Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

Borjas, Rosendo; Mariappan Balasekaran, Samundeeswari; Poineau, Frederic

doi:10.1107/S241431461800528X

Bis(tetraphenylarsonium) hexachloridozirconate(IV) acetonitrile tetrasolvate

Journal Article · Fri Apr 06 00:00:00 EDT 2018 · IUCrData

DOI:https://doi.org/10.1107/S241431461800528X· OSTI ID:1432087

Borjas, Rosendo; ; Poineau, Frederic

The bis(tetraphenylarsonium) hexachloridozirconate(IV) salt, (AsPh ₄ ) ₂ [ZrCl ₆ ] (Ph = C ₆ H ₅ ), was prepared more than 25 years ago [Esmadi & Sutcliffe (1991). Indian J. Chem. 30 A , 99–101], but its crystal structure was never reported. By following a similar experimental procedure, the compound was synthesized and its crystal structure was investigated as a acetonitrile tetrasolvate, (As(C ₆ H ₅ ) ₄ ) ₂ [ZrCl ₆ ]·4CH ₃ CN, by single-crystal X –ray diffraction. The [ZrCl ₆ ] ²⁻ anion adopts a slightly distorted octahedral coordination sphere, with Zr—Cl bond lengths of 2.4586 (6), 2.4723 (6), and 2.4818 (5) Å, and Cl—Zr—Cl angles ranging from 89.602 (19) to 90.397 (19)°.

Sponsoring Organization:: USDOE

Grant/Contract Number:: NE0008449

OSTI ID:: 1432087

Journal Information:: IUCrData, Journal Name: IUCrData Journal Issue: 4 Vol. 3; ISSN 2414-3146; ISSN IUCRBK

Publisher:: International Union of Crystallography (IUCr)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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