A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode

Oh, Seung-Min; Oh, Pilgun; Kim, Sang-Ok; Manthiram, Arumugam

doi:10.1149/2.0931702jes

A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode

Journal Article · Thu Dec 29 04:00:00 EST 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0931702jes· OSTI ID:1430255

Oh, Seung-Min ^[1]; Oh, Pilgun ^[2]; Kim, Sang-Ok ^[2]; Manthiram, Arumugam ^[2]

Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program & Texas Materials Inst.; None
Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program & Texas Materials Inst.

A low-cost sodium-ion full cell with a O3-type layered Na[Cu_0.2(Fe_1/3Mn2/3)_0.8]O₂ cathode and an alloy-type P-TiP2-C anode is presented. The cathode is synthesized by an oxalate coprecipitation method and optimized cathodes shows a high specific capacity of 135 mAh g^-1 at 0.1C rate with a high rate capability of 90 mAh g-1 at 1C rate and 70 mAh g^-1 at 2C rate with good cyclability. The full cell exhibits better capacity retention than the half cell with the cathode due to the elimination of the degradation caused by sodium-metal anode. The dramatically enhanced electrochemical performance of the Na[Cu_0.2(Fe_1/3Mn_2/3)_0.8]O₂ / P-TiP₂-C full cell compared to that of the sample with no Cu is attributed to the structural stabilization imparted by Cu by suppressing the phase change from the O3 structure to the P3 structure during cycling.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Materials Sciences & Engineering Division

Grant/Contract Number:: SC0005397

OSTI ID:: 1430255

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 2 Vol. 164; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode Mu, Linqin; Xu, Shuyin; Li, Yunming Advanced Materials, Vol. 27, Issue 43 https://doi.org/10.1002/adma.201502449	journal	October 2015
Air-Stable Copper-Based P2-Na _7/9 Cu _2/9 Fe _1/9 Mn _2/3 O ₂ as a New Positive Electrode Material for Sodium-Ion Batteries Li, Yunming; Yang, Zhenzhong; Xu, Shuyin Advanced Science, Vol. 2, Issue 6 https://doi.org/10.1002/advs.201500031	journal	May 2015
Sodium deintercalation from sodium iron oxide Takeda, Yasuo; Nakahara, Kazuaki; Nishijima, Motoaki Materials Research Bulletin, Vol. 29, Issue 6 https://doi.org/10.1016/0025-5408(94)90122-8	journal	June 1994
Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2 Komaba, Shinichi; Takei, Chikara; Nakayama, Tetsuri Electrochemistry Communications, Vol. 12, Issue 3 https://doi.org/10.1016/j.elecom.2009.12.033	journal	March 2010
Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application Kim, Donghan; Lee, Eungje; Slater, Michael Electrochemistry Communications, Vol. 18 https://doi.org/10.1016/j.elecom.2012.02.020	journal	January 2012
NaFe0.5Co0.5O2 as high energy and power positive electrode for Na-ion batteries Yoshida, Hiroaki; Yabuuchi, Naoaki; Komaba, Shinichi Electrochemistry Communications, Vol. 34 https://doi.org/10.1016/j.elecom.2013.05.012	journal	September 2013
A new phenomenon in sodium batteries: Voltage step due to solvent interaction Rudola, Ashish; Aurbach, Doron; Balaya, Palani Electrochemistry Communications, Vol. 46 https://doi.org/10.1016/j.elecom.2014.06.008	journal	September 2014
P2-type layered Na0.45Ni0.22Co0.11Mn0.66O2 as intercalation host material for lithium and sodium batteries Buchholz, Daniel; Chagas, Luciana Gomes; Winter, Martin Electrochimica Acta, Vol. 110 https://doi.org/10.1016/j.electacta.2013.02.109	journal	November 2013
P2-type Na0.67Mn0.65Fe0.2Ni0.15O2 Cathode Material with High-capacity for Sodium-ion Battery Yuan, Dingding; Hu, Xiaohong; Qian, Jiangfeng Electrochimica Acta, Vol. 116 https://doi.org/10.1016/j.electacta.2013.10.211	journal	January 2014
Lithium batteries: Status, prospects and future Scrosati, Bruno; Garche, Jürgen Journal of Power Sources, Vol. 195, Issue 9 https://doi.org/10.1016/j.jpowsour.2009.11.048	journal	May 2010
Na4Co3(PO4)2P2O7: A novel storage material for sodium-ion batteries Nose, Masafumi; Nakayama, Hideki; Nobuhara, Kunihiro Journal of Power Sources, Vol. 234 https://doi.org/10.1016/j.jpowsour.2013.01.162	journal	July 2013
Physicochemical properties of NaxCoO2 as a cathode for solid state sodium battery Bhide, Amrtha; Hariharan, K. Solid State Ionics, Vol. 192, Issue 1 https://doi.org/10.1016/j.ssi.2010.04.022	journal	June 2011
High-Performance Red P-Based P–TiP ₂ –C Nanocomposite Anode for Lithium-Ion and Sodium-Ion Storage Kim, Sang-Ok; Manthiram, Arumugam Chemistry of Materials, Vol. 28, Issue 16 https://doi.org/10.1021/acs.chemmater.6b02482	journal	August 2016
Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi _{¹ / ₃} Mn _{¹ / ₃} Co _{¹ / ₃} O ₂ Sathiya, M.; Hemalatha, K.; Ramesha, K. Chemistry of Materials, Vol. 24, Issue 10 https://doi.org/10.1021/cm300466b	journal	April 2012
High Capacity O3-Type Na[Li _0.05 (Ni _0.25 Fe _0.25 Mn _0.5 ) _0.95 ]O ₂ Cathode for Sodium Ion Batteries Oh, Seung-Min; Myung, Seung-Taek; Hwang, Jang-Yeon Chemistry of Materials, Vol. 26, Issue 21 https://doi.org/10.1021/cm502481b	journal	October 2014
Study on the Reversible Electrode Reaction of Na _{1– x} Ni _0.5 Mn _0.5 O ₂ for a Rechargeable Sodium-Ion Battery Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri Inorganic Chemistry, Vol. 51, Issue 11 https://doi.org/10.1021/ic300357d	journal	May 2012
Role of Ligand-to-Metal Charge Transfer in O3-Type NaFeO ₂ –NaNiO ₂ Solid Solution for Enhanced Electrochemical Properties Wang, Xianfen; Liu, Guandong; Iwao, Tatsumi The Journal of Physical Chemistry C, Vol. 118, Issue 6 https://doi.org/10.1021/jp411382r	journal	January 2014
Advanced Na[Ni _0.25 Fe _0.5 Mn _0.25 ]O ₂ /C–Fe ₃ O ₄ Sodium-Ion Batteries Using EMS Electrolyte for Energy Storage Oh, Seung-Min; Myung, Seung-Taek; Yoon, Chong Seung Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl500077v	journal	February 2014
Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries Hwang, Jang-Yeon; Oh, Seung-Min; Myung, Seung-Taek Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7865	journal	April 2015
Electrochemical investigation of the P2–NaxCoO2 phase diagram Berthelot, R.; Carlier, D.; Delmas, C. Nature Materials, Vol. 10, Issue 1 https://doi.org/10.1038/nmat2920	journal	December 2010
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
A layer-structured Na2CoP2O7 pyrophosphate cathode for sodium-ion batteries Barpanda, Prabeer; Lu, Jiechen; Ye, Tian RSC Advances, Vol. 3, Issue 12 https://doi.org/10.1039/C3RA23026K	journal	January 2013
Layered Na0.71CoO2: a powerful candidate for viable and high performance Na-batteries D'Arienzo, Massimiliano; Ruffo, Riccardo; Scotti, Roberto Physical Chemistry Chemical Physics, Vol. 14, Issue 17 https://doi.org/10.1039/c2cp40699c	journal	January 2012
An advanced sodium-ion rechargeable battery based on a tin–carbon anode and a layered oxide framework cathode Oh, Seung-Min; Myung, Seung-Taek; Jang, Min-Woo Physical Chemistry Chemical Physics, Vol. 15, Issue 11 https://doi.org/10.1039/c3cp00070b	journal	January 2013
Synthesis and electrochemical behaviors of layered Na0.67[Mn0.65Co0.2Ni0.15]O2 microflakes as a stable cathode material for sodium-ion batteries Yuan, Dingding; He, Wei; Pei, Feng Journal of Materials Chemistry A, Vol. 1, Issue 12 https://doi.org/10.1039/c3ta01430d	journal	January 2013
A new polymorph of Na2MnP2O7 as a 3.6 V cathode material for sodium-ion batteries Barpanda, Prabeer; Ye, Tian; Avdeev, Maxim Journal of Materials Chemistry A, Vol. 1, Issue 13 https://doi.org/10.1039/c3ta10210f	journal	January 2013
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Electrochemical Properties of NaCuO2 for Sodium-Ion Secondary Batteries Ono, Y.; Yui, Y.; Hayashi, M. ECS Transactions, Vol. 58, Issue 12 https://doi.org/10.1149/05812.0033ecst	journal	February 2014
In Situ X-Ray Diffraction Study of P2-Na[sub 2/3][Ni[sub 1/3]Mn[sub 2/3]]O[sub 2] Lu, Zhonghua; Dahn, J. R. Journal of The Electrochemical Society, Vol. 148, Issue 11 https://doi.org/10.1149/1.1407247	journal	January 2001
Electrochemically Reversible Sodium Intercalation of Layered NaNi0.5Mn0.5O2 and NaCrO2 Komaba, Shinichi; Nakayama, Tetsuri; Ogata, Atsushi 214th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3112727	conference	January 2009
Electrochemical Na-Deintercalation from NaVO2 Didier, C.; Guignard, M.; Denage, C. Electrochemical and Solid-State Letters, Vol. 14, Issue 5 https://doi.org/10.1149/1.3555102	journal	January 2011
NaCrO2 is a Fundamentally Safe Positive Electrode Material for Sodium-Ion Batteries with Liquid Electrolytes Xia, Xin; Dahn, J. R. Electrochemical and Solid-State Letters, Vol. 15, Issue 1 https://doi.org/10.1149/2.002201esl	journal	January 2012
On the Comparative Stability of Li and Na Metal Anode Interfaces in Conventional Alkyl Carbonate Electrolytes Iermakova, D. I.; Dugas, R.; Palacín, M. R. Journal of The Electrochemical Society, Vol. 162, Issue 13 https://doi.org/10.1149/2.0091513jes	journal	January 2015
Synthesis and Electrode Performance of O3-Type NaFeO ₂ -NaNi _1/2 Mn _1/2 O ₂ Solid Solution for Rechargeable Sodium Batteries Yabuuchi, Naoaki; Yano, Masaya; Yoshida, Hiroaki Journal of The Electrochemical Society, Vol. 160, Issue 5 https://doi.org/10.1149/2.018305jes	journal	January 2013
Structural and Electrochemical Characterizations of P2 and New O3-Na _x Mn _1-y Fe _y O ₂ Phases Prepared by Auto-Combustion Synthesis for Na-Ion Batteries Mortemard de Boisse, B.; Carlier, D.; Guignard, M. Journal of The Electrochemical Society, Vol. 160, Issue 4 https://doi.org/10.1149/2.032304jes	journal	January 2013
Crystal Structures and Electrode Performance of Alpha-NaFeO2 for Rechargeable Sodium Batteries Yabuuchi, Naoaki; Yoshida, Hiroaki; Komaba, Shinichi Electrochemistry, Vol. 80, Issue 10 https://doi.org/10.5796/electrochemistry.80.716	journal	January 2012

Cited By (5)

High Energy Density Sodium-Ion Battery with Industrially Feasible and Air-Stable O3-Type Layered Oxide Cathode Deng, Jianqiu; Luo, Wen-Bin; Lu, Xiao Advanced Energy Materials, Vol. 8, Issue 5 https://doi.org/10.1002/aenm.201701610	journal	October 2017
Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium‐Ion Batteries Liu, Qiannan; Hu, Zhe; Chen, Mingzhe Small, Vol. 15, Issue 32 https://doi.org/10.1002/smll.201805381	journal	February 2019
Nonaqueous Sodium‐Ion Full Cells: Status, Strategies, and Prospects Niu, Yu‐Bin; Yin, Ya‐Xia; Guo, Yu‐Guo Small, Vol. 15, Issue 32 https://doi.org/10.1002/smll.201900233	journal	March 2019
High performance manganese-based layered oxide cathodes: overcoming the challenges of sodium ion batteries Ortiz-Vitoriano, Nagore; Drewett, Nicholas E.; Gonzalo, Elena Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/c7ee00566k	journal	January 2017
Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities Rahman, Muhammad Mominur; Xu, Yahong; Cheng, Hao Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/c8ee00309b	journal	January 2018

Similar Records

N-doped Fe₃C@C as an efficient polyselenide reservoir for high-performance sodium-selenium batteries

Journal Article · Sat Jun 15 00:00:00 EDT 2019 · Energy Storage Materials · OSTI ID:1598239

LiCoO₂-Based Fiber Cathodes for Electrospun Full Cell Li-ion Batteries

Journal Article · Tue Aug 09 00:00:00 EDT 2016 · Electrochimica Acta · OSTI ID:1435796

Yolk-shell structured Sb@C anodes for high energy Na-ion batteries

Journal Article · Mon Sep 04 00:00:00 EDT 2017 · Nano Energy · OSTI ID:1379956

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
Sodium-ion batteries
alloy anodes
full cell
layered cathodes

A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode

Citation Formats

References (36)

Cited By (5)

Similar Records

Related Subjects