skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Methodology for understanding interactions between electrolyte additives and cathodes: a case of the tris(2,2,2-trifluoroethyl)phosphite additive

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/C7TA08289D· OSTI ID:1427486

Both experiments and theory show that TTFP does not passivate NMC532 cathode surface towards electrolyte oxidation.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1427486
Journal Information:
Journal of Materials Chemistry. A, Vol. 6, Issue 1; ISSN 2050-7488
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 21 works
Citation information provided by
Web of Science

References (58)

Generalized Gradient Approximation Made Simple journal October 1996
The formation of cation-ligand complexes of tributylammonium cation with diethyl carbonate, ethylene carbonate, propylene carbonate, 4-butyrolactone, ethyl acetate, and cyclopentanone ino-dichlorobenzene at 25�C journal December 1979
Lithium Batteries and Cathode Materials journal October 2004
Projector augmented-wave method journal December 1994
Liquid Chromatography-Quadruple Time of Flight Mass Spectrometry Analysis of Products in Degraded Lithium-Ion Batteries journal January 2015
Study of Electrolyte Components in Li Ion Cells Using Liquid-Liquid Extraction and Gas Chromatography Coupled with Mass Spectrometry journal January 2014
The effects of FePO4-coating on high-voltage cycling stability and rate capability of Li[Ni0.5Co0.2Mn0.3]O2 journal November 2012
Mechanistic Insight in the Function of Phosphite Additives for Protection of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode in High Voltage Li-Ion Cells journal April 2016
Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries journal May 2016
Effect of Added LiBOB on High Voltage (LiNi0.5Mn1.5O4) Spinel Cathodes journal January 2011
Rates and mechanisms of hydrolysis of esters of phosphorous acid journal January 1988
Adsorption of CO 2 on Graphene: A Combined TPD, XPS, and vdW-DF Study journal January 2017
Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries journal January 2010
Predicting and Extending the Lifetime of Li-Ion Batteries journal January 2013
Tris(2,2,2-trifluoroethyl) phosphite as an electrolyte additive for high-voltage lithium-ion batteries using lithium-rich layered oxide cathode journal November 2015
Surface Structure, Morphology, and Stability of Li(Ni 1/3 Mn 1/3 Co 1/3 )O 2 Cathode Material journal April 2017
Tris(trimethylsilyl) Phosphite (TMSPi) and Triethyl Phosphite (TEPi) as Electrolyte Additives for Lithium Ion Batteries: Mechanistic Insights into Differences during LiNi 0.5 Mn 0.3 Co 0.2 O 2 -Graphite Full Cell Cycling journal January 2017
Qualitative and quantitative investigation of organophosphates in an electrochemically and thermally treated lithium hexafluorophosphate-based lithium ion battery electrolyte by a developed liquid chromatography-tandem quadrupole mass spectrometry method journal January 2016
Identification and formation mechanism of individual degradation products in lithium-ion batteries studied by liquid chromatography/electrospray ionization mass spectrometry and atmospheric solid analysis probe mass spectrometry: Identification of degradation products in LIBs by LC/ESI-MS and ASAP-MS journal July 2016
Aging characteristics of high-power lithium-ion cells with LiNi0.8Co0.15Al0.05O2 and Li4/3Ti5/3O4 electrodes journal October 2005
Characterization of Lithium Alkyl Carbonates by X-ray Photoelectron Spectroscopy: Experimental and Theoretical Study journal August 2005
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries journal January 1998
Ab initiomolecular dynamics for liquid metals journal January 1993
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal October 2004
Tris(hexafluoro-iso-propyl)phosphate as an SEI-Forming Additive on Improving the Electrochemical Performance of the Li[Li 0.2 Mn 0.56 Ni 0.16 Co 0.08 ]O 2 Cathode Material journal December 2012
Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells journal June 2012
Investigation of thermal aging and hydrolysis mechanisms in commercial lithium ion battery electrolyte journal November 2013
Higher, Stronger, Better…︁ A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries journal June 2012
Adsorption of water on thin V2O3(0001) films journal March 2006
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal September 2010
Studies on capacity fade of lithium-ion batteries journal December 2000
Ageing mechanisms in lithium-ion batteries journal September 2005
Complexes of the platinum metals containing weak donor ligands journal February 1981
Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte journal July 2015
First-Principles Analysis of Phase Stability in Layered–Layered Composite Cathodes for Lithium-Ion Batteries journal March 2014
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis journal June 1977
Review—Chemical Analysis for a Better Understanding of Aging and Degradation Mechanisms of Non-Aqueous Electrolytes for Lithium Ion Batteries: Method Development, Application and Lessons Learned journal January 2015
Improvement of structural and electrochemical properties of AlF3-coated Li[Ni1/3Co1/3Mn1/3]O2 cathode materials on high voltage region journal April 2008
Electrolyte additives for lithium ion battery electrodes: progress and perspectives journal January 2016
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Graphite-Filled Poly(vinylidene fluoride) (PVdF) by XPS journal April 1999
Phosphorus incorporation during Si(001):P gas-source molecular beam epitaxy: Effects on growth kinetics and surface morphology journal June 2008
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells journal December 2016
Evaluation of Electrolyte Oxidation Stability on Charged LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Surface through Potentiostatic Holds journal January 2016
Inner-orbital photoelectron spectroscopy of the alkali metal halides, perchlorates, phosphates, and pyrophosphates journal February 1973
Effect of lithium difluoro(oxalate)borate (LiDFOB) additive on the performance of high-voltage lithium-ion batteries journal March 2012
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal February 2006
Challenges in the development of advanced Li-ion batteries: a review journal January 2011
The Role of Additives in Improving Performance in High Voltage Lithium-Ion Batteries with Potentiostatic Holds journal January 2017
Comparison of Metal Ion Dissolutions from Lithium Ion Battery Cathodes journal January 2006
Lithium-Ion Batteries: Thermal Reactions of Electrolyte with the Surface of Metal Oxide Cathode Particles journal January 2006
Interpreting High Precision Coulometry Results on Li-ion Cells journal January 2011
Evidence of Transition-Metal Accumulation on Aged Graphite Anodes by SIMS journal January 2008
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries journal August 2013
Improvement of the high-temperature, high-voltage cycling performance of LiNi0.5Co0.2Mn0.3O2 cathode with TiO2 coating journal December 2012
A novel electrolyte with the ability to form a solid electrolyte interface on the anode and cathode of a LiMn2O4/graphite battery journal January 2013
Enhancing the High-Voltage Cycling Performance of LiNi 0.5 Mn 0.3 Co 0.2 O 2 by Retarding Its Interfacial Reaction with an Electrolyte by Atomic-Layer-Deposited Al 2 O 3 journal November 2015
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal March 2014

Cited By (3)

Highly Improved Cycling Stability of Anion De-/Intercalation in the Graphite Cathode for Dual-Ion Batteries journal November 2018
3-(Phenylsulfonyl)propionitrile as a higher voltage bifunctional electrolyte additive to improve the performance of lithium-ion batteries journal January 2018
Decomposition of Phosphorus-Containing Additives at a Charged NMC Surface through Potentiostatic Holds journal January 2019