An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes

Son, Seoung-Bum; Gao, Tao; Harvey, Steve P.; Steirer, K. Xerxes; Stokes, Adam; Norman, Andrew; Wang, Chunsheng; Cresce, Arthur; Xu, Kang; Ban, Chunmei

doi:10.1038/s41557-018-0019-6

An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes

Journal Article · Mon Apr 02 00:00:00 EDT 2018 · Nature Chemistry

DOI:https://doi.org/10.1038/s41557-018-0019-6· OSTI ID:1432192

Son, Seoung-Bum ^[1]; Gao, Tao ^[2]; Harvey, Steve P. ^[1]; Steirer, K. Xerxes ^[3]; Stokes, Adam ^[4]; Norman, Andrew ^[1]; Wang, Chunsheng ^[2]; Cresce, Arthur ^[5]; Xu, Kang ^[5]; Ban, Chunmei ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)
Univ. of Maryland, College Park, MD (United States)
Colorado School of Mines, Golden, CO (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States); Colorado School of Mines, Golden, CO (United States)
Army Research Lab., Adelphi, MD (United States)

Magnesium-based batteries possess potential advantages over their lithium counterparts. However, reversible Mg chemistry requires a thermodynamically stable electrolyte at low potential, which is usually achieved with corrosive components and at the expense of stability against oxidation. In lithium-ion batteries the conflict between the cathodic and anodic stabilities of the electrolytes is resolved by forming an anode interphase that shields the electrolyte from being reduced. This strategy cannot be applied to Mg batteries because divalent Mg²⁺ cannot penetrate such interphases. Here, we engineer an artificial Mg²⁺-conductive interphase on the Mg anode surface, which successfully decouples the anodic and cathodic requirements for electrolytes and demonstrate highly reversible Mg chemistry in oxidation-resistant electrolytes. The artificial interphase enables the reversible cycling of a Mg/V₂O₅ full-cell in the water-containing, carbonate-based electrolyte. This approach provides a new avenue not only for Mg but also for other multivalent-cation batteries facing the same problems, taking a step towards their use in energy-storage applications.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), NREL Laboratory Directed Research and Development (LDRD)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1432192

Report Number(s):: NREL/JA--5900-66801

Journal Information:: Nature Chemistry, Journal Name: Nature Chemistry Journal Issue: 5 Vol. 10; ISSN 1755-4330

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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