Unique [Mn6Bi5]- Nanowires in KMn6Bi5: A Quasi-One-Dimensional Antiferromagnetic Metal

Bao, Jin-Ke; Tang, Zhang-Tu; Jung, Hee Joon; Liu, Ji-Yong; Liu, Yi; Li, Lin; Li, Yu-Ke; Xu, Zhu-An; Feng, Chun-Mu; Chen, Haijie; Chung, Duck Young; Dravid, Vinayak P.; Cao, Guang-Han; Kanatzidis, Mercouri G.

doi:10.1021/jacs.8b00465

Title: Unique [Mn₆Bi₅]^- Nanowires in KMn₆Bi₅: A Quasi-One-Dimensional Antiferromagnetic Metal

Journal Article · Thu Mar 01 00:00:00 EST 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b00465· OSTI ID:1433916

^[1]; Tang, Zhang-Tu ^[2]; Jung, Hee Joon ^[3]; Liu, Ji-Yong ^[4]; Liu, Yi ^[2]; Li, Lin ^[5]; Li, Yu-Ke ^[5]; Xu, Zhu-An ^[6]; Feng, Chun-Mu ^[2];

^[7];

^[8];

^[3];

^[6];

^[9]

Zhejiang Univ., Hangzhou (China). Dept. of Physics; Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Zhejiang Univ., Hangzhou (China). Dept. of Physics
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Zhejiang Univ., Hangzhou (China). Dept. of Chemistry
Hangzhou Normal Univ. (China). Dept. of Physics
Zhejiang Univ., Hangzhou (China). Dept. of Physics. State Key Lab. of Silicon Materials; Nanjing Univ. (China). Collaborative Innovation Centre of Advanced Microstructures
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry

In this paper, we report a new quasi-one-dimensional compound KMn₆Bi₅ composed of parallel nanowires crystallizing in a monoclinic space group C2/m with a = 22.994(2) Å, b = 4.6128(3) Å, c = 13.3830(13) Å and β = 124.578(6)°. The nanowires are infinite [Mn₆Bi₅]^- columns each of which is composed of a nanotube of Bi atoms acting as the cladding with a nanorod of Mn atoms located in the central axis of the nanotubes. The nanorods of Mn atoms inside the Bi cladding are stabilized by Mn–Mn bonding and are defined by distorted Mn-centered cluster icosahedra of Mn₁₃ sharing their vertices along the b axis. The [Mn₆Bi₅]^- nanowires are linked with weak internanowire Bi–Bi bonds and charge balanced with K⁺ ions. The [Mn₆Bi₅]^- nanowires were directly imaged by high-resolution transmission electron microscopy and scanning transmission electron microscopy. Magnetic susceptibility studies show one-dimensional characteristics with an antiferromagnetic transition at ~75 K and a small average effective magnetic moment (1.56 μ_B/Mn for H ∥ b and 1.37 μ_B/Mn for H ⊥ b) of Mn from Curie–Weiss fits above 150 K. Specific heat measurements reveal an electronic specific heat coefficient γ of 6.5(2) mJ K^–2(mol-Mn)^-1 and a small magnetic entropy change ΔS_mag ≈ 1.6 J K^–1 (mol-Mn)^-1 across the antiferromagnetic transition. Finally, in contrast to a metallic resistivity along the column, the resistivity perpendicular to the column shows a change from a semiconducting behavior at high temperatures to a metallic one at low temperatures, indicating an incoherent-to-coherent crossover of the intercolumn tunneling of electrons.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States); Zhejiang Univ., Hangzhou (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China

Grant/Contract Number:: AC02-06CH11357; ECCS-1542205; DMR-1720139; 11674281; 2017YFA0303002

OSTI ID:: 1433916

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 12; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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Title: Unique [Mn6Bi5]- Nanowires in KMn6Bi5: A Quasi-One-Dimensional Antiferromagnetic Metal

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Title: Unique [Mn₆Bi₅]^- Nanowires in KMn₆Bi₅: A Quasi-One-Dimensional Antiferromagnetic Metal