Investigation of Glutaric Anhydride as an Electrolyte Additive for Graphite/LiNi 0.5 Mn 0.3 Co 0.2 O 2 Full Cells

Peebles, Cameron; He, Meinan; Feng, Zhenxing; Su, Chi-Cheung; Zeng, Li; Bedzyk, Michael J.; Fenter, Paul; Wang, Yan; Zhang, Zhengcheng; Liao, Chen

doi:10.1149/2.0721702jes

Investigation of Glutaric Anhydride as an Electrolyte Additive for Graphite/LiNi _0.5 Mn _0.3 Co _0.2 O ₂ Full Cells

Journal Article · Fri Dec 16 23:00:00 EST 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0721702jes· OSTI ID:1429907

Peebles, Cameron; He, Meinan; Feng, Zhenxing; Su, Chi-Cheung; Zeng, Li; Bedzyk, Michael J.; Fenter, Paul; Wang, Yan; Zhang, Zhengcheng; Liao, Chen

The effects of glutaric anhydride (GA) as an electrolyte additive for graphite/LiNi0.5Mn0.3Co0.2O2 full cells operating between 3.0-4.4 V were investigated. Linear scan voltammetry (LSV) revealed that GA preferentially oxidized prior to the carbonate-based electrolyte while Li/graphite half cells revealed that GA can suppress electrolyte decomposition on the graphite electrode giving rise to the bifunctional nature of this additive. The addition of both 0.5 and 1.0 wt% of GA into the carbonate-based electrolyte resulted in superior cycling performance compared to the baseline electrolyte as demonstrated by the slight increase in initial capacities and significant increases in capacity retention over 117 cycles at C/3. Electrochemical impedance spectroscopy (EIS) showed that while the overall impedance of the GA containing cells was higher than the cells with the baseline electrolyte the change in impedance between post-formation and post-cycling was smallest for the cells containing GA. Additionally, X-ray photoelectron spectroscopy (XPS) analysis confirmed that GA decomposed on the cathode surface leading to an increase in oxygen-containing species, a decrease in LiF species and a simultaneous increase in LixPOyFz species. (C) 2016 The Electrochemical Society. All rights reserved.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1429907

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 2 Vol. 164; ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

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Investigation of Glutaric Anhydride as an Electrolyte Additive for Graphite/LiNi _0.5 Mn _0.3 Co _0.2 O ₂ Full Cells