The Application of Poly(3-hexylthiophene-2,5-diyl) as a Protective Coating for High Rate Cathode Materials

Lai, Chun-Han; Ashby, David S.; Lin, Terri C.; Lau, Jonathon; Dawson, Andrew; Tolbert, Sarah H.; Dunn, Bruce S.

doi:10.1021/acs.chemmater.7b05116

Title: The Application of Poly(3-hexylthiophene-2,5-diyl) as a Protective Coating for High Rate Cathode Materials

Journal Article · Tue Apr 03 00:00:00 EDT 2018 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.7b05116· OSTI ID:1427969

^[1]; Ashby, David S. ^[1]; Lin, Terri C. ^[2]; Lau, Jonathon ^[1]; Dawson, Andrew ^[2]; Tolbert, Sarah H. ^[3]; Dunn, Bruce S. ^[4]

Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry
Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering and The California NanoSystems Inst.
Univ. of California, Los Angeles, CA (United States). The California NanoSystems Inst.

Poly (3-hexylthiophene-2,5-diyl) (P3HT), a conducting polymer studied extensively for its optoelectronic devices, offers a number of advantageous properties when used as a conductive binder for lithium-ion battery cathode materials. By mixing with carbon nanotubes (CNT), P3HTCNT serves as a surface coating for the cathode material LiNi_0.8Co_0.15Al_0.05O₂ (NCA). Oxidation of the P3HT enables high electronic and ionic conductivity to be achieved over the potential range where the NCA is electrochemically active. In addition to the conductivity benefits from electrochemical doping, the P3HT-CNT coating suppresses electrolyte breakdown, thus inhibiting growth of the solid electrolyte interphase (SEI) layer and preventing intergranular cracking in the NCA particles. In conclusion, The use of the P3HT-CNT binder system leads to improved cycling for NCA at high power density with capacities of 80 mAh g^-1 obtained after 1000 cycles at 16C, a value that is 4 times greater than what is achieved in the control electrode.

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Research Organization:: Univ. of California, Los Angeles, CA (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR)

Grant/Contract Number:: SC0014213; N00014-16-1-2164; AC02-76SF00515

OSTI ID:: 1427969

Journal Information:: Chemistry of Materials, Vol. 30, Issue 8; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 46 works

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