Correlating Transport and Structural Properties in Li 1+xAlxGe2–x(PO 4)3 (LAGP) Prepared from Aqueous Solution

Weiss, Manuel; Weber, Dominik A.; Senyshyn, Anatoliy; Janek, Jürgen; Zeier, Wolfgang G.

doi:10.1021/acsami.8b00842

Title: Correlating Transport and Structural Properties in Li _1+xAl_xGe_2–x(PO ₄)₃ (LAGP) Prepared from Aqueous Solution

Journal Article · Thu Mar 08 00:00:00 EST 2018 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.8b00842· OSTI ID:1434719

Weiss, Manuel ^[1]; Weber, Dominik A. ^[1]; Senyshyn, Anatoliy ^[2];

^[1];

^[1]

Justus-Liebig-Univ., Gießen (Germany)
Technische Univ. Munchen, Garching (Germany)

Li_1+xAl_xGe_2–x(PO₄)₃ (LAGP) is a solid lithium-ion conductor belonging to the NASICON family, representing the solid solution of LiGe₂(PO₄)₃ and AlPO₄. The typical syntheses of LAGP either involve high-temperature melt-quenching, which is complicated and expensive, or a sol–gel process requiring costly organic germanium precursors. Herein, we report a simple method based on aqueous solutions without the need of ethoxide precursors. Using synchrotron and neutron diffraction, the crystal structure, the occupancies for Al and Ge, and the distribution of lithium were determined. Substitution of germanium by aluminum allows for an increased Li⁺ incorporation in the material and the actual Li⁺ content in the sample increases with the nominal Li⁺ content and a solubility limit is observed for higher aluminum content. By means of impedance spectroscopy, an increase in the ionic conductivity with increasing lithium content is observed. Whereas the lithium ionic conductivity improves, due to the increasing carrier density, the bulk activation energy increases. This correlation suggests that changes in the transport mechanism and correlated motion may be at play in the Li_1+xAl_xGe_2–x(PO₄)₃ solid solution.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: BASF SE; International Network for Electrochemistry and Batteries; Justus-Liebig-University Giessen; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1434719

Journal Information:: ACS Applied Materials and Interfaces, Vol. 10, Issue 13; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 56 works

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Title: Correlating Transport and Structural Properties in Li 1+xAlxGe2–x(PO 4)3 (LAGP) Prepared from Aqueous Solution

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