabilization by the interaction with transition-metal ions Dei, Andrea.; Gatteschi, Dante.; Pardi, Luca. Inorganic Chemistry, Vol. 30, Issue 12 https://doi.org/10.1021/ic00012a006	journal	June 1991
Electrochemical Techniques for Intercalation Electrode Materials in Rechargeable Batteries Zhu, Yujie; Gao, Tao; Fan, Xiulin Accounts of Chemical Research, Vol. 50, Issue 4 https://doi.org/10.1021/acs.accounts.7b00031	journal	February 2017
Electronic Transport in Organic Materials: Comparison of Band Theory with Percolation/(Variable Range) Hopping Theory Stallinga, P. Advanced Materials, Vol. 23, Issue 30 https://doi.org/10.1002/adma.201101129	journal	June 2011
Charge storage in doped poly(thiophene): Optical and electrochemical studies Chung, T. -C.; Kaufman, J. H.; Heeger, A. J. Physical Review B, Vol. 30, Issue 2 https://doi.org/10.1103/PhysRevB.30.702	journal	July 1984
Oliver Kahn Lecture: Composition and structure of the V[TCNE]x (TCNE=tetracyanoethylene) room-temperature, organic-based magnet – A personal perspective Miller, Joel S. Polyhedron, Vol. 28, Issue 9-10 https://doi.org/10.1016/j.poly.2008.11.030	journal	June 2009
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes Sathiya, M.; Rousse, G.; Ramesha, K. Nature Materials, Vol. 12, Issue 9 https://doi.org/10.1038/nmat3699	journal	July 2013
A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from T _c = 26 to 80 K Jeon, Ie-Rang; Negru, Bogdan; Van Duyne, Richard P. Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b10382	journal	December 2015
A Novel Hybrid Supramolecular Network Assembled from Perfect ??? Stacking of an Anionic Inorganic Layer and a Cationic Hydronium-Ion-Mediated Organic Layer Luo, Tzuoo-Tsair; Liu, Yen-Hsiang; Tsai, Hui-Lien European Journal of Inorganic Chemistry, Vol. 2004, Issue 21 https://doi.org/10.1002/ejic.200400199	journal	November 2004
Synthesis and Characterization of V ^V (3,6-DBSQ)(3,6-DBCat) ₂ , a d ⁰ Metal Complex with Dioxygenase Catalytic Activity Morris, Aimee M.; Pierpont, Cortlandt G.; Finke, Richard G. Inorganic Chemistry, Vol. 48, Issue 8 https://doi.org/10.1021/ic802122q	journal	March 2009
Monometallic Lanthanoid Assembly Showing Ferromagnetism with a Curie Temperature of 11 K Nakabayashi, Koji; Ohkoshi, Shin-ichi Inorganic Chemistry, Vol. 48, Issue 18 https://doi.org/10.1021/ic900625a	journal	September 2009
Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties Férey, Gérard; Millange, Franck; Morcrette, Mathieu Angewandte Chemie International Edition, Vol. 46, Issue 18 https://doi.org/10.1002/anie.200605163	journal	April 2007
Electrical conductivity, thermoelectric power, and ESR of a new family of molecular conductors, dicyanoquinonediimine-metal [(DCNQI ) 2 M] compounds Mori, Takehiko; Inokuchi, Hiroo; Kobayashi, Akiko Physical Review B, Vol. 38, Issue 9 https://doi.org/10.1103/PhysRevB.38.5913	journal	September 1988
π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet Kambe, Tetsuya; Sakamoto, Ryota; Hoshiko, Ken Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja312380b	journal	February 2013
Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2−) and the Significantly Stronger Coupling Chloranilate(•3−) Radical Trianion Min, Kil Sik; DiPasquale, Antonio G.; Golen, James A. Journal of the American Chemical Society, Vol. 129, Issue 8 https://doi.org/10.1021/ja067208q	journal	February 2007
Cu ₃ (hexaiminotriphenylene) ₂ : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F. Angewandte Chemie International Edition, Vol. 54, Issue 14 https://doi.org/10.1002/anie.201411854	journal	February 2015
Small polaron hopping in spinel manganates Schmidt, R.; Basu, A.; Brinkman, A. W. Physical Review B, Vol. 72, Issue 11 https://doi.org/10.1103/PhysRevB.72.115101	journal	September 2005
Electrically Conductive Porous Metal-Organic Frameworks Sun, Lei; Campbell, Michael G.; Dincă, Mircea Angewandte Chemie International Edition, Vol. 55, Issue 11 https://doi.org/10.1002/anie.201506219	journal	January 2016
Metal–Organic Frameworks (MOFs) Zhou, Hong-Cai “Joe”; Kitagawa, Susumu Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS90059F	journal	January 2014
Synthetic, structural, and physical studies of titanium complexes of catechol and 3,5-di-tert-butylcatechol Borgias, Brandan A.; Cooper, Stephen R.; Koh, Yun Bai Inorganic Chemistry, Vol. 23, Issue 8 https://doi.org/10.1021/ic00176a005	journal	April 1984
Perturbation calculation from the charge-transfer spectrum data of intervalence site-transfer D.C. conductivity in Prussian Blue England, Steven J.; Kathirgamanathan, Poopathy; Rosseinsky, David R. Journal of the Chemical Society, Chemical Communications, Issue 17 https://doi.org/10.1039/c39800000840	journal	January 1980
Six-Membered Electron Transfer Series [V(dithiolene) ₃ ] ^z ( z = 1+, 0, 1−, 2−, 3−, 4−). An X-ray Absorption Spectroscopic and Density Functional Theoretical Study Sproules, Stephen; Weyhermüller, Thomas; DeBeer, Serena Inorganic Chemistry, Vol. 49, Issue 11 https://doi.org/10.1021/ic100344f	journal	June 2010
Emerging Multifunctional Metal-Organic Framework Materials Li, Bin; Wen, Hui-Min; Cui, Yuanjing Advanced Materials, Vol. 28, Issue 40 https://doi.org/10.1002/adma.201601133	journal	July 2016
Characterization of the Chloranilate(•3−) π Radical as a Strong Spin-Coupling Bridging Ligand Min, Kil Sik; Rheingold, Arnold L.; DiPasquale, Antonio Inorganic Chemistry, Vol. 45, Issue 16 https://doi.org/10.1021/ic061076k	journal	August 2006
Optical transitions of symmetrical mixed-valence systems in the Class II–III transition regimeElectronic supplementary information (ESI) is available: derivation of eqn. (39c), table summarizing the relationships between band maxima and band widths predicted by the two-state model and table of spectral properties of mixed-valence ruthenium(II)/(III) bridged by pyrazine and dicyanamide. See http://www.rsc.org/suppdata/cs/b0/b008034i/ Brunschwig, Bruce S.; Creutz, Carol; Sutin, Norman Chemical Society Reviews, Vol. 31, Issue 3 https://doi.org/10.1039/b008034i	journal	April 2002
Mixed Valency in a 3D Semiconducting Iron–Fluoranilate Coordination Polymer Murase, Ryuichi; Abrahams, Brendan F.; D’Alessandro, Deanna M. Inorganic Chemistry, Vol. 56, Issue 15 https://doi.org/10.1021/acs.inorgchem.7b01038	journal	July 2017
Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3 Pearce, Paul E.; Perez, Arnaud J.; Rousse, Gwenaelle Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4864	journal	February 2017
Role of NEt ₄ ⁺ in Orienting and Locking Together [M ₂ lig ₃ ] ^2– (6,3) Sheets (H ₂ lig = Chloranilic or Fluoranilic Acid) to Generate Spacious Channels Perpendicular to the Sheets Kingsbury, Christopher J.; Abrahams, Brendan F.; D’Alessandro, Deanna M. Crystal Growth & Design, Vol. 17, Issue 4 https://doi.org/10.1021/acs.cgd.6b01886	journal	February 2017
Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane: M(TCNQ) ₂ (M = Mn, Fe, Co, Ni) ^† Clérac, Rodolphe; O'Kane, Shannon; Cowen, Jerry Chemistry of Materials, Vol. 15, Issue 9 https://doi.org/10.1021/cm021053d	journal	May 2003
Organic semiconductors: A theoretical characterization of the basic parameters governing charge transport Bredas, J. L.; Calbert, J. P.; da Silva Filho, D. A. Proceedings of the National Academy of Sciences, Vol. 99, Issue 9 https://doi.org/10.1073/pnas.092143399	journal	April 2002
The quest for magnets composed of vanadium and 1,4-benzoquinones Thorum, Mathew S.; Taliaferro, Michelle L.; Min, Kil Sik Polyhedron, Vol. 26, Issue 9-11 https://doi.org/10.1016/j.poly.2006.11.030	journal	June 2007
Microporous magnets Dechambenoit, Pierre; Long, Jeffrey R. Chemical Society Reviews, Vol. 40, Issue 6 https://doi.org/10.1039/c0cs00167h	journal	January 2011
New Porous Crystals of Extended Metal-Catecholates Hmadeh, Mohamad; Lu, Zheng; Liu, Zheng Chemistry of Materials, Vol. 24, Issue 18, p. 3511-3513 https://doi.org/10.1021/cm301194a	journal	August 2012
Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework Kobayashi, Yoji; Jacobs, Benjamin; Allendorf, Mark D. Chemistry of Materials, Vol. 22, Issue 14 https://doi.org/10.1021/cm101238m	journal	July 2010
Spin liquids in frustrated magnets Balents, Leon Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08917	journal	March 2010
Is iron unique in promoting electrical conductivity in MOFs? Sun, Lei; Hendon, Christopher H.; Park, Sarah S. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/C7SC00647K	journal	January 2017
Dihydroxybenzoquinone as Linker for the Synthesis of Permanently Porous Aluminum Metal–Organic Frameworks Halis, Selda; Inge, A. Ken; Dehning, Niklas Inorganic Chemistry, Vol. 55, Issue 15 https://doi.org/10.1021/acs.inorgchem.6b00661	journal	July 2016
Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium D'Alessandro, Deanna M.; Keene, F. Richard Chemical Reviews, Vol. 106, Issue 6 https://doi.org/10.1021/cr050010o	journal	June 2006
High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja502765n	journal	April 2014
Some electronic properties of the molybdenum bronzes Dickens, P. G.; Neild, D. J. Transactions of the Faraday Society, Vol. 64 https://doi.org/10.1039/tf9686400013	journal	January 1968
Variable Coordination Mode of Chloranilic Acid. Synthesis, Structure, and Electrochemical Properties of Some Osmium Complexes Gupta, Parna; Das, Anindya; Basuli, Falguni Inorganic Chemistry, Vol. 44, Issue 6 https://doi.org/10.1021/ic049149s	journal	March 2005
Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K. Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601 https://doi.org/10.1002/chem.201103433	journal	June 2012
A Family of Layered Chiral Porous Magnets Exhibiting Tunable Ordering Temperatures Atzori, Matteo; Benmansour, Samia; Mínguez Espallargas, Guillermo Inorganic Chemistry, Vol. 52, Issue 17 https://doi.org/10.1021/ic4013284	journal	August 2013
Mixed Valence Chemistry-A Survey and Classification Robin, Melvin B.; Day, Peter Advances in Inorganic Chemistry and Radiochemistry https://doi.org/10.1016/S0065-2792(08)60179-X	book	January 1968
Million-Fold Electrical Conductivity Enhancement in Fe ₂ (DEBDC) versus Mn ₂ (DEBDC) (E = S, O) Sun, Lei; Hendon, Christopher H.; Minier, Mikael A. Journal of the American Chemical Society, Vol. 137, Issue 19 https://doi.org/10.1021/jacs.5b02897	journal	May 2015
Spin Exchange Effects on the Physicochemical Properties of Tetraoxolene-Bridged Bimetallic Complexes Guo, Dong; McCusker, James K. Inorganic Chemistry, Vol. 46, Issue 8 https://doi.org/10.1021/ic070005y	journal	April 2007
Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework Clough, Andrew J.; Skelton, Jonathan M.; Downes, Courtney A. Journal of the American Chemical Society, Vol. 139, Issue 31 https://doi.org/10.1021/jacs.7b05742	journal	July 2017
Multistep redox series of the tris(o-semiquinone)chromium(III) complexes Downs, Hartley H.; Buchanan, Robert M.; Pierpont, Cortlandt G. Inorganic Chemistry, Vol. 18, Issue 7 https://doi.org/10.1021/ic50197a003	journal	July 1979
2D Conductive Iron-Quinoid Magnets Ordering up to T _c = 105 K via Heterogenous Redox Chemistry DeGayner, Jordan A.; Jeon, Ie-Rang; Sun, Lei Journal of the American Chemical Society, Vol. 139, Issue 11 https://doi.org/10.1021/jacs.7b00705	journal	March 2017
Preface: Forum on Redox-Active Ligands Chirik, Paul J. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic201881k	journal	October 2011
Polymerie 2,5-Dihydroxy-1,4-benzoquinone Transition Metal Complexes Na2(H2O)24[M2(C6H2O4)3] (M = Mn2+, Cd2+) Weiss, Armin; Riegler, Eugen; Robl, Christian Zeitschrift für Naturforschung B, Vol. 41, Issue 12 https://doi.org/10.1515/znb-1986-1204	journal	December 1986
Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity Erickson, Kristopher J.; Léonard, François; Stavila, Vitalie Advanced Materials, Vol. 27, Issue 22 https://doi.org/10.1002/adma.201501078	journal	April 2015
Über Oxycarbonsäure-titanate, Polyphenol-titanate und einige analoge Verbindungen. (VII. Mitteilung: Über die Molekularverbindungen anorganischer Halogenide) Rosenheim, Arthur; Sorge, Ottokar Berichte der deutschen chemischen Gesellschaft (A and B Series), Vol. 53, Issue 6 https://doi.org/10.1002/cber.19200530609	journal	June 1920
Transition metal complexes of o-benzoquinone, o-semiquinone, and catecholate ligands Pierpont, Cortlandt G.; Buchanan, Robert M. Coordination Chemistry Reviews, Vol. 38, Issue 1 https://doi.org/10.1016/S0010-8545(00)80499-3	journal	August 1981
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu Journal of the American Chemical Society, Vol. 134, Issue 31 https://doi.org/10.1021/ja3059827	journal	July 2012
A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour Huang, Xing; Sheng, Peng; Tu, Zeyi Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8408	journal	June 2015
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M. Journal of the American Chemical Society, Vol. 137, Issue 43 https://doi.org/10.1021/jacs.5b09600	journal	October 2015
Discovery of a Neutral-to-Ionic Phase Transition in Organic Materials Torrance, J. B.; Vazquez, J. E.; Mayerle, J. J. Physical Review Letters, Vol. 46, Issue 4 https://doi.org/10.1103/PhysRevLett.46.253	journal	January 1981
Intrinsically conducting metal–organic frameworks Leong, Chanel F.; Usov, Pavel M.; D’Alessandro, Deanna M. MRS Bulletin, Vol. 41, Issue 11 https://doi.org/10.1557/mrs.2016.241	journal	November 2016
Synthesis, crystal structure and electrochemistry of bis(N,N-dimethylammonium) tris(1,2-benzenedithiolato)titanate(IV) Könemann, Martin; Stüer, Wolfram; Kirschbaum, Kristin Polyhedron, Vol. 13, Issue 9 https://doi.org/10.1016/S0277-5387(00)81709-X	journal	May 1994
Electron Hopping Conduction in the Soliton Model of Polyacetylene Kivelson, S. Physical Review Letters, Vol. 46, Issue 20 https://doi.org/10.1103/PhysRevLett.46.1344	journal	May 1981
Conductive metal–organic frameworks and networks: fact or fantasy? Hendon, Christopher H.; Tiana, Davide; Walsh, Aron Physical Chemistry Chemical Physics, Vol. 14, Issue 38, p. 13120-13132 https://doi.org/10.1039/c2cp41099k	journal	January 2012
Theoretical study of o-quinone complexes of chromium and vanadium Gordon, Douglas J.; Fenske, Richard F. Inorganic Chemistry, Vol. 21, Issue 8 https://doi.org/10.1021/ic00138a001	journal	August 1982
Study of LiFePO[sub 4] by Cyclic Voltammetry Yu, Denis Y. W.; Fietzek, Christopher; Weydanz, Wolfgang Journal of The Electrochemical Society, Vol. 154, Issue 4 https://doi.org/10.1149/1.2434687	journal	January 2007
A Dual−Ion Battery Cathode via Oxidative Insertion of Anions in a Metal–Organic Framework Aubrey, Michael L.; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 137, Issue 42 https://doi.org/10.1021/jacs.5b08022	journal	October 2015
Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)- a Topology Abrahams, Brendan F.; Hudson, Timothy A.; McCormick, Laura J. Crystal Growth & Design, Vol. 11, Issue 7 https://doi.org/10.1021/cg2005908	journal	July 2011
Electronic Properties of Doped Semiconductors Shklovskii, Boris I.; Efros, Alex L. Springer Series in Solid-State Sciences https://doi.org/10.1007/978-3-662-02403-4	book	January 1984
Optical and conductive properties of pyrazine-bridged iron, ruthenium and osmium octaethylporphyrin coordination polymers Collman, James P.; McDevitt, John T.; Yee, Gordon T. Synthetic Metals, Vol. 15, Issue 2-3 https://doi.org/10.1016/0379-6779(86)90016-0	journal	July 1986
Electroconductive Porous Coordination Polymer Cu[Cu(pdt) ₂ ] Composed of Donor and Acceptor Building Units Takaishi, Shinya; Hosoda, Miyuki; Kajiwara, Takashi Inorganic Chemistry, Vol. 48, Issue 19 https://doi.org/10.1021/ic802117q	journal	October 2009
Superexchange metal-metal coupling in dinuclear pentaammineruthenium complexes incorporating a 1,4-dicyanamidobenzene dianion bridging ligand Aquino, M. A. S.; Lee, F. L.; Gabe, E. J. Journal of the American Chemical Society, Vol. 114, Issue 13 https://doi.org/10.1021/ja00039a026	journal	June 1992
Noninnocence in Metal Complexes: A Dithiolene Dawn Eisenberg, Richard; Gray, Harry B. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic2011748	journal	October 2011
Synthetic, structural, and physical studies of bis(triethylammonium) tris(catecholato)vanadate(IV), potassium bis(catecholato)oxovanadate(IV), and potassium tris(catecholato)vanadate (III) Cooper, Stephen R.; Koh, Yun Bai; Raymond, Kenneth N. Journal of the American Chemical Society, Vol. 104, Issue 19 https://doi.org/10.1021/ja00383a016	journal	September 1982
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks Park, Sarah S.; Hontz, Eric R.; Sun, Lei Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja512437u	journal	January 2015
Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator Kambe, Tetsuya; Sakamoto, Ryota; Kusamoto, Tetsuro Journal of the American Chemical Society, Vol. 136, Issue 41 https://doi.org/10.1021/ja507619d	journal	October 2014
Electronic Structure, Chemical Bonding, and Vibronic Coupling in Mn ^IV /Mn ^III Mixed Valent Li _x Mn ₂ O ₄ Spinels and Their Effect on the Dynamics of Intercalated Li: A Cluster Study Using DFT Atanasov, M.; Barras, J. -L.; Benco, L. Journal of the American Chemical Society, Vol. 122, Issue 19 https://doi.org/10.1021/ja9904484	journal	May 2000
Vibrational studies on electronic structures in metallic and insulating phases of the Cu complexes of substituted dicyanoquinonediimines (DCNQI). A comparison with the cases of the Li and Ba complexes Yamakita, Yoshihiro; Furukawa, Yukio; Kobayashi, Akiko The Journal of Chemical Physics, Vol. 100, Issue 4 https://doi.org/10.1063/1.466493	journal	February 1994
Mn ₂ (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) _∞ Chains and High Intrinsic Charge Mobility Sun, Lei; Miyakai, Tomoyo; Seki, Shu Journal of the American Chemical Society, Vol. 135, Issue 22 https://doi.org/10.1021/ja4037516	journal	May 2013
Electrical conductivity and electroluminescence of a new anthracene-based metal–organic framework with π-conjugated zigzag chains Chen, Dashu; Xing, Hongzhu; Su, Zhongmin Chemical Communications, Vol. 52, Issue 10 https://doi.org/10.1039/C5CC09065B	journal	January 2016
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C. Science, Vol. 343, Issue 6166, p. 66-69 https://doi.org/10.1126/science.1246738	journal	December 2013
Conduction in non-crystalline materials: III. Localized states in a pseudogap and near extremities of conduction and valence bands Mott, N. F. Philosophical Magazine, Vol. 19, Issue 160 https://doi.org/10.1080/14786436908216338	journal	April 1969
Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b10385	journal	December 2015
The organic π-electron metal system with interaction through mixed-valence metal cation: Electronic and structural properties of radical salts of dicyano-quinodiimine, (DMe-DCNQI)2Cu and (MeCl-DCNQI)2Cu Kobayashi, A.; Kato, R.; Kobayashi, H. Solid State Communications, Vol. 64, Issue 1 https://doi.org/10.1016/0038-1098(87)90517-5	journal	October 1987
Electrical switching and memory phenomena in Cu‐TCNQ thin films Potember, R. S.; Poehler, T. O.; Cowan, D. O. Applied Physics Letters, Vol. 34, Issue 6 https://doi.org/10.1063/1.90814	journal	March 1979

Cited By (15)

Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles Su, Jian; Yuan, Shuai; Wang, Tao Chemical Science, Vol. 11, Issue 7 https://doi.org/10.1039/c9sc06009j	journal	January 2020
Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds Xie, Jiaze; Boyn, Jan-Niklas; Filatov, Alexander S. Chemical Science, Vol. 11, Issue 4 https://doi.org/10.1039/c9sc04381k	journal	January 2020
Two-dimensional magnetic materials of cobalt( ii ) triangular lattices constructed by a mixed benzimidazole–dicarboxylate strategy Kong, Jiao-Jiao; Jiang, Yu-Xuan; Zhang, Jia-Chen CrystEngComm, Vol. 21, Issue 15 https://doi.org/10.1039/c9ce00129h	journal	January 2019
Square Grid Metal–Chloranilate Networks as Robust Host Systems for Guest Sorption Kingsbury, Christopher J.; Abrahams, Brendan F.; Auckett, Josie E. Chemistry – A European Journal, Vol. 25, Issue 20 https://doi.org/10.1002/chem.201805600	journal	March 2019
A Series of Early Lanthanide Chloranilate Frameworks with a Square Grid Topology Hua, Carol; Tay, Hui Min; He, Qilin Australian Journal of Chemistry, Vol. 72, Issue 10 https://doi.org/10.1071/ch19193	journal	January 2019
Coordination‐driven self‐assembly of Cp*Rh‐Based Rectangles, Cages and Their Host−Guest Binding Study Lin, Lin; Lin, Yue‐Jian; Jin, Guo‐Xin Applied Organometallic Chemistry, Vol. 33, Issue 7 https://doi.org/10.1002/aoc.4926	journal	April 2019
Synthetic investigation of competing magnetic interactions in 2D metal–chloranilate radical frameworks Collins, Kelsey A.; Saballos, Richard J.; Fataftah, Majed S. Chemical Science https://doi.org/10.1039/d0sc01994a	journal	January 2020
Theoretical discovery of Dirac half metal in experimentally synthesized two dimensional metal semiquinoid frameworks Tang, Cheng; Zhang, Chunmei; Jiang, Zhenyi Journal of Materials Chemistry C, Vol. 7, Issue 19 https://doi.org/10.1039/c9tc01134j	journal	January 2019
Conductive two-dimensional metal–organic frameworks as multifunctional materials Ko, Michael; Mendecki, Lukasz; Mirica, Katherine A. Chemical Communications, Vol. 54, Issue 57 https://doi.org/10.1039/c8cc02871k	journal	January 2018
Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks Skorupskii, Grigorii; Trump, Benjamin A.; Kasel, Thomas W. Nature Chemistry, Vol. 12, Issue 2 https://doi.org/10.1038/s41557-019-0372-0	journal	November 2019
A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4+4] metallocycles Sutton, Ashley L.; Abrahams, Brendan F.; Hudson, Timothy A. New Journal of Chemistry, Vol. 44, Issue 27 https://doi.org/10.1039/d0nj02413a	journal	January 2020
Recent Development and Application of Conductive MOFs Li, Pengfei; Wang, Bo Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800078	journal	August 2018
Coordination polymer-based conductive materials: ionic conductivity vs. electronic conductivity Wang, Hai-Ning; Meng, Xing; Dong, Long-Zhang Journal of Materials Chemistry A, Vol. 7, Issue 42 https://doi.org/10.1039/c9ta08253k	journal	January 2019
Redox-active metal–organic frameworks for energy conversion and storage Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta04680a	journal	January 2019
Reversible redox switching of magnetic order and electrical conductivity in a 2D manganese benzoquinoid framework Liu, Lujia; DeGayner, Jordan A.; Sun, Lei Chemical Science, Vol. 10, Issue 17 https://doi.org/10.1039/c9sc00606k	journal	January 2019

Similar Records

Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium

Journal Article · Sun Feb 04 23:00:00 EST 2018 · Journal of the American Chemical Society · OSTI ID:1460997

Two-dimensional, conductive niobium and molybdenum metal-organic frameworks

Journal Article · Thu Sep 03 00:00:00 EDT 2020 · Chem. Sci. · OSTI ID:1659291

Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal Organic Framework

Journal Article · Thu Nov 10 23:00:00 EST 2016 · Journal of the American Chemical Society · OSTI ID:1238293

Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium

Citation Formats

References (87)

Cited By (15)

Similar Records

Related Subjects