Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry

Palomino, Robert M.; Hamlyn, Rebecca; Liu, Zongyuan; Grinter, David C.; Waluyo, Iradwikanari; Rodriguez, Jose A.; Senanayake, Sanjaya D.

doi:10.1016/j.elspec.2017.04.006

Title: Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry

Journal Article · Thu Apr 27 00:00:00 EDT 2017 · Journal of Electron Spectroscopy and Related Phenomena

DOI:https://doi.org/10.1016/j.elspec.2017.04.006· OSTI ID:1425096

Palomino, Robert M. ^[1]; Hamlyn, Rebecca ^[2]; Liu, Zongyuan ^[1]; Grinter, David C. ^[1]; Waluyo, Iradwikanari ^[3]; Rodriguez, Jose A. ^[4]; Senanayake, Sanjaya D. ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
Stony Brook Univ., NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Stony Brook Univ., NY (United States). Dept. of Chemistry

In this paper we provide a summary of the recent development of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) and its application to catalytic surface chemistry. The methodology as well as significant advantages and challenges associated with this novel technique are described. Details about specific examples of using AP-XPS to probe surface chemistry under working reaction conditions for a number of reactions are explained: CO oxidation, water-gas shift (WGS), CO₂ hydrogenation, dry reforming of methane (DRM) and ethanol steam reforming (ESR). In conclusion, we discuss insights into the future development of the AP-XPS technique and its applications.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1425096

Alternate ID(s):: OSTI ID: 1495732

Report Number(s):: BNL-203312-2018-JAAM

Journal Information:: Journal of Electron Spectroscopy and Related Phenomena, Vol. 221; ISSN 0368-2048

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 33 works

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