The broadband rotational spectrum of fully deuterated acetaldehyde (CD3CDO) in a CW supersonic expansion

Zaleski, Daniel P.; Duan, Chuanxi; Carvajal, Miguel; Kleiner, Isabelle; Prozument, Kirill

doi:10.1016/j.jms.2017.01.010

Title: The broadband rotational spectrum of fully deuterated acetaldehyde (CD₃CDO) in a CW supersonic expansion

Journal Article · Thu Feb 09 00:00:00 EST 2017 · Journal of Molecular Spectroscopy

DOI:https://doi.org/10.1016/j.jms.2017.01.010· OSTI ID:1427542

Zaleski, Daniel P. ^[1]; Duan, Chuanxi ^[2]; Carvajal, Miguel ^[3]; Kleiner, Isabelle ^[4]; Prozument, Kirill ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Central China Normal Univ., Wuhan (China). College of Physical Science and Technology
Univ. de Huelva, Huelva (Spain). Dept. Ciencias Integradas, Facultad de Ciencias Experimentales
Universites Paris Est & Paris Diderot, Creteil cedex (France). Laboratoire Interuniversitaire des Systemes Atmospheriques (LISA)

The broadband pure rotational spectra of CD₃CDO, ¹³CD₃CDO, CD₃ ¹³CDO, and CD₃CD¹⁸O have been recorded using a BrightSpec W-Band (75–110 GHz) chirped-pulse Fourier transform millimeter wave (CP-FTmmW) spectrometer. The sample was enriched with deuterium, whereas the ¹³C and ¹⁸O isotopologues were observed in natural abundance (with respect to the enriched fully deuterated parent containing ¹²C and ¹⁶O). The analysis of the spectra is described and the derived molecular constants are compared to those of known acetaldehyde isotopologues. Furthermore, we have demonstrated the ability to record rotational spectra in a steady-state “CW” supersonic expansion with a duty cycle of 80%. Finally, the advantages and limitations of the segmented chirp spectrometer coupled with a CW molecular source as well as design of the vacuum and pumping system are discussed.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Natural Science Foundation of China (NSFC); Spanish Ministerio de Economia y Competitividad (MINECO)

Grant/Contract Number:: AC02-06CH11357; 11574107

OSTI ID:: 1427542

Alternate ID(s):: OSTI ID: 1495570

Journal Information:: Journal of Molecular Spectroscopy, Vol. 342, Issue C; ISSN 0022-2852

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
42 ENGINEERING
Acetaldehyde
ChirpedPulse
Internal Rotation
Millimeter Wave
Rotational Spectroscopy
Supersonic Expansion

Title: The broadband rotational spectrum of fully deuterated acetaldehyde (CD3CDO) in a CW supersonic expansion

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Title: The broadband rotational spectrum of fully deuterated acetaldehyde (CD₃CDO) in a CW supersonic expansion