A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications

Liu, Jian; Zheng, Jian; Barpaga, Dushyant; Sabale, Sandip; Arey, Bruce; Derewinski, Miroslaw A.; McGrail, B. Peter; Motkuri, Radha Kishan

doi:10.1002/ejic.201800042

Title: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications: A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications

Journal Article · Mon Feb 12 00:00:00 EST 2018 · European Journal of Inorganic Chemistry

DOI:https://doi.org/10.1002/ejic.201800042· OSTI ID:1427910

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^[1]; Sabale, Sandip ^[2]; Arey, Bruce ^[3];

^[1]; McGrail, B. Peter ^[1];

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Pacific Northwest National Laboratory, 99352 Richland WA USA
Pacific Northwest National Laboratory, 99352 Richland WA USA; P.G. Department of Chemistry, Jaysingpur College, 416101 Jaysingpur Maharashtra India
Environmental Molecular Sciences Laboratory (EMSL), Pacific Northwest National Laboratory, 99352 Richland WA USA

A mixed metal strategy, in which two different metal nodes coexist in one MOF framework, was examined using MOF-74. The Ni salt precursor for the MOF-74(Ni) analogue was partially replaced during synthesis with relatively inexpensive Zn salt. These bimetallic MOFs were developed and examined for water sorption for potential use in adsorption cooling/chiller applications. Varying concentration ratios of Ni:Zn in MOF-74 achieved using this mixed metal strategy were shown to provide unique impacts on H2O uptake while significantly mitigating the costs of synthesis

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Geothermal Technologies Office

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1427910

Report Number(s):: PNNL-SA-129916; 830403000

Journal Information:: European Journal of Inorganic Chemistry, Vol. 2018, Issue 7; ISSN 1434-1948

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: English

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