A vacuum ultraviolet photoionization study on the thermal decomposition of ammonium perchlorate

Gobi, Sandor; Zhao, Long; Xu, Bo; Ablikim, Utuq; Ahmed, Musahid; Kaiser, Ralf I.

doi:10.1016/j.cplett.2017.11.026

Title: A vacuum ultraviolet photoionization study on the thermal decomposition of ammonium perchlorate

Journal Article · Tue Nov 14 00:00:00 EST 2017 · Chemical Physics Letters

DOI:https://doi.org/10.1016/j.cplett.2017.11.026· OSTI ID:1436661

Gobi, Sandor ^[1]; Zhao, Long ^[1]; Xu, Bo ^[2]; Ablikim, Utuq ^[2]; Ahmed, Musahid ^[2]; Kaiser, Ralf I. ^[1]

University of Hawaii at Manoa, Honolulu, HI (United States). Dept. of Chemistry and W.M. Keck Lab. in Astrochemistry
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Chemical Sciences Division

Pyrolysis products of ammonium perchlorate (NH₄ClO₄) at 483 K were monitored on line and in situ via single photon photoionization reflectron time-of-flight spectrometry (PI-ReTOF-MS) in the photon energy range of 9.00–17.50 eV. The photoionization efficiency curves (PIE) of the subliming product molecules were collected and allowed for detection of three class of products containing chlorine, nitrogen, and oxygen including atoms and free radicals. The results found suggest a new insight into possible low-temperature decomposition pathways of NH₄ClO₄.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; US Department of the Navy, Office of Naval Research (ONR)

Grant/Contract Number:: AC02-05CH11231; N00014-16-1-2078

OSTI ID:: 1436661

Alternate ID(s):: OSTI ID: 1576823

Journal Information:: Chemical Physics Letters, Vol. 691, Issue C; ISSN 0009-2614

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 14 works

Citation information provided by
Web of Science

References (43)

Thermal decomposition of ammonium perchlorate Boldyrev, V. V. Thermochimica Acta, Vol. 443, Issue 1 https://doi.org/10.1016/j.tca.2005.11.038	journal	April 2006
DISSOCIATION PRESSURE OF AMMONIUM PERCHLORATE ¹ Inami, S. Henry; Rosser, Willis A.; Wise, Henry The Journal of Physical Chemistry, Vol. 67, Issue 5 https://doi.org/10.1021/j100799a032	journal	May 1963
Decomposition and combustion of ammonium perchlorate Jacobs, Patrick William McCarthy; Whitehead, H. M. Chemical Reviews, Vol. 69, Issue 4 https://doi.org/10.1021/cr60260a005	journal	August 1969
Mechanism of the decomposition of ammonium perchlorate Jacobs, P. W. M.; Pearson, G. S. Combustion and Flame, Vol. 13, Issue 4 https://doi.org/10.1016/0010-2180(69)90112-6	journal	August 1969
Thermal decomposition of ammonium perchlorate Keenan, A. G.; Siegmund, Robert F. Quarterly Reviews, Chemical Society, Vol. 23, Issue 3 https://doi.org/10.1039/qr9692300430	journal	January 1969
Studies on energetic compounds Singh, Gurdip; Kapoor, Inder Pal Singh; Mannan, S. Mudi Journal of Hazardous Materials, Vol. 79, Issue 1-2 https://doi.org/10.1016/S0304-3894(00)00159-X	journal	December 2000
Mass spectrometric study of the thermal decomposition of ammonium perchlorate Heath, G. A.; Majer, J. R. Transactions of the Faraday Society, Vol. 60 https://doi.org/10.1039/tf9646001783	journal	January 1964
Mass‐Spectrometric Study of the Thermal Decomposition of Ammonium Perchlorate Maycock, J. N.; Verneker, V. R. Pai; Jacobs, P. W. M. The Journal of Chemical Physics, Vol. 46, Issue 7 https://doi.org/10.1063/1.1841138	journal	April 1967
Thermal decomposition of ammonium perchlorate Rosser, W. A.; Inami, S. H.; Wise, H. Combustion and Flame, Vol. 12, Issue 5 https://doi.org/10.1016/0010-2180(68)90054-0	journal	October 1968
Role of the Scanning Electron Microscope in the Study of Solid Rocket Propel I ant Combustion, I. Ammonium Perchlorate Decomposition and Deflagration Boggs, T. L.; Kraeutle, K. J. Combustion Science and Technology, Vol. 1, Issue 2 https://doi.org/10.1080/00102206908952192	journal	September 1969
The Thermal Decomposition of Orthorhombic Ammonium Perchlorate Single Crystals Kraeutle, K. J. The Journal of Physical Chemistry, Vol. 74, Issue 6 https://doi.org/10.1021/j100701a033	journal	March 1970
Application of Internal Reflectance Spectroscopy to the Study of Solid Propellant: II. Thermal Decomposition of Ammonium Perchlorate Dauerman, Leonard; Kimmel, Howard; Wu, Y. J. Combustion Science and Technology, Vol. 5, Issue 1 https://doi.org/10.1080/00102207208952513	journal	March 1972
On the mechanism of the thermal decomposition of ammonium perchlorate Boldyrev, V. V.; Alexandrov, V. V.; Boldyreva, A. V. Combustion and Flame, Vol. 15, Issue 1 https://doi.org/10.1016/S0010-2180(70)80066-9	journal	August 1970
Detection of species resulting from condensed phase decomposition of ammonium perchlorate Hackman, E. Ellsworth; Hesser, Henry H.; Beachell, Harold C. The Journal of Physical Chemistry, Vol. 76, Issue 24 https://doi.org/10.1021/j100668a006	journal	November 1972
Laser Raman study of the thermal decomposition of solid NH ₄ ClO ₄ Brill, T. B.; Goetz, F. The Journal of Chemical Physics, Vol. 65, Issue 3 https://doi.org/10.1063/1.433147	journal	August 1976
Ammonium perchlorate decomposition: Neat and solution ¹ Oxley, J. C.; Smith, J. L.; Valenzuela, B. R. Journal of Energetic Materials, Vol. 13, Issue 1-2 https://doi.org/10.1080/07370659508019344	journal	March 1995
Low-temperature thermal decomposition of large single crystals of ammonium perchlorate Majda, Dorota; Korobov, Alexander; Filek, Urszula Chemical Physics Letters, Vol. 454, Issue 4-6 https://doi.org/10.1016/j.cplett.2008.02.016	journal	March 2008
Low-temperature thermal decomposition of crystalline partly and completely deuterated ammonium perchlorate Majda, Dorota; Korobov, Alexander; Filek, Urszula Chemical Physics Letters, Vol. 504, Issue 4-6 https://doi.org/10.1016/j.cplett.2011.01.069	journal	March 2011
Kinetics of Thermal Decomposition of Ammonium Perchlorate by TG/DSC-MS-FTIR Zhu, Yan-Li; Huang, Hao; Ren, Hui Journal of Energetic Materials, Vol. 32, Issue 1 https://doi.org/10.1080/07370652.2012.725453	journal	July 2013
Thermal decomposition of ammonium perchlorate—A TGA–FTIR–MS study: Part I Mallick, Lovely; Kumar, Sudarshan; Chowdhury, Arindrajit Thermochimica Acta, Vol. 610 https://doi.org/10.1016/j.tca.2015.04.025	journal	June 2015
Thermal decomposition of ammonium perchlorate—A TGA-FTIR-MS study: Part II Mallick, Lovely; Kumar, Sudarshan; Chowdhury, Arindrajit Thermochimica Acta, Vol. 653 https://doi.org/10.1016/j.tca.2017.04.004	journal	July 2017
Electron Radiolysis of Ammonium Perchlorate: A Reflectron Time-of-Flight Mass Spectrometric Study Góbi, Sándor; Bergantini, Alexandre; Turner, Andrew M. The Journal of Physical Chemistry A, Vol. 121, Issue 20 https://doi.org/10.1021/acs.jpca.7b01862	journal	May 2017
Ab initio chemical kinetics for ClO reactions with HOx, ClOx and NOx (x=1,2): A review Zhu, R. S.; Lin, M. C. Computational and Theoretical Chemistry, Vol. 965, Issue 2-3 https://doi.org/10.1016/j.comptc.2010.12.002	journal	May 2011
Ab Initio Studies of ClO _x Reactions. 2. Unimolecular Decomposition of s-ClO ₃ and the Bimolecular O + OClO Reaction Zhu, R. S.; Lin, M. C. The Journal of Physical Chemistry A, Vol. 106, Issue 36 https://doi.org/10.1021/jp020015e	journal	April 2002
Ab initio studies of ClOx reactions. VIII. Isomerization and decomposition of ClO2 radicals and related bimolecular processes Zhu, R. S.; Lin, M. C. The Journal of Chemical Physics, Vol. 119, Issue 4 https://doi.org/10.1063/1.1585027	journal	July 2003
Ab Initio/RRKM Study of the O( ¹ D) + NH ₃ Reaction: Prediction of Product Branching Ratios Wang, Ling; Mebel, Alexander M.; Yang, Xueming The Journal of Physical Chemistry A, Vol. 108, Issue 52 https://doi.org/10.1021/jp0458452	journal	December 2004
Computational Studies on the Kinetics and Mechanisms for NH ₃ Reactions with ClO _x ( x = 0−4) Radicals Xu, Z. F.; Lin, M. C. The Journal of Physical Chemistry A, Vol. 111, Issue 4 https://doi.org/10.1021/jp065397t	journal	February 2007
A quantum statistical analysis of the rate constant for the HO2 + NH2 reaction Sumathi, R.; Peyerimhoff, S. D. Chemical Physics Letters, Vol. 263, Issue 6 https://doi.org/10.1016/S0009-2614(96)01283-3	journal	December 1996
Ab Initio Study of the ClO + NH ₂ Reaction: Prediction of the Total Rate Constant and Product Branching Ratios ^† Zhu, R. S.; Lin, M. C. The Journal of Physical Chemistry A, Vol. 111, Issue 19 https://doi.org/10.1021/jp067178d	journal	May 2007
Energetics of ammonium perchlorate decomposition steps Politzer, Peter; Lane, Pat Journal of Molecular Structure: THEOCHEM, Vol. 454, Issue 2-3 https://doi.org/10.1016/S0166-1280(98)00293-0	journal	November 1998
Application of Reflectron Time-of-Flight Mass Spectroscopy in the Analysis of Astrophysically Relevant Ices Exposed to Ionization Radiation: Methane (CH ₄ ) and D4-Methane (CD ₄ ) as a Case Study Jones, Brant M.; Kaiser, Ralf I. The Journal of Physical Chemistry Letters, Vol. 4, Issue 11 https://doi.org/10.1021/jz400692r	journal	May 2013
ON THE FORMATION AND ISOMER SPECIFIC DETECTION OF PROPENAL (C ₂ H ₃ CHO) AND CYCLOPROPANONE (c-C ₃ H ₄ O) IN INTERSTELLAR MODEL ICES—A COMBINED FTIR AND REFLECTRON TIME-OF-FLIGHT MASS SPECTROSCOPIC STUDY Abplanalp, Matthew J.; Borsuk, Aleca; Jones, Brant M. The Astrophysical Journal, Vol. 814, Issue 1 https://doi.org/10.1088/0004-637X/814/1/45	journal	November 2015
IN SITU DETECTION OF CHLORINE DIOXIDE (ClO ₂ ) IN THE RADIOLYSIS OF PERCHLORATES AND IMPLICATIONS FOR THE STABILITY OF ORGANICS ON MARS Góbi, Sándor; Bergantini, Alexandre; Kaiser, Ralf I. The Astrophysical Journal, Vol. 832, Issue 2 https://doi.org/10.3847/0004-637X/832/2/164	journal	November 2016
Evidence for perchlorates and the origin of chlorinated hydrocarbons detected by SAM at the Rocknest aeolian deposit in Gale Crater: EVIDENCE FOR PERCHLORATES AT ROCKNEST Glavin, Daniel P.; Freissinet, Caroline; Miller, Kristen E. Journal of Geophysical Research: Planets, Vol. 118, Issue 10 https://doi.org/10.1002/jgre.20144	journal	October 2013
Volatile, Isotope, and Organic Analysis of Martian Fines with the Mars Curiosity Rover Leshin, L. A.; Mahaffy, P. R.; Webster, C. R. Science, Vol. 341, Issue 6153 https://doi.org/10.1126/science.1238937	journal	September 2013
On the formation of nitrogen-substituted polycyclic aromatic hydrocarbons (NPAHs) in circumstellar and interstellar environments Parker, Dorian S. N.; Kaiser, Ralf I. Chemical Society Reviews, Vol. 46, Issue 2 https://doi.org/10.1039/C6CS00714G	journal	January 2017
ZEKE-PEPICO investigations of dissociation energies in ionic reactions Weitzel, Karl-Michael; Mähnert, Joachim; Penno, Martin Chemical Physics Letters, Vol. 224, Issue 3-4 https://doi.org/10.1016/0009-2614(94)00567-2	journal	July 1994
Recent Applications of Synchrotron VUV Photoionization Mass Spectrometry: Insight into Combustion Chemistry Li, Yuyang; Qi, Fei Accounts of Chemical Research, Vol. 43, Issue 1 https://doi.org/10.1021/ar900130b	journal	January 2010
Isomeric identification of polycyclic aromatic hydrocarbons formed in combustion with tunable vacuum ultraviolet photoionization Qi, Fei; Yang, Rui; Yang, Bin Review of Scientific Instruments, Vol. 77, Issue 8 https://doi.org/10.1063/1.2234855	journal	August 2006
Combustion chemistry probed by synchrotron VUV photoionization mass spectrometry Qi, Fei Proceedings of the Combustion Institute, Vol. 34, Issue 1 https://doi.org/10.1016/j.proci.2012.09.002	journal	January 2013
Studies of a fuel-rich propane flame with photoionization mass spectrometry Cool, Terrill A.; Nakajima, Koichi; Taatjes, Craig A. Proceedings of the Combustion Institute, Vol. 30, Issue 1 https://doi.org/10.1016/j.proci.2004.08.103	journal	January 2005
Photoionization cross sections for reaction intermediates in hydrocarbon combustion Cool, Terrill A.; Wang, Juan; Nakajima, Koichi International Journal of Mass Spectrometry, Vol. 247, Issue 1-3 https://doi.org/10.1016/j.ijms.2005.08.018	journal	December 2005
Combustion of butanol isomers – A detailed molecular beam mass spectrometry investigation of their flame chemistry Oßwald, Patrick; Güldenberg, Hanna; Kohse-Höinghaus, Katharina Combustion and Flame, Vol. 158, Issue 1 https://doi.org/10.1016/j.combustflame.2010.06.003	journal	January 2011

Cited By (4)

Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface Komorek, R.; Xu, B.; Yao, J. Review of Scientific Instruments, Vol. 89, Issue 11 https://doi.org/10.1063/1.5048315	journal	November 2018
Thermal decomposition of energetic materials using TG-FTIR and TG-MS: a state-of-the-art review Benhammada, Abdenacer; Trache, Djalal Applied Spectroscopy Reviews, Vol. 55, Issue 8 https://doi.org/10.1080/05704928.2019.1679825	journal	October 2019
Constraining the Molecular Complexity in the Interstellar Medium—The Formation of Ethyl Methyl Ether (CH ₃ OCH ₂ CH ₃ ) in Star-forming Regions Bergantini, Alexandre; Frigge, Robert; Kaiser, Ralf I. The Astrophysical Journal, Vol. 859, Issue 1 https://doi.org/10.3847/1538-4357/aabc52	journal	May 2018
Porous Cr ₂ O ₃ bead with a 3D continuous pore architecture: synthesis and its catalytic performance for decomposition of ammonium perchlorate Wang, Dakang; Jiang, Yanqiu; Hu, Yinghui New Journal of Chemistry, Vol. 43, Issue 26 https://doi.org/10.1039/c9nj01025d	journal	January 2019

Similar Records

A vacuum ultraviolet photoionization study on high-temperature decomposition of JP-10 (exo-tetrahydrodicyclopentadiene)

Journal Article · Fri May 05 00:00:00 EDT 2017 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1436661

Zhao, Long; Yang, Tao; Kaiser, Ralf I.; +9 more

Degradation of Adenine on the Martian Surface in the Presence of Perchlorates and Ionizing Radiation: A Reflectron Time-of-flight Mass Spectrometric Study

Journal Article · Sat Apr 01 00:00:00 EDT 2017 · Astrophysical Journal · OSTI ID:1436661

Góbi, Sándor; Bergantini, Alexandre

In situ detection of chlorine dioxide (clo{sub 2}) in the radiolysis of perchlorates and implications for the stability of organics on mars

Journal Article · Thu Dec 01 00:00:00 EST 2016 · Astrophysical Journal · OSTI ID:1436661

Góbi, Sándor; Bergantini, Alexandre

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: A vacuum ultraviolet photoionization study on the thermal decomposition of ammonium perchlorate

Citation Formats

References (43)

Cited By (4)

Similar Records

Related Subjects