Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks

Zhang, Liangliang; Yuan, Shuai; Feng, Liang; Guo, Bingbing; Qin, Jun‐Sheng; Xu, Ben; Lollar, Christina; Sun, Daofeng; Zhou, Hong‐Cai

doi:10.1002/anie.201802661

Title: Pore‐Environment Engineering with Multiple Metal Sites in Rare‐Earth Porphyrinic Metal–Organic Frameworks

Journal Article · Sat Mar 24 00:00:00 EDT 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201802661· OSTI ID:1429520

Zhang, Liangliang ^[1]; Yuan, Shuai ^[2];

^[2]; Guo, Bingbing ^[1]; Qin, Jun‐Sheng ^[2]; Xu, Ben ^[1]; Lollar, Christina ^[2]; Sun, Daofeng ^[1];

^[3]

College of Science China University of Petroleum (East China) Qingdao Shandong 266580 China
Department of Chemistry Texas A&,M University College Station TX 77843 USA
Department of Chemistry Texas A&,M University College Station TX 77843 USA, Department of Materials Science and Engineering Texas A&,M University College Station TX 77842 USA

Abstract Multi‐component metal–organic frameworks (MOFs) with precisely controlled pore environments are highly desired owing to their potential applications in gas adsorption, separation, cooperative catalysis, and biomimetics. A series of multi‐component MOFs, namely PCN‐900(RE), were constructed from a combination of tetratopic porphyrinic linkers, linear linkers, and rare‐earth hexanuclear clusters (RE ₆ ) under the guidance of thermodynamics. These MOFs exhibit high surface areas (up to 2523 cm ² g ⁻¹ ) and unlimited tunability by modification of metal nodes and/or linker components. Post‐synthetic exchange of linear linkers and metalation of two organic linkers were realized, allowing the incorporation of a wide range of functional moieties. Two different metal sites were sequentially placed on the linear linker and the tetratopic porphyrinic linker, respectively, giving rise to an ideal platform for heterogeneous catalysis.

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Sponsoring Organization:: USDOE

OSTI ID:: 1429520

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 57 Journal Issue: 18; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 122 works

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