Time-Resolved Kinetic Chirped-Pulse Rotational Spectroscopy in a Room-Temperature Flow Reactor

Zaleski, Daniel P.; Harding, Lawrence B.; Klippenstein, Stephen J.; Ruscic, Branko; Prozument, Kirill

doi:10.1021/acs.jpclett.7b02864

Title: Time-Resolved Kinetic Chirped-Pulse Rotational Spectroscopy in a Room-Temperature Flow Reactor

Journal Article · Fri Dec 01 00:00:00 EST 2017 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.7b02864· OSTI ID:1426235

^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Chirped-pulse Fourier transform millimeter-wave spectroscopy is a potentially powerful tool for studying chemical reaction dynamics and kinetics. Branching ratios of multiple reaction products and intermediates can be measured with unprecedented chemical specificity; molecular isomers, conformers, and vibrational states have distinct rotational spectra. Here we demonstrate chirped-pulse spectroscopy of vinyl cyanide photoproducts in a flow tube reactor at ambient temperature of 295 K and pressures of 1-10 mu bar. This in situ and time-resolved experiment illustrates the utility of this novel approach to investigating chemical reaction dynamics and kinetics. Following 193 nm photodissociation of CH2CHCN, we observe rotational relaxation of energized HCN, HNC, and HCCCN photoproducts with 10 mu s time resolution and sample the vibrational population distribution of HCCCN. The experimental branching ratio HCN/HCCCN is compared with a model based on RRKM theory using high-level ab initio calculations, which were in turn validated by comparisons to Active Thermochemical Tables enthalpies.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1426235

Journal Information:: Journal of Physical Chemistry Letters, Vol. 8, Issue 24; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 14 works

Citation information provided by
Web of Science

References (75)

Kinetics of polyatomic free radicals produced by laser photolysis. 5. Study of the equilibrium methyl + oxygen .dblarw. CH3O2 between 421 and 538.degree. Slagle, Irene R.; Gutman, David Journal of the American Chemical Society, Vol. 107, Issue 19 https://doi.org/10.1021/ja00305a003	journal	September 1985
The multiplexed chemical kinetic photoionization mass spectrometer: A new approach to isomer-resolved chemical kinetics Osborn, David L.; Zou, Peng; Johnsen, Howard Review of Scientific Instruments, Vol. 79, Issue 10 https://doi.org/10.1063/1.3000004	journal	October 2008
Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO Taatjes, C. A.; Welz, O.; Eskola, A. J. Science, Vol. 340, Issue 6129 https://doi.org/10.1126/science.1234689	journal	April 2013
Kinetics and Products of Vinyl + 1,3-Butadiene, a Potential Route to Benzene Buras, Zachary J.; Dames, Enoch E.; Merchant, Shamel S. The Journal of Physical Chemistry A, Vol. 119, Issue 28 https://doi.org/10.1021/jp512705r	journal	February 2015
Probing the low-temperature chain-branching mechanism of n -butane autoignition chemistry via time-resolved measurements of ketohydroperoxide formation in photolytically initiated n- C 4 H 10 oxidation Eskola, A. J.; Welz, O.; Zádor, J. Proceedings of the Combustion Institute, Vol. 35, Issue 1 https://doi.org/10.1016/j.proci.2014.05.011	journal	January 2015
Vibrational relaxation in seeded supersonic alkali halide beams Mariella, R. P.; Neoh, S. K.; Herschbach, D. R. The Journal of Chemical Physics, Vol. 67, Issue 7 https://doi.org/10.1063/1.435263	journal	October 1977
Collision-induced energy flow between vibrational modes of small polyatomic molecules Flynn, George W. Accounts of Chemical Research, Vol. 14, Issue 11 https://doi.org/10.1021/ar00071a002	journal	November 1981
Vibrational relaxation of linear molecules in a nozzle expansion Deleon, Robert L.; Muenter, J. S. Chemical Physics Letters, Vol. 111, Issue 1-2 https://doi.org/10.1016/0009-2614(84)80453-4	journal	October 1984
Chirped-pulse millimeter-wave spectroscopy for dynamics and kinetics studies of pyrolysis reactions Prozument, Kirill; Barratt Park, G.; Shaver, Rachel G. Phys. Chem. Chem. Phys., Vol. 16, Issue 30 https://doi.org/10.1039/C3CP55352C	journal	January 2014
Observation of Transition-State Vibrational Thresholds in the Rate of Dissociation of Ketene Lovejoy, E. R.; Kim, S. K.; Moore, C. B. Science, Vol. 256, Issue 5063 https://doi.org/10.1126/science.256.5063.1541	journal	June 1992
The Roaming Atom: Straying from the Reaction Path in Formaldehyde Decomposition Townsend, D. Science, Vol. 306, Issue 5699 https://doi.org/10.1126/science.1104386	journal	November 2004
A new approach toward transition state spectroscopy Prozument, Kirill; Shaver, Rachel Glyn; Ciuba, Monika A. Faraday Discussions, Vol. 163 https://doi.org/10.1039/c3fd20160k	journal	January 2013
Determination of the Rate Constant for the OH(X ² Π) + OH(X ² Π) → H ₂ O + O( ³ P) Reaction Over the Temperature Range 295 to 701 K Altinay, Gokhan; Macdonald, R. Glen The Journal of Physical Chemistry A, Vol. 118, Issue 1 https://doi.org/10.1021/jp409344q	journal	December 2013
Three-center versus four-center elimination in photolysis of vinyl fluoride and vinyl bromide at 193 nm: Bimodal rotational distribution of HF and HBr (v⩽5) detected with time-resolved Fourier transform spectroscopy Lin, Shiaw-Ruey; Lin, Shih-Che; Lee, Yu-Chang The Journal of Chemical Physics, Vol. 114, Issue 17 https://doi.org/10.1063/1.1343079	journal	May 2001
Photodissociation of vinyl cyanide at 193 nm: Nascent product distributions of the molecular elimination channels Wilhelm, Michael J.; Nikow, Matthew; Letendre, Laura The Journal of Chemical Physics, Vol. 130, Issue 4 https://doi.org/10.1063/1.3065986	journal	January 2009
Photolysis (193 nm) of SO ₂ : Nascent Product Energy Distribution Examined through IR Emission Ma, Jianqiang; Wilhelm, Michael J.; Smith, Jonathan M. The Journal of Physical Chemistry A, Vol. 116, Issue 1 https://doi.org/10.1021/jp2061943	journal	December 2011
Direct frequency comb measurement of OD + CO -> DOCO kinetics Bjork, B. J.; Bui, T. Q.; Heckl, O. H. Science, Vol. 354, Issue 6311 https://doi.org/10.1126/science.aag1862	journal	October 2016
Application of Microwave Spectroscopy to Kinetic Study of the Reaction of Carbonyl Sulfide with Atomic Oxygen Yoshida, Noritetsu; Saito, Shuji Bulletin of the Chemical Society of Japan, Vol. 51, Issue 6 https://doi.org/10.1246/bcsj.51.1635	journal	June 1978
Millimeter‐wave detection of free radicals using pulsed laser photolysis Kolbe, W. F.; Leskovar, B. Review of Scientific Instruments, Vol. 56, Issue 8 https://doi.org/10.1063/1.1138156	journal	August 1985
Millimeter- and Submillimeter-wave Kinetic Spectroscopy of Reaction Intermediates Endo, Yasuki; Kanamori, Hideto; Hirota, Eizi Laser Chemistry, Vol. 7, Issue 2-4 https://doi.org/10.1155/LC.7.61	journal	January 1987
Branching ratios in atomic oxygen (3P) reactions of terminal olefins studied by kinetic microwave absorption spectroscopy Koda, Seiichiro; Endo, Yasuki; Tsuchiya, Soji The Journal of Physical Chemistry, Vol. 95, Issue 3 https://doi.org/10.1021/j100156a038	journal	February 1991
The rotational spectrum of epifluorohydrin measured by chirped-pulse Fourier transform microwave spectroscopy Brown, Gordon G.; Dian, Brian C.; Douglass, Kevin O. Journal of Molecular Spectroscopy, Vol. 238, Issue 2 https://doi.org/10.1016/j.jms.2006.05.003	journal	August 2006
A broadband Fourier transform microwave spectrometer based on chirped pulse excitation Brown, Gordon G.; Dian, Brian C.; Douglass, Kevin O. Review of Scientific Instruments, Vol. 79, Issue 5 https://doi.org/10.1063/1.2919120	journal	May 2008
Measuring Picosecond Isomerization Kinetics via Broadband Microwave Spectroscopy Dian, B. C.; Brown, G. G.; Douglass, K. O. Science, Vol. 320, Issue 5878 https://doi.org/10.1126/science.1155736	journal	May 2008
Conformational isomerization kinetics of pent-1-en-4-yne with 3,330 cm-1 of internal energy measured by dynamic rotational spectroscopy Dian, B. C.; Brown, G. G.; Douglass, K. O. Proceedings of the National Academy of Sciences, Vol. 105, Issue 35 https://doi.org/10.1073/pnas.0800520105	journal	August 2008
Broadband Molecular Rotational Spectroscopy Special Issue Pate, Brooks H.; De Lucia, Frank C. Journal of Molecular Spectroscopy, Vol. 280 https://doi.org/10.1016/j.jms.2012.08.003	journal	October 2012
Structures of Cage, Prism, and Book Isomers of Water Hexamer from Broadband Rotational Spectroscopy Perez, C.; Muckle, M. T.; Zaleski, D. P. Science, Vol. 336, Issue 6083 https://doi.org/10.1126/science.1220574	journal	May 2012
A Ka-band chirped-pulse Fourier transform microwave spectrometer Zaleski, Daniel P.; Neill, Justin L.; Muckle, Matt T. Journal of Molecular Spectroscopy, Vol. 280 https://doi.org/10.1016/j.jms.2012.07.014	journal	October 2012
Broadband Rotational Spectroscopy for Molecular Structure and Dynamics Studies Schnell, Melanie Zeitschrift für Physikalische Chemie, Vol. 227, Issue 1 https://doi.org/10.1524/zpch.2012.0213	journal	January 2013
Perspective: The first ten years of broadband chirped pulse Fourier transform microwave spectroscopy Park, G. Barratt; Field, Robert W. The Journal of Chemical Physics, Vol. 144, Issue 20 https://doi.org/10.1063/1.4952762	journal	May 2016
Design and evaluation of a pulsed-jet chirped-pulse millimeter-wave spectrometer for the 70–102 GHz region Park, G. Barratt; Steeves, Adam H.; Kuyanov-Prozument, Kirill The Journal of Chemical Physics, Vol. 135, Issue 2 https://doi.org/10.1063/1.3597774	journal	July 2011
Chirped-pulse terahertz spectroscopy for broadband trace gas sensing Gerecht, Eyal; Douglass, Kevin O.; Plusquellic, David F. Optics Express, Vol. 19, Issue 9 https://doi.org/10.1364/OE.19.008973	journal	January 2011
An arbitrary waveform generator based chirped pulse Fourier transform spectrometer operating from 260 to 295GHz Steber, Amanda L.; Harris, Brent J.; Neill, Justin L. Journal of Molecular Spectroscopy, Vol. 280 https://doi.org/10.1016/j.jms.2012.07.015	journal	October 2012
Concerted hydrogen-bond breaking by quantum tunneling in the water hexamer prism Richardson, J. O.; Perez, C.; Lobsiger, S. Science, Vol. 351, Issue 6279 https://doi.org/10.1126/science.aae0012	journal	March 2016
Dissociation Pathways of 2,3-Dihydrofuran Measured by Chirped-Pulse Fourier Transform Microwave Spectroscopy Karunatilaka, Chandana; Shirar, Amanda J.; Storck, Giana L. The Journal of Physical Chemistry Letters, Vol. 1, Issue 10 https://doi.org/10.1021/jz100426c	journal	April 2010
THE DETECTION OF INTERSTELLAR ETHANIMINE (CH ₃ CHNH) FROM OBSERVATIONS TAKEN DURING THE GBT PRIMOS SURVEY Loomis, Ryan A.; Zaleski, Daniel P.; Steber, Amanda L. The Astrophysical Journal, Vol. 765, Issue 1 https://doi.org/10.1088/2041-8205/765/1/L9	journal	February 2013
Exotic SiO ₂ H ₂ Isomers: Theory and Experiment Working in Harmony McCarthy, Michael C.; Gauss, Jürgen The Journal of Physical Chemistry Letters, Vol. 7, Issue 10 https://doi.org/10.1021/acs.jpclett.6b00632	journal	May 2016
A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. II. Performance and applications for reaction dynamics Abeysekera, Chamara; Zack, Lindsay N.; Park, G. Barratt The Journal of Chemical Physics, Vol. 141, Issue 21 https://doi.org/10.1063/1.4903253	journal	December 2014
Chirped-Pulse Fourier Transform Microwave Spectroscopy Coupled with a Flash Pyrolysis Microreactor: Structural Determination of the Reactive Intermediate Cyclopentadienone Kidwell, Nathanael M.; Vaquero-Vara, Vanesa; Ormond, Thomas K. The Journal of Physical Chemistry Letters, Vol. 5, Issue 13 https://doi.org/10.1021/jz5010895	journal	June 2014
A Signature of Roaming Dynamics in the Thermal Decomposition of Ethyl Nitrite: Chirped-Pulse Rotational Spectroscopy and Kinetic Modeling Prozument, Kirill; Suleimanov, Yury V.; Buesser, Beat The Journal of Physical Chemistry Letters, Vol. 5, Issue 21 https://doi.org/10.1021/jz501758p	journal	October 2014
A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. I. The low-temperature flow system Oldham, James M.; Abeysekera, Chamara; Joalland, Baptiste The Journal of Chemical Physics, Vol. 141, Issue 15 https://doi.org/10.1063/1.4897979	journal	October 2014
Photodissociation of acrylonitrile at 193 nm: A photofragment translational spectroscopy study using synchrotron radiation for product photoionization Blank, David A.; Suits, Arthur G.; Lee, Yuan T. The Journal of Chemical Physics, Vol. 108, Issue 14 https://doi.org/10.1063/1.475989	journal	April 1998
The unimolecular dissociation of vinylcyanide: A theoretical investigation of a complex multichannel reaction Derecskei-Kovacs, Agnes; North, Simon W. The Journal of Chemical Physics, Vol. 110, Issue 6 https://doi.org/10.1063/1.477929	journal	February 1999
The radical photodissociation channel of acrylonitrile North, Simon W.; Hall, Gregory E. Chemical Physics Letters, Vol. 263, Issue 1-2 https://doi.org/10.1016/S0009-2614(96)01191-8	journal	December 1996
Ab Initio and RRKM Study of the HCN/HNC Elimination Channels from Vinyl Cyanide Homayoon, Zahra; Vázquez, Saulo A.; Rodríguez-Fernández, Roberto The Journal of Physical Chemistry A, Vol. 115, Issue 6 https://doi.org/10.1021/jp109843a	journal	February 2011
The photodissociation mechanisms of acrylonitrile: Ab initio calculations on reaction channels and surface intersections Du, Wei-Na; Luo, Cheng; Li, Ze-Sheng The Journal of Chemical Physics, Vol. 129, Issue 17 https://doi.org/10.1063/1.2994733	journal	November 2008
Pseudo-equilibrium geometry of HNO determined by an E-Band CP-FTmmW spectrometer Zaleski, Daniel P.; Prozument, Kirill Chemical Physics Letters, Vol. 680 https://doi.org/10.1016/j.cplett.2017.05.040	journal	July 2017
Broadband Fourier transform rotational spectroscopy for structure determination: The water heptamer Pérez, Cristóbal; Lobsiger, Simon; Seifert, Nathan A. Chemical Physics Letters, Vol. 571 https://doi.org/10.1016/j.cplett.2013.04.014	journal	May 2013
Pure Rotational Spectrum of HCN in the Terahertz Region: Use of a New Planar Schottky Diode Multiplier Maiwald, F.; Lewen, F.; Ahrens, V. Journal of Molecular Spectroscopy, Vol. 202, Issue 1 https://doi.org/10.1006/jmsp.2000.8118	journal	July 2000
The Millimeter- and Submillimeter-Wave Spectrum of HC3N in the Ground and Vibrationally Excited States Thorwirth, S.; Müller, H. S. P.; Winnewisser, G. Journal of Molecular Spectroscopy, Vol. 204, Issue 1 https://doi.org/10.1006/jmsp.2000.8209	journal	November 2000
Laboratory Measurements of the Hyperfine Structure of H ¹⁴ N ¹² C and D ¹⁴ N ¹² C Bechtel, Hans A.; Steeves, Adam H.; Field, Robert W. The Astrophysical Journal, Vol. 649, Issue 1 https://doi.org/10.1086/508272	journal	September 2006
Ro-vibrational relaxation of HCN in collisions with He: Rigid bender treatment of the bending-rotation interaction Stoecklin, Thierry; Denis-Alpizar, Otoniel; Halvick, Philippe The Journal of Chemical Physics, Vol. 139, Issue 12 https://doi.org/10.1063/1.4822296	journal	September 2013
The rotational excitation of HCN and HNC by He: temperature dependence of the collisional rate coefficients: Rotational excitation of HCN and HNC by He Dumouchel, F.; Faure, A.; Lique, F. Monthly Notices of the Royal Astronomical Society, Vol. 406, Issue 4 https://doi.org/10.1111/j.1365-2966.2010.16826.x	journal	May 2010
Collisional excitation of HC ₃ N by para- and ortho-H ₂ Faure, Alexandre; Lique, François; Wiesenfeld, Laurent Monthly Notices of the Royal Astronomical Society, Vol. 460, Issue 2 https://doi.org/10.1093/mnras/stw1156	journal	May 2016
Kinetics and thermochemistry of the acetyl radical: study of the acetyl + hydrogen bromide .fwdarw. acetaldehyde + bromine atom reaction Niiranen, Jukka T.; Gutman, David; Krasnoperov, L. N. The Journal of Physical Chemistry, Vol. 96, Issue 14 https://doi.org/10.1021/j100193a044	journal	July 1992
The broadband rotational spectrum of fully deuterated acetaldehyde (CD3CDO) in a CW supersonic expansion Zaleski, Daniel P.; Duan, Chuanxi; Carvajal, Miguel Journal of Molecular Spectroscopy, Vol. 342 https://doi.org/10.1016/j.jms.2017.01.010	journal	December 2017
Complete experimental rovibrational eigenenergies of HCN up to 6880 cm ⁻¹ above the ground state Mellau, Georg Ch. The Journal of Chemical Physics, Vol. 134, Issue 23 https://doi.org/10.1063/1.3598942	journal	June 2011
Chirped-pulse millimeter-wave spectroscopy: Spectrum, dynamics, and manipulation of Rydberg–Rydberg transitions Colombo, Anthony P.; Zhou, Yan; Prozument, Kirill The Journal of Chemical Physics, Vol. 138, Issue 1 https://doi.org/10.1063/1.4772762	journal	January 2013
Multi-resonance effects within a single chirp in broadband rotational spectroscopy: The rapid adiabatic passage regime for benzonitrile Schmitz, David; Alvin Shubert, V.; Betz, Thomas Journal of Molecular Spectroscopy, Vol. 280 https://doi.org/10.1016/j.jms.2012.08.001	journal	October 2012
Chirped-Pulse Millimeter-Wave Spectroscopy of Rydberg-Rydberg Transitions Prozument, Kirill; Colombo, Anthony P.; Zhou, Yan Physical Review Letters, Vol. 107, Issue 14 https://doi.org/10.1103/PhysRevLett.107.143001	journal	September 2011
Edge effects in chirped-pulse Fourier transform microwave spectra Park, G. Barratt; Field, Robert W. Journal of Molecular Spectroscopy, Vol. 312 https://doi.org/10.1016/j.jms.2015.03.010	journal	June 2015
Transient emission, off‐resonant transient absorption, and Fourier transform microwave spectroscopy McGurk, J. C.; Mäder, H.; Hofmann, R. T. The Journal of Chemical Physics, Vol. 61, Issue 9 https://doi.org/10.1063/1.1682562	journal	November 1974
Submillimeter, Millimeter, and Microwave Spectral line Catalog Pickett, H. M.; Poynter, R. L.; Cohen, E. A. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 60, Issue 5 https://doi.org/10.1016/S0022-4073(98)00091-0	journal	November 1998
PGOPHER: A program for simulating rotational, vibrational and electronic spectra Western, Colin M. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 186 https://doi.org/10.1016/j.jqsrt.2016.04.010	journal	January 2017
Systematic exploration of the mechanism of chemical reactions: the global reaction route mapping (GRRM) strategy using the ADDF and AFIR methods Maeda, Satoshi; Ohno, Koichi; Morokuma, Keiji Physical Chemistry Chemical Physics, Vol. 15, Issue 11 https://doi.org/10.1039/c3cp44063j	journal	January 2013
An automated method to find transition states using chemical dynamics simulations Martínez-Núñez, Emilio Journal of Computational Chemistry, Vol. 36, Issue 4 https://doi.org/10.1002/jcc.23790	journal	November 2014
An automated transition state search using classical trajectories initialized at multiple minima Martínez-Núñez, Emilio Physical Chemistry Chemical Physics, Vol. 17, Issue 22 https://doi.org/10.1039/C5CP02175H	journal	January 2015
Introduction to Active Thermochemical Tables: Several “Key” Enthalpies of Formation Revisited ^† Ruscic, Branko; Pinzon, Reinhardt E.; Morton, Melita L. The Journal of Physical Chemistry A, Vol. 108, Issue 45 https://doi.org/10.1021/jp047912y	journal	November 2004
Active Thermochemical Tables: thermochemistry for the 21st century Ruscic, Branko; Pinzon, Reinhardt E.; Laszewski, Gregor von Journal of Physics: Conference Series, Vol. 16 https://doi.org/10.1088/1742-6596/16/1/078	journal	January 2005
Active Thermochemical Tables: Sequential Bond Dissociation Enthalpies of Methane, Ethane, and Methanol and the Related Thermochemistry Ruscic, Branko The Journal of Physical Chemistry A, Vol. 119, Issue 28 https://doi.org/10.1021/acs.jpca.5b01346	journal	February 2015
High-Accuracy Estimates for the Vinylidene-Acetylene Isomerization Energy and the Ground State Rotational Constants of :C═CH ₂ Lee, Hyunwoo; Baraban, Joshua H.; Field, Robert W. The Journal of Physical Chemistry A, Vol. 117, Issue 46 https://doi.org/10.1021/jp400035a	journal	May 2013
Weakly Bound Free Radicals in Combustion: “Prompt” Dissociation of Formyl Radicals and Its Effect on Laminar Flame Speeds Labbe, Nicole J.; Sivaramakrishnan, Raghu; Goldsmith, C. Franklin The Journal of Physical Chemistry Letters, Vol. 7, Issue 1 https://doi.org/10.1021/acs.jpclett.5b02418	journal	December 2015
From theoretical reaction dynamics to chemical modeling of combustion Klippenstein, Stephen J. Proceedings of the Combustion Institute, Vol. 36, Issue 1 https://doi.org/10.1016/j.proci.2016.07.100	journal	January 2017
Catalysis by clusters with precise numbers of atoms Tyo, Eric C.; Vajda, Stefan Nature Nanotechnology, Vol. 10, Issue 7 https://doi.org/10.1038/nnano.2015.140	journal	July 2015
Copper Cluster Size Effect in Methanol Synthesis from CO ₂ Yang, Bing; Liu, Cong; Halder, Avik The Journal of Physical Chemistry C, Vol. 121, Issue 19 https://doi.org/10.1021/acs.jpcc.7b01835	journal	May 2017

Cited By (7)

Photodissociation transition states characterized by chirped pulse millimeter wave spectroscopy Prozument, Kirill; Baraban, Joshua H.; Changala, P. Bryan Proceedings of the National Academy of Sciences, Vol. 117, Issue 1 https://doi.org/10.1073/pnas.1911326116	journal	December 2019
Quantitative analysis of gas phase molecular constituents using frequency-modulated rotational spectroscopy Lou, Minghe; Swearer, Dayne F.; Gottheim, Samuel Review of Scientific Instruments, Vol. 90, Issue 5 https://doi.org/10.1063/1.5093912	journal	May 2019
Photochemical isomerization reactions of acrylonitrile. A mechanistic study Su, Ming-Der RSC Advances, Vol. 8, Issue 11 https://doi.org/10.1039/c7ra12614j	journal	January 2018
The Hunt for Elusive Molecules: Insights from Joint Theoretical and Experimental Investigations Martin‐Drumel, Marie‐Aline; Baraban, Joshua H.; Changala, P. Bryan Chemistry – A European Journal, Vol. 25, Issue 30 https://doi.org/10.1002/chem.201805986	journal	March 2019
Automated assignment of rotational spectra using artificial neural networks Zaleski, Daniel P.; Prozument, Kirill The Journal of Chemical Physics, Vol. 149, Issue 10 https://doi.org/10.1063/1.5037715	journal	September 2018
Direct Measurements of Small Polar Impurities in Gasoline Mixtures Using Molecular Rotational Resonance Spectroscopy Christophe, Artressa L.; Barnes, Jalon T.; Twagirayezu, Sylvestre Applied Spectroscopy https://doi.org/10.1177/0003702819859012	journal	September 2019
Automated Assignment of Rotational Spectra Using Artificial Neural Networks Zaleski, Daniel; Prozument, Kirill Proceedings of the 73rd International Symposium on Molecular Spectroscopy https://doi.org/10.15278/isms.2018.th01	conference	June 2018

Similar Records

Photodissociation of vinyl cyanide at 193 nm: Nascent product distributions of the molecular elimination channels

Journal Article · Wed Jan 28 00:00:00 EST 2009 · Journal of Chemical Physics · OSTI ID:1426235

Wilhelm, Michael J; Nikow, Matthew; Letendre, Laura; +1 more

Photodissociation transition states characterized by chirped pulse millimeter wave spectroscopy

Journal Article · Wed Dec 18 00:00:00 EST 2019 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1426235

Prozument, Kirill; Baraban, Joshua H.; Changala, P. Bryan; +6 more

Product Branching in the Low Temperature Reaction of CN with Propyne by Chirped-Pulse Microwave Spectroscopy in a Uniform Supersonic Flow

Journal Article · Wed Apr 15 00:00:00 EDT 2015 · Journal of Physical Chemistry Letters · OSTI ID:1426235

Abeysekera, Chamara; Joalland, Baptiste; Ariyasingha, Nuwandi; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Branching ratio
Chemical reaction dynamics and kinetics
Gas phase
HC3N
Rotational relaxation and equilibration
Vibrational level population distribution

Title: Time-Resolved Kinetic Chirped-Pulse Rotational Spectroscopy in a Room-Temperature Flow Reactor

Citation Formats

References (75)

Cited By (7)

Similar Records

Related Subjects