Interaction of Black Phosphorus with Oxygen and Water

Huang, Yuan; Qiao, Jingsi; He, Kai; Bliznakov, Stoyan; Sutter, Eli; Chen, Xianjue; Luo, Da; Meng, Fanke; Su, Dong; Decker, Jeremy; Ji, Wei; Ruoff, Rodney S.; Sutter, Peter

doi:10.1021/acs.chemmater.6b03592

Title: Interaction of Black Phosphorus with Oxygen and Water

Journal Article · Mon Oct 24 00:00:00 EDT 2016 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.6b03592· OSTI ID:1433967

Huang, Yuan ^[1]; Qiao, Jingsi ^[2]; He, Kai ^[3]; Bliznakov, Stoyan ^[3]; Sutter, Eli ^[4]; Chen, Xianjue ^[5]; Luo, Da ^[5]; Meng, Fanke ^[3]; Su, Dong ^[3]; Decker, Jeremy ^[5]; Ji, Wei ^[2]; Ruoff, Rodney S. ^[6]; Sutter, Peter ^[4]

Institute for Basic Science (IBS), Ulsan (Republic of Korea); Brookhaven National Lab. (BNL), Upton, NY (United States)
Renmin Univ. of China, Beijing (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Nebraska-Lincoln, Lincoln, NE (United States)
Institute for Basic Science (IBS), Ulsan (Republic of Korea)
Institute for Basic Science (IBS), Ulsan (Republic of Korea); Ulsan National Institute of Science and Technology, Ulsan (Republic of Korea)

Black phosphorus (BP) has attracted significant interest as a monolayer or few-layer material with extraordinary electrical and optoelectronic properties. Chemical reactions with different ambient species, notably oxygen and water, are important as they govern key properties such as stability in air, electronic structure and charge transport, wetting by aqueous solutions, etc. Here, we report experiments combined with ab-initio calculations that address the effects of oxygen and water in contact with BP. Our results show that the reaction with oxygen is primarily responsible for changing properties of BP. Oxidation involving the dissociative chemisorption of O₂ causes the decomposition of BP and continuously lowers the conductance of BP field-effect transistors (FETs). In contrast, BP is stable in contact with deaerated (i.e., O₂ depleted) water and the carrier mobility in BP FETs gated by H₂O increases significantly due to efficient dielectric screening of scattering centers by the high-k dielectric. Isotope labeling experiments, contact angle measurements and calculations show that the pristine BP surface is hydrophobic, but is turned progressively hydrophilic by oxidation. Lastly, our results open new avenues for exploring applications that require contact of BP with aqueous solutions including solution gating, electrochemistry, and solution-phase approaches for exfoliation, dispersion, and delivery of BP.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1433967

Report Number(s):: BNL-203500-2018-JAAM; TRN: US1803027

Journal Information:: Chemistry of Materials, Vol. 28, Issue 22; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 403 works

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High-quality in situ fabricated Nb Josephson junctions with black phosphorus barriers Chen, Wei; Xu, Zuyu; Tian, Wanghao Superconductor Science and Technology, Vol. 32, Issue 11 https://doi.org/10.1088/1361-6668/ab3dc7	journal	September 2019
Water-Catalyzed Oxidation of Few-Layer Black Phosphorous in a Dark Environment Hu, Zehua; Li, Qiang; Lei, Bo Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201705012	journal	June 2017
Stabilizing black phosphorus nanosheets via edge-selective bonding of sacrificial C60 molecules Zhu, Xianjun; Zhang, Taiming; Jiang, Daochuan Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06437-1	journal	October 2018
2D-Pnictogens: alloy-based anode battery materials with ultrahigh cycling stability Beladi-Mousavi, Seyyed Mohsen; Pumera, Martin Chemical Society Reviews, Vol. 47, Issue 18 https://doi.org/10.1039/c8cs00425k	journal	January 2018
Emerging Applications of Elemental 2D Materials Glavin, Nicholas R.; Rao, Rahul; Varshney, Vikas Advanced Materials, Vol. 32, Issue 7 https://doi.org/10.1002/adma.201904302	journal	October 2019
Orientation‐Dependent Intercalation Channels for Lithium and Sodium in Black Phosphorus Kim, Sungkyu; Cui, Jiang; Dravid, Vinayak P. Advanced Materials, Vol. 31, Issue 46 https://doi.org/10.1002/adma.201904623	journal	September 2019
Monolayer black phosphorus by sequential wet-chemical surface oxidation Wild, Stefan; Lloret, Vicent; Vega-Mayoral, Victor RSC Advances, Vol. 9, Issue 7 https://doi.org/10.1039/c8ra09069f	journal	January 2019
Autoperforation of 2D materials for generating two-terminal memristive Janus particles Liu, Pingwei; Liu, Albert Tianxiang; Kozawa, Daichi Nature Materials, Vol. 17, Issue 11 https://doi.org/10.1038/s41563-018-0197-z	journal	October 2018
Two-Dimensional Materials for Antimicrobial Applications: Graphene Materials and Beyond Sun, Wei; Wu, Fu-Gen Chemistry - An Asian Journal, Vol. 13, Issue 22 https://doi.org/10.1002/asia.201800851	journal	September 2018
A first-principles study on the adsorption of small molecules on antimonene: oxidation tendency and stability Kistanov, Andrey A.; Cai, Yongqing; Kripalani, Devesh R. Journal of Materials Chemistry C, Vol. 6, Issue 15 https://doi.org/10.1039/c8tc00338f	journal	January 2018
2D Elemental Nanomaterials Beyond Graphene Vishnoi, Pratap; Pramoda, K.; Rao, C. N. R. ChemNanoMat, Vol. 5, Issue 9 https://doi.org/10.1002/cnma.201900176	journal	June 2019
Effect of TCNQ Layer Cover on Oxidation Dynamics of Black Phosphorus Meingast, Laura; Koleśnik-Gray, Maria; Siebert, Martin physica status solidi (RRL) - Rapid Research Letters, Vol. 12, Issue 8 https://doi.org/10.1002/pssr.201800179	journal	May 2018
2D Black Phosphorus–Based Biomedical Applications Luo, Miaomiao; Fan, Taojian; Zhou, Yun Advanced Functional Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adfm.201808306	journal	February 2019
A batch-by-batch free route for the continuous production of black phosphorus nanosheets for targeted combination cancer therapy Poudel, Bijay Kumar; Hwang, Jungho; Ku, Sae Kwang NPG Asia Materials, Vol. 10, Issue 8 https://doi.org/10.1038/s41427-018-0068-8	journal	August 2018
Hybrid nanocomposites of 2D black phosphorus nanosheets encapsulated in PMMA polymer material: new platforms for advanced device fabrication Telesio, Francesca; Passaglia, Elisa; Cicogna, Francesca Nanotechnology, Vol. 29, Issue 29 https://doi.org/10.1088/1361-6528/aabd8d	journal	May 2018
Mechanistic insights in phosphorene degradation Babar, Rohit; Kabir, Mukul Physical Review Materials, Vol. 3, Issue 7 https://doi.org/10.1103/physrevmaterials.3.074008	journal	July 2019
Intrinsic Correlation between Electronic Structure and Degradation: From Few‐Layer to Bulk Black Phosphorus Kim, Minju; Kim, Han‐gyu; Park, Soohyung Angewandte Chemie, Vol. 131, Issue 12 https://doi.org/10.1002/ange.201811743	journal	January 2019
Azide Passivation of Black Phosphorus Nanosheets: Covalent Functionalization Affords Ambient Stability Enhancement Yang, Shangfeng; Liu, Yajuan; Gao, Pengfei Angewandte Chemie https://doi.org/10.1002/ange.201813218	journal	December 2018
Band Structure of the IV-VI Black Phosphorus Analog and Thermoelectric SnSe Pletikosić, Ivo; Von Rohr, Fabian; Pervan, Petar American Physical Society https://doi.org/10.5167/uzh-167495	text	January 2018
Raman and electrical transport properties of few-layered arsenic-doped black phosphorus Pradhan, Nihar R.; Garcia, Carlos; Lucking, Michael C. Royal Society of Chemistry https://doi.org/10.7892/boris.140693	text	January 2019
Water-Catalyzed Oxidation of Few-Layer Black Phosphorous in a Dark Environment Hu, Zehua; Li, Qiang; Lei, Bo Angewandte Chemie, Vol. 129, Issue 31 https://doi.org/10.1002/ange.201705012	journal	June 2017
Few Layer 2D Pnictogens (P & Sb) Catalyze the Alkylation of Soft Nucleophiles with Esters Lioret, Vincet; Rivero-Crespo, Miguel Angel; Vidal-Moya, Jose Alejandro Nanoscience https://doi.org/10.26434/chemrxiv.7123184.v1	preprint	September 2018
Emerging Applications of Elemental 2D Materials. Glavin, Nicholas R.; Rao, Rahul; Varshney, Vikas Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.45784	text	January 2020
Few Layer 2D Pnictogens (P & Sb) Catalyze the Alkylation of Soft Nucleophiles with Esters Lloret, Vicent; Rivero-Crespo, Miguel Angel; Vidal-Moya, Jose Alejandro Nanoscience https://doi.org/10.26434/chemrxiv.7123184	preprint	September 2018
A First-Principles Study on the Adsorption of Small Molecules on Antimonene: Oxidation Tendency and Stability Kistanov, Andrey A.; Cai, Yongqing; Kripalani, Devesh R. arXiv https://doi.org/10.48550/arxiv.1803.07824	text	January 2018
Atomically thin p-n junctions based on two-dimensional materials Frisenda, Riccardo; Molina-Mendoza, Aday J.; Mueller, Thomas arXiv https://doi.org/10.48550/arxiv.1809.03728	text	January 2018
Effect of TCNQ layer cover on oxidation dynamics of black phosphorus Meingast, Laura; Koleśnik-Gray, Maria; Siebert, Martin arXiv https://doi.org/10.48550/arxiv.1809.08915	text	January 2018
Mechanistic insights on the phosphorene degradation Babar, Rohit; Kabir, Mukul arXiv https://doi.org/10.48550/arxiv.1904.08822	text	January 2019
Environmental Stability of Bismuthene: Oxidation Mechanism and Structural Stability of 2D Pnictogens Kistanov, Andrey A.; Khadiullin, Salavat Kh.; Zhou, Kun arXiv https://doi.org/10.48550/arxiv.1907.04806	text	January 2019

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