Tunable Assembly of Gold Nanorods in Polymer Solutions To Generate Controlled Nanostructured Materials

Poling-Skutvik, Ryan; Lee, Jonghun; Narayanan, Suresh; Krishnamoorti, Ramanan; Conrad, Jacinta C.

doi:10.1021/acsanm.7b00277

Title: Tunable Assembly of Gold Nanorods in Polymer Solutions To Generate Controlled Nanostructured Materials

Journal Article · Wed Jan 17 00:00:00 EST 2018 · ACS Applied Nano Materials

DOI:https://doi.org/10.1021/acsanm.7b00277· OSTI ID:1427771

^[1]; Lee, Jonghun ^[2]; Narayanan, Suresh ^[2];

^[1];

^[1]

University of Houston, TX (United States). Department of Chemical and Biomolecular Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

In this study, gold nanorods grafted with short chain polymers are assembled into controlled open structures using polymer-induced depletion interactions and structurally characterized using small angle x-ray scattering. When the nanorod diameter is smaller than the radius of gyration of the depletant polymer, the depletion interaction depends solely on the correlation length of the polymer solution and not directly on the polymer molecular weight. As the polymer concentration increases, the stronger depletion interactions increasingly compress the grafted chains and push the gold nanorods closer together. By contrast, other structural characteristics such as the number of nearest neighbors and fractal dimension exhibit a non-monotonic dependence on polymer concentration. These parameters are maximal at intermediate concentrations, which are attributed to a crossover from reaction-limited to diffusion-limited aggregation. Finally, the control over structural properties of anisotropic nanoscale building blocks demonstrated here will be beneficial to designing and producing materials in situ with specific direction-dependent nanoscale properties and provides a crucial route for advances in additive manufacturing.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC); Welch Foundation

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1427771

Journal Information:: ACS Applied Nano Materials, Vol. 1, Issue 2; ISSN 2574-0970

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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depletion interactions
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protein limit
small-angle X-ray scattering
ultraviolet−visible spectroscopy

Title: Tunable Assembly of Gold Nanorods in Polymer Solutions To Generate Controlled Nanostructured Materials

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