Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation

Kim, Hyunchul; Choi, Woon Ih; Jang, Yoonjung; Balasubramanian, Mahalingam; Lee, Wontae; Park, Gwi Ok; Park, Su Bin; Yoo, Jaeseung; Hong, Jin Seok; Choi, Youn -Suk; Lee, Hyo Sug; Bae, In Tae; Kim, Ji Man; Yoon, Won -Sub

doi:10.1021/acsnano.8b00435

Title: Exceptional Lithium Storage in a Co(OH)₂ Anode: Hydride Formation

Journal Article · Mon Feb 26 00:00:00 EST 2018 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.8b00435· OSTI ID:1434329

Kim, Hyunchul ^[1];

^[2]; Jang, Yoonjung ^[1]; Balasubramanian, Mahalingam ^[3]; Lee, Wontae ^[1]; Park, Gwi Ok ^[1]; Park, Su Bin ^[1]; Yoo, Jaeseung ^[1]; Hong, Jin Seok ^[2]; Choi, Youn -Suk ^[2]; Lee, Hyo Sug ^[2];

^[1];

^[1]

Sungkyunkwan Univ., Suwon (South Korea)
Samsung Advanced Institute of Technology, Suwon (South Korea)
Argonne National Lab. (ANL), Argonne, IL (United States)

Current lithium ion battery technology is tied in with conventional reaction mechanisms such as insertion, conversion, and alloying reactions even though most future applications like EVs demand much higher energy densities than current ones. Exploring the exceptional reaction mechanism and related electrode materials can be critical for pushing current battery technology to a next level. Here, we introduce an exceptional reaction with a Co(OH)₂ material which exhibits an initial charge capacity of 1112 mAh g^–1, about twice its theoretical value based on known conventional conversion reaction, and retains its first cycle capacity after 30 cycles. The combined results of synchrotron X-ray diffraction and X-ray absorption spectroscopy indicate that nanosized Co metal particles and LiOH are generated by conversion reaction at high voltages, and Co_xH_y, Li₂O, and LiH are subsequently formed by hydride reaction between Co metal, LiOH, and other lithium species at low voltages, resulting in a anomalously high capacity beyond the theoretical capacity of Co(OH)₂. This is further corroborated by AIMD simulations, localized STEM, and XPS. Furthermore, these findings will provide not only further understanding of exceptional lithium storage of recent nanostructured materials but also valuable guidance to develop advanced electrode materials with high energy density for next-generation batteries.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1434329

Journal Information:: ACS Nano, Vol. 12, Issue 3; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 51 works

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Related Subjects

25 ENERGY STORAGE
colloidal silica-assisted Co(OH)2
high capacity
hydride formation
lithium ion batteries
reaction mechanism

Title: Exceptional Lithium Storage in a Co(OH)2 Anode: Hydride Formation

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Title: Exceptional Lithium Storage in a Co(OH)₂ Anode: Hydride Formation