Suppression of the commensurate magnetic phase in nanosized hübnerite MnWO4

Zajdel, P.; G?gor, A.; Pajerowski, D. M.; Ptak, M.; Szlawska, M.

doi:10.1103/PhysRevB.95.174427

Title: Suppression of the commensurate magnetic phase in nanosized hübnerite $MnW O_{4}$

Journal Article · Thu May 18 00:00:00 EDT 2017 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.95.174427· OSTI ID:1430608

Zajdel, P. ^[1]; G?gor, A. ^[2]; Pajerowski, D. M. ^[3]; Ptak, M. ^[2]; Szlawska, M. ^[2]

Univ. of Silesia, Katowice (Poland). Inst. of Physics
Polish Academy of Sciences (PAS), Warsaw (Poland). Inst. of Low Temperature and Structure Research
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division

Magnetic structures of nanosized (20 to 70 nm) powders of MnWO₄ and MnWO₄:Mo were studied using neutron powder diffraction (NPD). Sizes and shapes of the crystallites calculated from anisotropic peak broadening of diffraction peaks were found to be orthogonal parallelepipedlike with the longest edge along the c axis and the shortest along the b axis. SQUID measurements indicate the presence of two magnetic transitions around 8 and 12 K. Rietveld refinement of the NPD data below the magnetic transition was consistent with the presence of an incommensurate spiral-like (ac-AF2) phase. Finally, a commensurate phase AF1 was not observed down to 2.5 K for all of the samples.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; National Institute of Standards and Technology (NIST); Polish State Committee for Scientific Research

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1430608

Journal Information:: Physical Review B, Vol. 95, Issue 17; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (35)

Suppression and recovery of the ferroelectric phase in multiferroic $Mn W O_{4}$ Chaudhury, R. P.; Lorenz, B.; Wang, Y. Q. Physical Review B, Vol. 77, Issue 10 https://doi.org/10.1103/PhysRevB.77.104406	journal	March 2008
Magnetic control of ferroelectric polarization Kimura, T.; Goto, T.; Shintani, H. Nature, Vol. 426, Issue 6962 https://doi.org/10.1038/nature02018	journal	November 2003
DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data Azuah, Richard Tumanjong; Kneller, Larry R.; Qiu, Yiming Journal of Research of the National Institute of Standards and Technology, Vol. 114, Issue 6 https://doi.org/10.6028/jres.114.025	journal	November 2009
Polarized-neutron-scattering studies on the chiral magnetism in multiferroic MnWO ₄ Finger, T.; Senff, D.; Schmalzl, K. Journal of Physics: Conference Series, Vol. 211 https://doi.org/10.1088/1742-6596/211/1/012001	journal	February 2010
Magnetic-field dependence of the ferroelectric polarization and spin-lattice coupling in multiferroic $Mn W O_{4}$ Taniguchi, K.; Abe, N.; Sagayama, H. Physical Review B, Vol. 77, Issue 6 https://doi.org/10.1103/PhysRevB.77.064408	journal	February 2008
Origin of multiferroicity in MnWO $_{4}$ Solovyev, I. V. Physical Review B, Vol. 87, Issue 14 https://doi.org/10.1103/PhysRevB.87.144403	journal	April 2013
Electric field control of ferroelectric domain structures in MnWO ₄ Yu, H. W.; Li, X.; Liu, M. F. Journal of Physics: Condensed Matter, Vol. 26, Issue 30 https://doi.org/10.1088/0953-8984/26/30/305901	journal	July 2014
Control of the Magnetoelectric Domain-Wall Stability by a Magnetic Field in a Multiferroic ${MnWO}_{4}$ Taniguchi, K.; Abe, N.; Umetsu, H. Physical Review Letters, Vol. 101, Issue 20 https://doi.org/10.1103/PhysRevLett.101.207205	journal	November 2008
Phonon properties of nanosized MnWO4 with different size and morphology Mączka, MirosŁaw; Ptak, Maciej; Kurnatowska, Michalina Journal of Solid State Chemistry, Vol. 184, Issue 9 https://doi.org/10.1016/j.jssc.2011.07.023	journal	September 2011
Polyol-mediated low-temperature synthesis of crystalline tungstate nanoparticles MWO4 (M = Mn, Fe, Co, Ni, Cu, Zn) Ungelenk, Jan; Speldrich, Manfred; Dronskowski, Richard Solid State Sciences, Vol. 31 https://doi.org/10.1016/j.solidstatesciences.2014.02.020	journal	May 2014
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Application of symmetrized harmonics expansion to correction of the preferred orientation effect Järvinen, M. Journal of Applied Crystallography, Vol. 26, Issue 4 https://doi.org/10.1107/S0021889893001219	journal	August 1993
Magnetic phase transitions of ${MnWO}_{4}$ studied by the use of neutron diffraction Lautenschläger, G.; Weitzel, H.; Vogt, T. Physical Review B, Vol. 48, Issue 9 https://doi.org/10.1103/PhysRevB.48.6087	journal	September 1993
A new polar symmetry of huebnerite (MnWO4) with ferrodistortive domains Park, S. H.; Mihailova, B.; Pedersen, B. Journal of Magnetism and Magnetic Materials, Vol. 394 https://doi.org/10.1016/j.jmmm.2015.06.039	journal	November 2015
Spherical neutron polarimetry (SNP) study of magneto-electric coupling in the multiferroic MnWO ₄ Poole, A.; Brown, P. J.; Wills, A. S. Journal of Physics: Conference Series, Vol. 145 https://doi.org/10.1088/1742-6596/145/1/012074	journal	January 2009
Phase transitions and magnetic structures in MnW _{1− x} Mo _x O ₄ compounds ( x ⩽ 0.2) Hardy, Vincent; Payen, Christophe; Damay, Françoise Journal of Physics: Condensed Matter, Vol. 28, Issue 33 https://doi.org/10.1088/0953-8984/28/33/336003	journal	June 2016
Domain dynamics in the multiferroic phase of ${MnWO}_{4}$ Niermann, D.; Grams, C. P.; Schalenbach, M. Physical Review B, Vol. 89, Issue 13 https://doi.org/10.1103/PhysRevB.89.134412	journal	April 2014
Phenomenological model of anisotropic peak broadening in powder diffraction Stephens, Peter W. Journal of Applied Crystallography, Vol. 32, Issue 2 https://doi.org/10.1107/S0021889898006001	journal	April 1999
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Ferroelectricity in the cycloidal spiral magnetic phase of $Mn W O_{4}$ Arkenbout, A. H.; Palstra, T. T. M.; Siegrist, T. Physical Review B, Vol. 74, Issue 18 https://doi.org/10.1103/PhysRevB.74.184431	journal	November 2006
A new multiferroic material: MnWO ₄ Heyer, O.; Hollmann, N.; Klassen, I. Journal of Physics: Condensed Matter, Vol. 18, Issue 39 https://doi.org/10.1088/0953-8984/18/39/L01	journal	September 2006
Increasing the Phase-Transition Temperatures in Spin-Frustrated Multiferroic MnWO ₄ by Mo Doping Meddar, Lynda; Josse, Michaël; Maglione, Mario Chemistry of Materials, Vol. 24, Issue 2 https://doi.org/10.1021/cm2031653	journal	December 2011
Local symmetry and magnetic anisotropy in multiferroic ${MnWO}_{4}$ and antiferromagnetic ${CoWO}_{4}$ studied by soft x-ray absorption spectroscopy Hollmann, N.; Hu, Z.; Willers, T. Physical Review B, Vol. 82, Issue 18 https://doi.org/10.1103/PhysRevB.82.184429	journal	November 2010
A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh) Wills, A. S. Physica B: Condensed Matter, Vol. 276-278 https://doi.org/10.1016/S0921-4526(99)01722-6	journal	March 2000
Phonon and magnetic properties of nanocrystalline MnWO4 prepared by hydrothermal method Mączka, Mirosław; Ptak, Maciej; Pikul, Adam Vibrational Spectroscopy, Vol. 58 https://doi.org/10.1016/j.vibspec.2011.12.010	journal	January 2012
Magnetic structure of manganesetungstate MnWO4 at 4.2°K Dachs, H.; Weitzel, H.; Stoll, E. Solid State Communications, Vol. 4, Issue 9 https://doi.org/10.1016/0038-1098(66)90333-4	journal	September 1966
Rietveld refinement of Debye–Scherrer synchrotron X-ray data from Al ₂ O ₃ Thompson, P.; Cox, D. E.; Hastings, J. B. Journal of Applied Crystallography, Vol. 20, Issue 2 https://doi.org/10.1107/S0021889887087090	journal	April 1987
Ultrafine MnWO4 nanoparticles and their magnetic properties Ungelenk, Jan; Roming, Sabine; Adler, Peter Solid State Sciences, Vol. 46 https://doi.org/10.1016/j.solidstatesciences.2015.06.004	journal	August 2015
Incommensurate magnetic structures of multiferroic MnWO $_{4}$ studied within the superspace formalism Urcelay-Olabarria, I.; Perez-Mato, J. M.; Ribeiro, J. L. Physical Review B, Vol. 87, Issue 1 https://doi.org/10.1103/PhysRevB.87.014419	journal	January 2013
Morphology control of MnWO4 nanocrystals by a solvothermal route Chen, Shu-Jian; Chen, Xue-Tai; Xue, Ziling Journal of Materials Chemistry, Vol. 13, Issue 5 https://doi.org/10.1039/b300457k	journal	March 2003
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Long-range magnetic interactions in the multiferroic antiferromagnet MnWO $_{4}$ Ye, Feng; Fishman, Randy S.; Fernandez-Baca, Jaime A. Physical Review B, Vol. 83, Issue 14 https://doi.org/10.1103/PhysRevB.83.140401	journal	April 2011
Spin Current and Magnetoelectric Effect in Noncollinear Magnets Katsura, Hosho; Nagaosa, Naoto; Balatsky, Alexander V. Physical Review Letters, Vol. 95, Issue 5 https://doi.org/10.1103/PhysRevLett.95.057205	journal	July 2005
Correlation between ferroelectric polarization and sense of helical spin order in multiferroic ${MnWO}_{4}$ Sagayama, Hajime; Taniguchi, Kouji; Abe, Nobuyuki Physical Review B, Vol. 77, Issue 22 https://doi.org/10.1103/PhysRevB.77.220407	journal	June 2008
Ion doping effects in multiferroic MnWO ₄ Bahoosh, Safa Golrokh; Wesselinowa, J. M. Journal of Applied Physics, Vol. 111, Issue 8 https://doi.org/10.1063/1.4703913	journal	April 2012

Similar Records

Investigation of the commensurate magnetic structure in the heavy-fermion compound

{CePt}_{2} {In}_{7}

using magnetic resonant x-ray diffraction

Journal Article · Thu Aug 10 00:00:00 EDT 2017 · Physical Review B · OSTI ID:1430608

Gauthier, Nicolas; Wermeille, Didier; Casati, Nicola; +4 more

Nanosized helical magnetic domains in strongly frustrated

{Fe}_{3} {PO}_{4} O_{3}

Journal Article · Mon Oct 26 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:1430608

Ross, K. A.; Bordelon, M. M.; Terho, G.; +1 more

Helical spin dynamics in commensurate magnets: A study on brochantite,

{Cu}_{4} {SO}_{4} {(OH)}_{6}

Journal Article · Thu Aug 17 00:00:00 EDT 2023 · Physical Review Research · OSTI ID:1430608

Nikitin, S. E.; Xie, Tao; Gazizulina, A.; +8 more

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY

Title: Suppression of the commensurate magnetic phase in nanosized hübnerite MnW O 4

Citation Formats

References (35)

Similar Records

Related Subjects

Title: Suppression of the commensurate magnetic phase in nanosized hübnerite $MnW O_{4}$