Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Ordonez, Carlos; Kinnibrugh, Tiffany; Xu, Hongwu; Lindline, Jennifer; Timofeeva, Tatiana; Wei, Qiang

doi:10.3390/cryst5020193

Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

Journal Article · Thu Apr 02 00:00:00 EDT 2015 · Crystals

DOI:https://doi.org/10.3390/cryst5020193· OSTI ID:1426822

Ordonez, Carlos; Kinnibrugh, Tiffany; Xu, Hongwu; Lindline, Jennifer; Timofeeva, Tatiana; Wei, Qiang

The solvothermal synthesis of framework isomers was carried out using the hybrid carboxylate and tetrazolate functional ligand, 4-tetrazolyl benzenecarboxylic acid (H2TBC, TBC = 4-tetrazolyl benzenecarboxylate) and zinc. H2TBC was also synthesized with the solvothermal approach, and is referred herein as structure 1. Using single-crystal X-ray diffraction, we found that the tetrazolate groups of TBC show an unusual “opposite-on” coordination mode with zinc. Three previously characterized metal-organic frameworks (MOFs) were obtained by systematically changing the solvents of the H2TBC-Zn reaction, (1) ZnTBC, 2, which has a non-porous structure; (2) Zn2(TBC)2(H2O), 3, which has an amphiphilic pore structure and (3) Zn2(TBC)2{guest}, 4, which is porous and has channels containing uncoordinated N heteroatoms. Fluorescence spectra of 4 reveal a strong blue emission mainly from the TBC ligands.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

OSTI ID:: 1426822

Alternate ID(s):: OSTI ID: 1208867

Journal Information:: Crystals, Journal Name: Crystals Journal Issue: 2 Vol. 5; ISSN CRYSBC; ISSN 2073-4352

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Germany

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
hybrid ligand
opposite-on coordination
solvothermal technique
tetrazolate

Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach

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