Transparent superhydrophobic surfaces using a spray coating process

Polyzos, Georgios; Jang, Gyoung Gug; Smith, D. Barton; List III, Frederick Alyious; Lassiter, Matthew G.; Park, Jaehyeung; Datskos, Panos G.

doi:10.1016/j.solmat.2017.10.029

Transparent superhydrophobic surfaces using a spray coating process

Journal Article · Fri Nov 03 00:00:00 EDT 2017 · Solar Energy Materials and Solar Cells

DOI:https://doi.org/10.1016/j.solmat.2017.10.029· OSTI ID:1426588

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

One significant maintenance problem and cost associated with solar energy conversion systems is the soiling due to the accumulation of dust and other pollutants. Here in this work, we describe a scalable approach for applying antisoiling coatings based on superhydrophobic (SH) silica particles using a spray coating process. A large water contact angle (WCA) is one of the characteristics of excellent SH surfaces and because of the low surface energy and low adhesion forces the soiling rate is reduced. Our findings indicate that the WCA depends strongly on the ratio of the polymer binder and the nanoparticles. The nanoparticle surface coverage of the spray coated samples was substantially improved after rinsing with solvent. This process tended to remove large aggregates and excess polymer binder and further increased the WCA by allowing exposure of the functionalized nanoparticles. The durability of the SH coatings was enhanced when the substrate was pretreated with polymer binder and an optimal curing time between 30 and 60 min. The abrasion tests of the SH coatings we report in this study showed that the WCA decreased from ~ 166° to ~ 157° after exposure to 2.6 g of sand. Such coatings will help reduce costs of periodic cleaning of solar energy conversion systems (photovoltaic panels and concentrated solar mirrors).

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1426588

Journal Information:: Solar Energy Materials and Solar Cells, Journal Name: Solar Energy Materials and Solar Cells Vol. 176; ISSN 0927-0248

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Superhydrophobic Polypropylene Surfaces Prepared with TiO ₂ Nanoparticles Functionalized by Dendritic Polymers Contreras, Cintia B.; Figueroa, Francisco N.; Weibel, Daniel E. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 56, Issue 18 https://doi.org/10.1002/pola.29086	journal	August 2018
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77 NANOSCIENCE AND NANOTECHNOLOGY
Antisoiling
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Nanoparticles
Optical transmission
Solar
Superhydrophobic

Transparent superhydrophobic surfaces using a spray coating process

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