Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction

Aragao, Isaias Barbosa; Ro, Insoo; Liu, Yifei; Ball, Madelyn; Huber, George W.; Zanchet, Daniela; Dumesic, James A.

doi:10.1016/j.apcatb.2017.10.004

Title: Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction

Journal Article · Wed Oct 04 00:00:00 EDT 2017 · Applied Catalysis B: Environmental

DOI:https://doi.org/10.1016/j.apcatb.2017.10.004· OSTI ID:1434303

Aragao, Isaias Barbosa ^[1]; Ro, Insoo ^[2]; Liu, Yifei ^[2]; Ball, Madelyn ^[2]; Huber, George W. ^[2]; Zanchet, Daniela ^[3]; Dumesic, James A. ^[2]

Univ. of Campinas (UNICAMP), Sao Paulo (Brazil); Univ. of Wisconsin-Madison, Madison, WI (United States)
Univ. of Wisconsin-Madison, Madison, WI (United States)
Univ. of Campinas (UNICAMP), Sao Paulo (Brazil)

FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO₂ catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. Here, the catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H₂O activation on FeO_x species at or near the Pt surface, mostly in the (II) oxidation state.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Contributing Organization:: Brazilian Synchrotron Light Laboratory (LNLS) and Advanced Photon Source at Argonne National Laboratory.

Grant/Contract Number:: SC0014058; AC02-06CH11357

OSTI ID:: 1434303

Alternate ID(s):: OSTI ID: 1549371

Journal Information:: Applied Catalysis B: Environmental, Vol. 222, Issue C; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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