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Experimental Determination of Stability Constant of Ferrous Iron Borate Complex [FeB(OH)4+] at 25°C from Solubility Measurements.

Journal Article · · Chemical Geology
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  1. Sandia National Lab. (SNL-NM), Carlsbad, NM (United States)
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The stability constant of FeB(OH)4+ is expected to find applications in many areas of study. For instance, FeB(OH)4+ may have played an important role in transport of ferrous iron in reducing water bodies at the surface of the primitive Earth. In the nearfield of geological repositories, the formation of FeB(OH)4+ can sequestrate soluble borate, lowering borate concentrations available to the formation of the Am(III)-borate aqueous complex.
Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Environmental Management (EM)
Grant/Contract Number:
AC04-94AL85000; NA0003525
OSTI ID:
1429703
Alternate ID(s):
OSTI ID: 1566169
Report Number(s):
SAND--2017-13064J; PII: S0009254118302353
Journal Information:
Chemical Geology, Journal Name: Chemical Geology Vol. 493; ISSN 0009-2541
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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