Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst

Palermo, Andrew; Solovyov, Andrew; Ertler, Daniel; Okrut, Alexander; Gates, Bruce C.; Katz, Alexander

doi:10.1039/c7sc00686a

Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst

Journal Article · Thu May 04 00:00:00 EDT 2017 · Chemical Science

DOI:https://doi.org/10.1039/c7sc00686a· OSTI ID:1429914

Palermo, Andrew ^[1]; Solovyov, Andrew ^[2]; Ertler, Daniel ^[2]; Okrut, Alexander ^[2]; Gates, Bruce C. ^[3]; ^[3]

Univ. of California, Davis, CA (United States); University of California, Davis
Univ. of California, Berkeley, CA (United States)
Univ. of California, Davis, CA (United States)

A closed Ir₄carbonyl cluster,1, comprising a tetrahedral metal frame and threetert-butyl-calix[4]arene(OPr)₃(OCH₂PPh₂) (Ph = phenyl; Pr = propyl) ligands at the basal plane, was silica supported and consists of “*” and “S” sites, which could be dialed in selectively for controlling ethylene hydrogenation catalysis.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Davis, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FG02-04ER15513; FG02-05ER15696

OSTI ID:: 1429914

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 7 Vol. 8; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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