Processing and characterization of ceramic superconductor/polymer composites

Conference · Fri Dec 31 04:00:00 EST 1993

OSTI ID:143576

Kander, R G; Namboodri, S L ^[1]

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1. Virginia Polytechnic Institute & State Univ., Blacksburg, VA (United States). Materials Science and Engineering Dept.

One way to more easily process a brittle high-temperature ceramic superconductor into a useful structure is to combine it with a polymer to form a composite material. Processing of polymer-based composites into complex shapes is well established and relatively easy when compared with traditional ceramic processing unit operations. In addition, incorporating a ceramic superconductor into a polymer matrix can improve mechanical performance as compared with a monolithic ceramic. Finally, because ceramic superconductors are susceptible to attack by moisture, a polymer-based composite structure can also provide protection from deleterious environmental effects. This paper focuses on the processing and subsequent characterization of ceramic superconductor/polymer composites designed primarily for electromagnetic shielding and diamagnetic applications. YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} [YBCO] ceramic superconductor is combined with poly(methyl methacrylate) [PMMA] to form novel composite structures. Composite structures have been molded with both a discontinuous superconducting phase (i.e., ceramic particulate reinforced polymers) and with a continuous superconducting phase (i.e., polymer infiltrated porous ceramics). Characterization of these composite structures includes the determination of diamagnetic strength, electromagnetic shielding effectiveness, mechanical performance, and environmental resistance. The goal of this program is to produce a composite structure with increased mechanical integrity and environmental resistance at liquid nitrogen temperatures without compromising the electromagnetic shielding and diamagnetic properties of the superconducting phase. Composites structures of this type are potentially useful in numerous magnetic applications including electromagnetic shielding, magnetic sensors, energy storage, magnetic levitation, and motor windings.

• OSTI ID: 143576
• Report Number(s): CONF-930246--; ISBN 0-87339-251-5
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
BARIUM OXIDES
COMPOSITE MATERIALS
COPPER OXIDES
CORROSION RESISTANCE
FABRICATION
MECHANICAL PROPERTIES
POLYMERS
YTTRIUM OXIDES