Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors

Lustig, William P.; Wang, Fangming; Teat, Simon J.; Hu, Zhichao; Gong, Qihan; Li, Jing

doi:10.1021/acs.inorgchem.6b00897

Chromophore-Based Luminescent Metal–Organic Frameworks as Lighting Phosphors

Journal Article · Tue May 31 00:00:00 EDT 2016 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b00897· OSTI ID:1436596

Lustig, William P. ^[1]; Wang, Fangming ^[1]; Teat, Simon J. ^[2]; Hu, Zhichao ^[1]; Gong, Qihan ^[1]; Li, Jing ^[1]

Rutgers Univ., Piscataway, NJ (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Here, energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecule s.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1436596

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 15 Vol. 55; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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