Polysulfide Speciation in the Bulk Electrolyte of a Lithium Sulfur Battery Supplemental.

McBrayer, Josefine D.; Perdue, Brian; Garzon, Fernando Henry; Apblett, Christopher A.

doi:10.1149/2.0441805jes

Polysulfide Speciation in the Bulk Electrolyte of a Lithium Sulfur Battery Supplemental.

Program Document · Thu Mar 01 04:00:00 EST 2018 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0441805jes· OSTI ID:1432473

McBrayer, Josefine D.; Perdue, Brian; Garzon, Fernando Henry; Apblett, Christopher A.

Abstract not provided.

View Program Document

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

DOE Contract Number:: AC04-94AL85000

OSTI ID:: 1432473

Report Number(s):: SAND2018-2835J; 661506

Country of Publication:: United States

Language:: English

References (36)

Confocal Raman Microscopy Toporski, Jan; Dieing, Thomas; Hollricher, Olaf Springer Series in Surface Sciences https://doi.org/10.1007/978-3-319-75380-5	book	January 2018
In Situ Raman Spectroscopy of Sulfur Speciation in Lithium–Sulfur Batteries Wu, Heng-Liang; Huff, Laura A.; Gewirth, Andrew A. ACS Applied Materials & Interfaces, Vol. 7, Issue 3 https://doi.org/10.1021/am5072942	journal	January 2015
In operando infrared spectroscopy of lithium polysulfides using a novel spectro-electrochemical cell Saqib, Najmus; Ohlhausen, Gretchen M.; Porter, Jason M. Journal of Power Sources, Vol. 364 https://doi.org/10.1016/j.jpowsour.2017.08.030	journal	October 2017
Evidence for the existence of Li ₂ S ₂ clusters in lithium–sulfur batteries: ab initio Raman spectroscopy simulation Partovi-Azar, Pouya; Kühne, Thomas D.; Kaghazchi, Payam Physical Chemistry Chemical Physics, Vol. 17, Issue 34 https://doi.org/10.1039/C5CP02781K	journal	January 2015
Raman spectra of sodium tetrasulfide in primary amines. Evidence for sulfide (S42- and S8n-) ions in rhombic sulfur-amine solutions Daly, Francis P.; Brown, Chris W. The Journal of Physical Chemistry, Vol. 79, Issue 4 https://doi.org/10.1021/j100571a013	journal	February 1975
Effects of Liquid Electrolytes on the Charge–Discharge Performance of Rechargeable Lithium/Sulfur Batteries: Electrochemical and in-Situ X-ray Absorption Spectroscopic Studies Gao, Jie; Lowe, Michael A.; Kiya, Yasuyuki The Journal of Physical Chemistry C, Vol. 115, Issue 50, p. 25132-25137 https://doi.org/10.1021/jp207714c	journal	October 2011
Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization Zheng, Dong; Qu, Deyu; Yang, Xiao-Qing Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201401888	journal	January 2015
Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification Barchasz, Céline; Molton, Florian; Duboc, Carole Analytical Chemistry, Vol. 84, Issue 9 https://doi.org/10.1021/ac2032244	journal	April 2012
Radical or Not Radical: Revisiting Lithium-Sulfur Electrochemistry in Nonaqueous Electrolytes Cuisinier, Marine; Hart, Connor; Balasubramanian, Mahalingam Advanced Energy Materials, Vol. 5, Issue 16 https://doi.org/10.1002/aenm.201401801	journal	January 2015
Raman spectra of rhombic sulfur dissolved in secondary amines Daly, Francis P.; Brown, Chris W. The Journal of Physical Chemistry, Vol. 80, Issue 5 https://doi.org/10.1021/j100546a012	journal	February 1976
In Charge of the World: Electrochemical Energy Storage Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng The Journal of Physical Chemistry Letters, Vol. 4, Issue 8 https://doi.org/10.1021/jz4006652	journal	March 2013
Chemical routes toward long-lasting lithium/sulfur cells Liu, Meinan; Ye, Fangmin; Li, Wanfei Nano Research, Vol. 9, Issue 1 https://doi.org/10.1007/s12274-016-1027-8	journal	January 2016
Polysulfide Anions II: Structure and Vibrational Spectra of the S ₄ ² ^- and S ₅ ² ^- Anions. Influence of the Cations on Bond Length, Valence, and Torsion Angle El Jaroudi, Omar; Picquenard, Eric; Demortier, Antoine Inorganic Chemistry, Vol. 39, Issue 12 https://doi.org/10.1021/ic991419x	journal	June 2000
Raman studies of sulfur-containing anions in inorganic polysulfides. Barium trisulfide Janz, G. J.; Roduner, E.; Coutts, J. W. Inorganic Chemistry, Vol. 15, Issue 8 https://doi.org/10.1021/ic50162a002	journal	August 1976
Recent progress and remaining challenges in sulfur-based lithium secondary batteries – a review Bresser, Dominic; Passerini, Stefano; Scrosati, Bruno Chemical Communications, Vol. 49, Issue 90 https://doi.org/10.1039/c3cc46131a	journal	January 2013
Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries Miller, Elizabeth C.; Kasse, Robert M.; Heath, Khloe N. Journal of The Electrochemical Society, Vol. 165, Issue 1 https://doi.org/10.1149/2.0091801jes	journal	June 2017
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
Raman studies of sulfur-containing anions in inorganic polysulfides. Potassium polysulfides Janz, G. J.; Coutts, J. W.; Downey, J. R. Inorganic Chemistry, Vol. 15, Issue 8 https://doi.org/10.1021/ic50162a003	journal	August 1976
Fair performance comparison of different carbon blacks in lithium–sulfur batteries with practical mass loadings – Simple design competes with complex cathode architecture Jozwiuk, Anna; Sommer, Heino; Janek, Jürgen Journal of Power Sources, Vol. 296 https://doi.org/10.1016/j.jpowsour.2015.07.070	journal	November 2015
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy Cuisinier, Marine; Cabelguen, Pierre-Etienne; Evers, Scott The Journal of Physical Chemistry Letters, Vol. 4, Issue 19 https://doi.org/10.1021/jz401763d	journal	September 2013
FT-Raman spectroscopy study of solvent-in-salt electrolytes Suo, Liumin; Zheng, Fang; Hu, Yong-Sheng Chinese Physics B, Vol. 25, Issue 1 https://doi.org/10.1088/1674-1056/25/1/016101	journal	January 2016
Identification and characterization of lithium polysulfides in solution in liquid ammonia Dubois, P.; Lelieur, J. P.; Lepoutre, G. Inorganic Chemistry, Vol. 27, Issue 1 https://doi.org/10.1021/ic00274a017	journal	January 1988
Raman studies of sulfur-containing anions in inorganic polysulfides. Sodium polysulfides Janz, G. J.; Downey, J. R.; Roduner, E. Inorganic Chemistry, Vol. 15, Issue 8 https://doi.org/10.1021/ic50162a004	journal	August 1976
Solvent-Dictated Lithium Sulfur Redox Reactions: An Operando UV–vis Spectroscopic Study Zou, Qingli; Lu, Yi-Chun The Journal of Physical Chemistry Letters, Vol. 7, Issue 8 https://doi.org/10.1021/acs.jpclett.6b00228	journal	April 2016
The Quest for Polysulfides in Lithium-Sulfur Battery Electrolytes: An Operando Confocal Raman Spectroscopy Study Hannauer, Julien; Scheers, Johan; Fullenwarth, Julien ChemPhysChem, Vol. 16, Issue 13 https://doi.org/10.1002/cphc.201500708	journal	September 2015
Confocal Raman Microscopy Dieing, Thomas; Hollricher, Olaf; Toporski, Jan Springer Series in Optical Sciences https://doi.org/10.1007/978-3-642-12522-5	book	January 2011
In-Situ Raman Investigation of Polysulfide Formation in Li-S Cells Hagen, M.; Schiffels, P.; Hammer, M. Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.045308jes	journal	January 2013
The Quest for Polysulfides in Lithium-Sulfur Battery Electrolytes: An Operando Confocal Raman Spectroscopy Study Hannauer, Julien; Scheers, Johan; Fullenwarth, Julien ChemPhysChem, Vol. 16, Issue 13 https://doi.org/10.1002/cphc.201500448	journal	July 2015
In Situ NMR Observation of the Temporal Speciation of Lithium Sulfur Batteries during Electrochemical Cycling Wang, Hao; Sa, Niya; He, Meinan The Journal of Physical Chemistry C, Vol. 121, Issue 11 https://doi.org/10.1021/acs.jpcc.7b01922	journal	March 2017
In-Situ Raman Spectroscopy of Sulfur Speciation in Lithium-Sulfur Batteries Wu, Heng-Liang; Huff, Laura A.; Gewirth, Andrew A. ECS Meeting Abstracts, Vol. MA2015-01, Issue 2, p. 249-249 https://doi.org/10.1149/ma2015-01/2/249	journal	April 2015
Confocal Raman microscopy Gomez-Lazaro, M.; Freitas, A.; Ribeiro, C. C. Fluorescence Imaging and Biological Quantification https://doi.org/10.1201/9781315121017-5	book	September 2017
Polysulfide Anions. 1. Structure and Vibrational Spectra of the S ₂ ² ^- and S ₃ ² ^- Anions. Influence of the Cations on Bond Length and Angle El Jaroudi, Omar; Picquenard, Eric; Demortier, Antoine Inorganic Chemistry, Vol. 38, Issue 10 https://doi.org/10.1021/ic9811143	journal	May 1999
Raman Spectroscopic and X-ray Diffraction Studies of Sulfur Composite Electrodes during Discharge and Charge Yeon, Jin-Tak; Jang, Jun-Young; Han, Jung-Gu Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.080208jes	journal	January 2012
Raman spectra of sulfur dissolved in primary amines Daly, Francis P.; Brown, Chris W. The Journal of Physical Chemistry, Vol. 77, Issue 15 https://doi.org/10.1021/j100634a008	journal	July 1973
In situ / operando characterization techniques for rechargeable lithium–sulfur batteries: a review Tan, Jian; Liu, Dongna; Xu, Xu Nanoscale, Vol. 9, Issue 48 https://doi.org/10.1039/C7NR06819K	journal	January 2017
Effect of chemical reactivity of polysulfide toward carbonate-based electrolyte on the electrochemical performance of Li–S batteries Yim, Taeeun; Park, Min-Sik; Yu, Ji-Sang Electrochimica Acta, Vol. 107 https://doi.org/10.1016/j.electacta.2013.06.039	journal	September 2013

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Monitoring Polysulfide Solubility and Diffusion in Fluorinated Ether‐Based Electrolytes by Operando Raman Spectroscopy Bouchal, Roza; Boulaoued, Athmane; Johansson, Patrik Batteries & Supercaps, Vol. 3, Issue 5 https://doi.org/10.1002/batt.201900188	journal	January 2020
Rechargeable Solid-State Copper Sulfide Cathodes for Alkaline Batteries: Importance of the Copper Valence State Duay, Jonathon; Lambert, Timothy N.; Kelly, Maria Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0261904jes	journal	January 2019

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