Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

Voylov, D. N.; Ivanov, I. N.; Bykov, V. I.; Tsybenova, S. B.; Merkulov, I. A.; Kurochkin, S. A.; Holt, A. P.; Kisliuk, A. M.; Sokolov, A. P.

doi:10.1039/C6RA14414D

Title: Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

Journal Article · Thu Aug 11 00:00:00 EDT 2016 · RSC Advances

DOI:https://doi.org/10.1039/C6RA14414D· OSTI ID:1436054

^[1]; Ivanov, I. N. ^[2]; Bykov, V. I. ^[3]; Tsybenova, S. B. ^[4]; Merkulov, I. A. ^[5]; Kurochkin, S. A. ^[6]; Holt, A. P. ^[1]; Kisliuk, A. M. ^[5]; Sokolov, A. P. ^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Emanuel Institute of Biochemical Physics, Moscow (Russia)
Moscow City Teach Training Univ., Moscow (Russia)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Institute of Problems of Chemical Physics, Chernogolovka (Russia)

Here, we report the observation of oscillatory redox reactions on the surface of multilayer graphene oxide (GO) films at room temperature.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1436054

Journal Information:: RSC Advances, Vol. 6, Issue 81; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

References (48)

Room-temperature metastability of multilayer graphene oxide films Kim, Suenne; Zhou, Si; Hu, Yike Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3316	journal	May 2012
Precise and Ultrafast Molecular Sieving Through Graphene Oxide Membranes Joshi, R. K.; Carbone, P.; Wang, F. C. Science, Vol. 343, Issue 6172 https://doi.org/10.1126/science.1245711	journal	February 2014
Self-Initiated Free Radical Grafting of Styrene Homo- and Copolymers onto Functionalized Graphene Beckert, Fabian; Rostas, Arpad M.; Thomann, Ralf Macromolecules, Vol. 46, Issue 14 https://doi.org/10.1021/ma400895f	journal	July 2013
Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets Kudin, Konstantin N.; Ozbas, Bulent; Schniepp, Hannes C. Nano Letters, Vol. 8, Issue 1 https://doi.org/10.1021/nl071822y	journal	January 2008
Water Dynamics in Graphite Oxide Investigated with Neutron Scattering Buchsteiner, Alexandra; Lerf, Anton; Pieper, Jörg The Journal of Physical Chemistry B, Vol. 110, Issue 45 https://doi.org/10.1021/jp0641132	journal	November 2006
MATERIALS SCIENCE: Graphene-Based Materials Li, D.; Kaner, R. B. Science, Vol. 320, Issue 5880 https://doi.org/10.1126/science.1158180	journal	May 2008
Oxygen-Functionalized Few-Layer Graphene Sheets as Active Catalysts for Oxidative Dehydrogenation Reactions Schwartz, Viviane; Fu, Wujun; Tsai, Yu-Tung ChemSusChem, Vol. 6, Issue 5 https://doi.org/10.1002/cssc.201200756	journal	March 2013
High-Performance Supercapacitors Based on Poly(ionic liquid)-Modified Graphene Electrodes Kim, Tae Young; Lee, Hyun Wook; Stoller, Meryl ACS Nano, Vol. 5, Issue 1, p. 436-442 https://doi.org/10.1021/nn101968p	journal	December 2010
Determination of the sp3/sp2 ratio of a-C:H by XPS and XAES Leung, T. Y.; Man, W. F.; Lim, P. K. Journal of Non-Crystalline Solids, Vol. 254, Issue 1-3 https://doi.org/10.1016/S0022-3093(99)00388-9	journal	September 1999
Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of copper phase in redox reactions Voylov, Dmitry N.; Agapov, Alexander L.; Sokolov, Alexei P. Carbon, Vol. 69 https://doi.org/10.1016/j.carbon.2013.12.067	journal	April 2014
The chemistry of graphene oxide Dreyer, Daniel R.; Park, Sungjin; Bielawski, Christopher W. Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B917103G	journal	January 2010
The consequences of imperfect mixing in autocatalytic chemical and biological systems Epstein, Irving R. Nature, Vol. 374, Issue 6520 https://doi.org/10.1038/374321a0	journal	March 1995
Clustering of Chemisorbed H(D) Atoms on the Graphite (0001) Surface due to Preferential Sticking Hornekær, L.; Rauls, E.; Xu, W. Physical Review Letters, Vol. 97, Issue 18 https://doi.org/10.1103/PhysRevLett.97.186102	journal	October 2006
Kinetic Study of the Graphite Oxide Reduction: Combined Structural and Gravimetric Experiments under Isothermal and Nonisothermal Conditions Barroso-Bujans, Fabienne; Alegría, Ángel; Colmenero, Juan The Journal of Physical Chemistry C, Vol. 114, Issue 49 https://doi.org/10.1021/jp108905j	journal	November 2010
Chemical methods for the production of graphenes Park, Sungjin; Ruoff, Rodney S. Nature Nanotechnology, Vol. 4, Issue 4, p. 217-224 https://doi.org/10.1038/nnano.2009.58	journal	March 2009
Restoration of graphene from graphene oxide by defect repair Cheng, Meng; Yang, Rong; Zhang, Lianchang Carbon, Vol. 50, Issue 7 https://doi.org/10.1016/j.carbon.2012.02.016	journal	June 2012
Graphene: Status and Prospects Geim, A. K. Science, Vol. 324, Issue 5934, p. 1530-1534 https://doi.org/10.1126/science.1158877	journal	June 2009
Origin of the Chemical and Kinetic Stability of Graphene Oxide Zhou, Si; Bongiorno, Angelo Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02484	journal	August 2013
Graphene and Graphene Oxide: Synthesis, Properties, and Applications Zhu, Yanwu; Murali, Shanthi; Cai, Weiwei Advanced Materials, Vol. 22, Issue 35, p. 3906-3924 https://doi.org/10.1002/adma.201001068	journal	June 2010
π-Conjugated Carbon Radicals at Graphene Oxide to Initiate Ultrastrong Chemiluminescence Yang, Liang; Zhang, Ruilong; Liu, Bianhua Angewandte Chemie International Edition, Vol. 53, Issue 38 https://doi.org/10.1002/anie.201405295	journal	July 2014
High resolution XPS of organic polymers, the scienta ESCA300 database. By G. Beamson and D. Briggs, Wiley, Chichester 1992, 295 pp., hardcover, £ 65.00, ISBN 0-471-93592-1 Hantsche, Harald Advanced Materials, Vol. 5, Issue 10 https://doi.org/10.1002/adma.19930051035	journal	October 1993
Graphene-based composite materials Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B. Nature, Vol. 442, Issue 7100, p. 282-286 https://doi.org/10.1038/nature04969	journal	July 2006
The Impact of Functionalization on the Stability, Work Function, and Photoluminescence of Reduced Graphene Oxide Kumar, Priyank V.; Bernardi, Marco; Grossman, Jeffrey C. ACS Nano, Vol. 7, Issue 2, p. 1638-1645 https://doi.org/10.1021/nn305507p	journal	January 2013
C–H bond formation at the graphite surface studied with core level spectroscopy Nikitin, Anton; Näslund, Lars-Åke; Zhang, Zhiyong Surface Science, Vol. 602, Issue 14 https://doi.org/10.1016/j.susc.2008.06.012	journal	July 2008
High translational energy release in H2 (D2) associative desorption from H (D) chemisorbed on C(0001) Baouche, S.; Gamborg, G.; Petrunin, V. V. The Journal of Chemical Physics, Vol. 125, Issue 8 https://doi.org/10.1063/1.2220565	journal	August 2006
Large-scale pattern growth of graphene films for stretchable transparent electrodes Kim, Keun Soo; Zhao, Yue; Jang, Houk Nature, Vol. 457, Issue 7230 https://doi.org/10.1038/nature07719	journal	January 2009
Direct Observation of Spatially Heterogeneous Single-Layer Graphene Oxide Reduction Kinetics McDonald, Matthew P.; Eltom, Ahmed; Vietmeyer, Felix Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl402057j	journal	November 2013
Graphene-based materials in electrochemistry Chen, Da; Tang, Longhua; Li, Jinghong Chemical Society Reviews, Vol. 39, Issue 8 https://doi.org/10.1039/b923596e	journal	January 2010
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Graphene photonics and optoelectronics Bonaccorso, F.; Sun, Z.; Hasan, T. Nature Photonics, Vol. 4, Issue 9 https://doi.org/10.1038/nphoton.2010.186	journal	August 2010
Solid-State NMR Studies of the Structure of Graphite Oxide He, Heyong; Riedl, Thomas; Lerf, Anton The Journal of Physical Chemistry, Vol. 100, Issue 51 https://doi.org/10.1021/jp961563t	journal	January 1996
Origin of Anomalous Water Permeation through Graphene Oxide Membrane Boukhvalov, Danil W.; Katsnelson, Mikhail I.; Son, Young-Woo Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl4020292	journal	July 2013
The Role of Oxygen during Thermal Reduction of Graphene Oxide Studied by Infrared Absorption Spectroscopy Acik, Muge; Lee, Geunsik; Mattevi, Cecilia The Journal of Physical Chemistry C, Vol. 115, Issue 40 https://doi.org/10.1021/jp2052618	journal	September 2011
Transport of hydrogen in films of graphite, amorphous silicon, and nickel oxide Gabis, I. E. Semiconductors, Vol. 31, Issue 2 https://doi.org/10.1134/1.1187091	journal	February 1997
Fabrication of copper nanoparticles/graphene oxide composites for surface-enhanced Raman scattering Zhang, Kailong Applied Surface Science, Vol. 258, Issue 19 https://doi.org/10.1016/j.apsusc.2012.04.002	journal	July 2012
Identifying Active Functionalities on Few-Layered Graphene Catalysts for Oxidative Dehydrogenation of Isobutane Dathar, Gopi Krishna Phani; Tsai, Yu-Tung; Gierszal, Kamil ChemSusChem, Vol. 7, Issue 2 https://doi.org/10.1002/cssc.201301006	journal	January 2014
Ultrathin Epitaxial Graphite: 2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics Berger, Claire; Song, Zhimin; Li, Tianbo The Journal of Physical Chemistry B, Vol. 108, Issue 52, p. 19912-19916 https://doi.org/10.1021/jp040650f	journal	December 2004
Ab initio study of hydrogen interaction with pure and nitrogen-doped carbon nanotubes Zhang, Zhiyong; Cho, Kyeongjae Physical Review B, Vol. 75, Issue 7 https://doi.org/10.1103/PhysRevB.75.075420	journal	February 2007
Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide Schniepp, Hannes C.; Li, Je-Luen; McAllister, Michael J. The Journal of Physical Chemistry B, Vol. 110, Issue 17 https://doi.org/10.1021/jp060936f	journal	May 2006
XPS photoemission in carbonaceous materials: A “defect” peak beside the graphitic asymmetric peak Estrade-Szwarckopf, Henriette Carbon, Vol. 42, Issue 8-9 https://doi.org/10.1016/j.carbon.2004.03.005	journal	January 2004
Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications Chen, Da; Feng, Hongbin; Li, Jinghong Chemical Reviews, Vol. 112, Issue 11 https://doi.org/10.1021/cr300115g	journal	August 2012
Revealing the ultrafast process behind the photoreduction of graphene oxide Gengler, Régis Y. N.; Badali, Daniel S.; Zhang, Dongfang Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3560	journal	October 2013
Carbon nanomaterial produced by microwave exfoliation of graphite oxide: new insights Shulga, Y. M.; Baskakov, S. A.; Knerelman, E. I. RSC Adv., Vol. 4, Issue 2 https://doi.org/10.1039/C3RA43612H	journal	January 2014
Diffusion driven layer-by-layer assembly of graphene oxide nanosheets into porous three-dimensional macrostructures Zou, Jianli; Kim, Franklin Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6254	journal	October 2014
Graphene Oxide as a Radical Initiator: Free Radical and Controlled Radical Polymerization of Sodium 4-Vinylbenzenesulfonate with Graphene Oxide Voylov, Dmitry; Saito, Tomonori; Lokitz, Bradley ACS Macro Letters, Vol. 5, Issue 2 https://doi.org/10.1021/acsmacrolett.6b00003	journal	January 2016
Preparation and characterization of graphene oxide paper Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J. Nature, Vol. 448, Issue 7152, p. 457-460 https://doi.org/10.1038/nature06016	journal	July 2007
Dual Path Mechanism in the Thermal Reduction of Graphene Oxide Larciprete, Rosanna; Fabris, Stefano; Sun, Tao Journal of the American Chemical Society, Vol. 133, Issue 43 https://doi.org/10.1021/ja205168x	journal	November 2011
The Route to Functional Graphene Oxide Haubner, Kinga; Murawski, Jan; Olk, Phillip ChemPhysChem, Vol. 11, Issue 10 https://doi.org/10.1002/cphc.201000132	journal	May 2010

Cited By (2)

Swelling of graphene oxide membranes in alcohols: effects of molecule size and air ageing Iakunkov, Artem; Sun, Jinhua; Rebrikova, Anastasia Journal of Materials Chemistry A, Vol. 7, Issue 18 https://doi.org/10.1039/c9ta01902b	journal	January 2019
Local oxidation and reduction of graphene Hong, Yi-Zhe; Chiang, Wei-Huan; Tsai, Hung-Chieh Nanotechnology, Vol. 28, Issue 39 https://doi.org/10.1088/1361-6528/aa802d	journal	September 2017

Similar Records

Room temperature reduction of multilayer graphene oxide film on a copper substrate: Penetration and participation of coper phase in redox reactions.

Journal Article · Wed Jan 01 00:00:00 EST 2014 · Carbon · OSTI ID:1436054

Voylov, Dmitry N; Agapov, Alexander L; Sokolov, Alexei P; +2 more

Effect of graphite oxide solution concentration on the properties of multilayer graphene

Journal Article · Wed Nov 27 00:00:00 EST 2013 · AIP Conference Proceedings · OSTI ID:1436054

Umar, Marjoni Imamora Ali; Yap, Chi Chin; Awang, Rozidawati; +2 more

Anomalous behaviour of magnetic coercivity in graphene oxide and reduced graphene oxide

Journal Article · Tue Jan 14 00:00:00 EST 2014 · Journal of Applied Physics · OSTI ID:1436054

Bagani, K.; Bhattacharya, A.; Kaur, J.; +3 more

Related Subjects

36 MATERIALS SCIENCE

Title: Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

Citation Formats

References (48)

Cited By (2)

Similar Records

Related Subjects