Best practices in evaluation of the magnetocaloric effect from bulk magnetization measurements

Neves Bez, H.; Yibole, H.; Pathak, A.; Mudryk, Y.; Pecharsky, V. K.

doi:10.1016/j.jmmm.2018.03.020

Title: Best practices in evaluation of the magnetocaloric effect from bulk magnetization measurements

Journal Article · Sun Jul 15 00:00:00 EDT 2018 · Journal of Magnetism and Magnetic Materials

DOI:https://doi.org/10.1016/j.jmmm.2018.03.020· OSTI ID:1436429

Neves Bez, H. ^[1]; Yibole, H. ^[2]; Pathak, A. ^[2]; Mudryk, Y. ^[2]; Pecharsky, V. K. ^[3]

Ames Lab. and Iowa State Univ., Ames, IA (United States); Federal Univ. of Santa Catarina (UFSC), Florianopolis, SC (Brazil). Polo – Research Lab. for Emerging Technologies in Cooling and Thermophysics, Dept. of Mechanical Engineering
Ames Lab. and Iowa State Univ., Ames, IA (United States)
Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering

Conventional magnetometry is irreplaceable in evaluating bulk magnetization of materials over broad temperature and field ranges. The technique is also effective in quantifying hysteresis that may be associated with magnetic and structural phase transitions that occur during the magnetizing/demagnetizing cycling, and the derived magnetic field-induced isothermal entropy change – one of the most important properties in the field of magnetocalorics. Both systematic and random errors present during the measurements of magnetization, however, may lead to erroneous conclusions. Using two well-known materials – elemental Gd and intermetallic Gd₅Si₂Ge₂ as examples, we consider best practices in performing reliable and rapid magnetization measurements for proper characterization of magnetocaloric properties.

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Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1436429

Report Number(s):: IS-J-9651; PII: S0304885317336211

Journal Information:: Journal of Magnetism and Magnetic Materials, Vol. 458, Issue C; ISSN 0304-8853

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 39 works

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References (29)

Entropy changes associated with the first-order magnetic transition in LaFe13−xSix Jia, L.; Liu, G. J.; Sun, J. R. Journal of Applied Physics, Vol. 100, Issue 12 https://doi.org/10.1063/1.2404468	journal	December 2006
Magnetic field dependence of the maximum magnetic entropy change Lyubina, Julia; Kuz’min, Michael D.; Nenkov, Konstantin Physical Review B, Vol. 83, Issue 1 https://doi.org/10.1103/PhysRevB.83.012403	journal	January 2011
The spike in the relation between entropy change and temperature in LaFe11.83Si1.17 compound Zhang, Hong-wei; Shen, Jun; Dong, Qiao-yan Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 13 https://doi.org/10.1016/j.jmmm.2008.02.128	journal	July 2008
Magnetocaloric effect from indirect measurements: Magnetization and heat capacity Pecharsky, V. K.; Gschneidner, K. A. Journal of Applied Physics, Vol. 86, Issue 1 https://doi.org/10.1063/1.370767	journal	July 1999
On the determination of the magnetic entropy change in materials with first-order transitions Caron, L.; Ou, Z. Q.; Nguyen, T. T. Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 21 https://doi.org/10.1016/j.jmmm.2009.06.086	journal	November 2009
Material properties and modeling characteristics for MnFeP1−xAsx materials for application in magnetic refrigeration Engelbrecht, K.; Nielsen, K. K.; Bahl, C. R. H. Journal of Applied Physics, Vol. 113, Issue 17 https://doi.org/10.1063/1.4803495	journal	May 2013
A detailed study of the hysteresis in La0.67Ca0.33MnO3 Bez, Henrique N.; Nielsen, Kaspar K.; Smith, Anders Journal of Magnetism and Magnetic Materials, Vol. 416 https://doi.org/10.1016/j.jmmm.2016.05.011	journal	October 2016
Magneto-elastic coupling in La(Fe, Mn, Si) ₁₃ H _y within the Bean-Rodbell model Bez, Henrique N.; Nielsen, Kaspar K.; Norby, Poul AIP Advances, Vol. 6, Issue 5 https://doi.org/10.1063/1.4944400	journal	May 2016
Modeling of Thermomagnetic Phenomena in Active Magnetocaloric Regenerators Trevizoli, Paulo V.; Barbosa, Jader R.; Tura, Armando Journal of Thermal Science and Engineering Applications, Vol. 6, Issue 3 https://doi.org/10.1115/1.4026814	journal	April 2014
Experimental and numerical results of a high frequency rotating active magnetic refrigerator Lozano, J. A.; Engelbrecht, K.; Bahl, C. R. H. International Journal of Refrigeration, Vol. 37 https://doi.org/10.1016/j.ijrefrig.2013.09.002	journal	January 2014
A model description of the first-order phase transition in MnFeP1−xAsx Tegus, O.; Lin, G. X.; Dagula, W. Journal of Magnetism and Magnetic Materials, Vol. 290-291 https://doi.org/10.1016/j.jmmm.2004.11.325	journal	April 2005
The room temperature metastable/stable phase relationships in the pseudo-binary Gd5Si4–Gd5Ge4 system Pecharsky, A. O.; Gschneidner, K. A.; Pecharsky, V. K. Journal of Alloys and Compounds, Vol. 338, Issue 1-2 https://doi.org/10.1016/S0925-8388(02)00226-8	journal	May 2002
Origin of Hysteresis in La _0.67 Ca _0.33 MnO ₃ Morrison, K.; Berenov, A.; Cohen, Lf MRS Proceedings, Vol. 1310 https://doi.org/10.1557/opl.2011.590	journal	January 2011
Reducing extrinsic hysteresis in first-order La(Fe,Co,Si)13 magnetocaloric systems Moore, J. D.; Morrison, K.; Sandeman, K. G. Applied Physics Letters, Vol. 95, Issue 25 https://doi.org/10.1063/1.3276565	journal	December 2009
Magnetic properties of Gd5(Si1.5Ge2.5) near the temperature and magnetic field induced first order phase transition Levin, E. M.; Gschneidner, K. A.; Pecharsky, V. K. Journal of Magnetism and Magnetic Materials, Vol. 231, Issue 2-3 https://doi.org/10.1016/S0304-8853(01)00154-8	journal	June 2001
Field-induced magnetostructural transition in ${Gd}_{5} {Ge}_{4}$ studied by pulsed magnetic fields Ouyang, Z. W.; Nojiri, H.; Yoshii, S. Physical Review B, Vol. 77, Issue 18 https://doi.org/10.1103/PhysRevB.77.184426	journal	May 2008
Consequences of the magnetocaloric effect on magnetometry measurements Hansen, B. R.; Bahl, C. R. H.; Kuhn, L. Theil Journal of Applied Physics, Vol. 108, Issue 4 https://doi.org/10.1063/1.3466977	journal	August 2010
Avalanche-like metamagnetic transition in (LaNd)CaMnO manganites Ghivelder, L.; Eslava, G. G.; Freitas, R. S. Journal of Alloys and Compounds, Vol. 680 https://doi.org/10.1016/j.jallcom.2016.04.152	journal	September 2016
Avalanche like field dependent magnetization of Mn-site doped charge-ordered manganites Hébert, S.; Maignan, A.; Hardy, V. Solid State Communications, Vol. 122, Issue 6 https://doi.org/10.1016/S0038-1098(02)00089-3	journal	May 2002
Dynamic behavior of magnetic avalanches in the spin-ice compound ${Dy}_{2} {Ti}_{2} O_{7}$ Jackson, M. J.; Lhotel, E.; Giblin, S. R. Physical Review B, Vol. 90, Issue 6 https://doi.org/10.1103/PhysRevB.90.064427	journal	August 2014
Demagnetizing factors for rectangular ferromagnetic prisms Aharoni, Amikam Journal of Applied Physics, Vol. 83, Issue 6 https://doi.org/10.1063/1.367113	journal	March 1998
Magnetic Disorder as a First-Order Phase Transformation Bean, C. P.; Rodbell, D. S. Physical Review, Vol. 126, Issue 1 https://doi.org/10.1103/PhysRev.126.104	journal	April 1962
The effect of demagnetization on the magnetocaloric properties of gadolinium Bahl, C. R. H.; Nielsen, K. K. Journal of Applied Physics, Vol. 105, Issue 1 https://doi.org/10.1063/1.3056220	journal	January 2009
Sensitivity study of multi-layer active magnetic regenerators using first order magnetocaloric material La(Fe,Mn,Si) ₁₃ H _y Lei, Tian; Nielsen, Kaspar K.; Engelbrecht, Kurt Journal of Applied Physics, Vol. 118, Issue 1 https://doi.org/10.1063/1.4923356	journal	July 2015
The influence of hysteresis on the determination of the magnetocaloric effect in Gd ₅ Si ₂ Ge ₂ von Moos, L.; Bahl, C. R. H.; Nielsen, K. K. Journal of Physics D: Applied Physics, Vol. 48, Issue 2 https://doi.org/10.1088/0022-3727/48/2/025005	journal	December 2014
Giant Magnetocaloric Effect in ${Gd}_{5} ({Si}_{2} {Ge}_{2})$ Pecharsky, V. K.; Gschneidner, Jr., K. A. Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497 https://doi.org/10.1103/PhysRevLett.78.4494	journal	June 1997
Direct measurements of the magnetic entropy change Nielsen, K. K.; Bez, H. N.; von Moos, L. Review of Scientific Instruments, Vol. 86, Issue 10 https://doi.org/10.1063/1.4932308	journal	October 2015
Dynamics of the First-Order Metamagnetic Transition in Magnetocaloric La(Fe,Si) ₁₃ : Reducing Hysteresis Lovell, Edmund; Pereira, André M.; Caplin, A. David Advanced Energy Materials, Vol. 5, Issue 6 https://doi.org/10.1002/aenm.201401639	journal	November 2014
Magnetic measurements: A powerful tool in magnetic refrigerator design Földeàki, M.; Chahine, R.; Bose, T. K. Journal of Applied Physics, Vol. 77, Issue 7 https://doi.org/10.1063/1.358648	journal	April 1995

Cited By (4)

Magnetic and cryogenic magnetocaloric properties of NaGdF ₄ nanocrystals Petrov, Dimitar N.; Lovchinov, V.; The Huy, Bui Journal of Applied Physics, Vol. 126, Issue 13 https://doi.org/10.1063/1.5114993	journal	October 2019
Evaluating Magnetocaloric Effect in Magnetocaloric Materials: A Novel Approach Based on Indirect Measurements Using Artificial Neural Networks Maiorino, Angelo; Del Duca, Manuel Gesù; Tušek, Jaka Energies, Vol. 12, Issue 10 https://doi.org/10.3390/en12101871	journal	May 2019
Magnetocaloric effect in the triangulated Kagome lattice Cu ₉ Cl ₂ (cpa) ₆ Skinner, Samuel F.; Coro, Ronald A.; Farmer, William M. AIP Advances, Vol. 9, Issue 3 https://doi.org/10.1063/1.5079871	journal	March 2019
Managing hysteresis of Gd ₅ Si ₂ Ge ₂ by magnetic field cycling Biswas, Anis; Mudryk, Yaroslav; Pathak, Arjun K. Journal of Applied Physics, Vol. 126, Issue 24 https://doi.org/10.1063/1.5129660	journal	December 2019

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Title: Best practices in evaluation of the magnetocaloric effect from bulk magnetization measurements

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