Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries

Jiang, Yi; Deng, Ya-Ping; Fu, Jing; Lee, Dong Un; Liang, Ruilin; Cano, Zachary Paul; Liu, Yangshuai; Bai, Zhengyu; Hwang, Sooyeon; Yang, Lin; Su, Dong; Chu, Weiguo; Chen, Zhongwei

doi:10.1002/aenm.201702900

Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries

Journal Article · Wed Jan 31 00:00:00 EST 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201702900· OSTI ID:1425093

Jiang, Yi ^[1]; Deng, Ya-Ping ^[2]; Fu, Jing ^[2]; Lee, Dong Un ^[2]; Liang, Ruilin ^[2]; Cano, Zachary Paul ^[2]; Liu, Yangshuai ^[2]; Bai, Zhengyu ^[3]; Hwang, Sooyeon ^[4]; Yang, Lin ^[3]; Su, Dong ^[4]; Chu, Weiguo ^[5]; ^[2]

National Center for Nanoscience and Technology, Beijing (China). CAS Key Lab. for Nanosystem and Hierarchical Fabrication. CAS Center for Excellence in Nanoscience; Univ. of Chinese Academy of Sciences, Beijing (China); Univ. of Waterloo, ON (Canada). Dept. of Chemical Engineering. Waterloo Inst. for Nanotechnology. Waterloo Inst. for Sustainable Energy
Univ. of Waterloo, ON (Canada). Dept. of Chemical Engineering. Waterloo Inst. for Nanotechnology. Waterloo Inst. for Sustainable Energy
Henan Normal Univ., Xinxiang (China). School of Chemistry and Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
National Center for Nanoscience and Technology, Beijing (China). CAS Key Lab. for Nanosystem and Hierarchical Fabrication. CAS Center for Excellence in Nanoscience; Univ. of Chinese Academy of Sciences, Beijing (China)

Rational construction of atomic-scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). In this paper, a hybrid of interpenetrating metallic Co and spinel Co₃O₄ “Janus” nanoparticles stitched in porous graphitized shells (Co/Co₃O₄@PGS) is synthesized via ionic exchange and redox between Co²⁺ and 2D metal–organic-framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells provides an optimal charge/mass transport environment. Furthermore, the defect-rich interfaces act as atomic-traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co₃O₄@PGS outperforms state-of-the-art noble-metal catalysts with a positive half-wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm^-2 for OER. Finally, in a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm^-2 is achieved by Zn–air batteries with Co/Co₃O₄@PGS within the rechargeable air electrode.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States); Henan Normal Univ., Xinxiang (China); National Center for Nanoscience and Technology, Beijing (China); Univ. of Waterloo, ON (Canada)

Sponsoring Organization:: 111 Project (China); Chinese Academy of Sciences (CAS); National Natural Science Foundation of China (NSFC); Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE

Grant/Contract Number:: SC0012704

OSTI ID:: 1425093

Report Number(s):: BNL--203305-2018-JAAM

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 15 Vol. 8; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

Encapsulation and Ostwald Ripening of Au and Au–Cl Complex Nanostructures in Silica Shells Lou, X. W.; Yuan, C.; Rhoades, E. Advanced Functional Materials, Vol. 16, Issue 13 https://doi.org/10.1002/adfm.200500909	journal	September 2006
Interface Engineered W _x C@WS ₂ Nanostructure for Enhanced Hydrogen Evolution Catalysis Wang, Fengmei; He, Peng; Li, Yuanchang Advanced Functional Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adfm.201605802	journal	January 2017
Recent Advances in Metal Oxide-based Electrode Architecture Design for Electrochemical Energy Storage Jiang, Jian; Li, Yuanyuan; Liu, Jinping Advanced Materials, Vol. 24, Issue 38 https://doi.org/10.1002/adma.201202146	journal	August 2012
Strongly Coupled NiCo ₂ O ₄ -rGO Hybrid Nanosheets as a Methanol-Tolerant Electrocatalyst for the Oxygen Reduction Reaction Zhang, Genqiang; Xia, Bao Yu; Wang, Xin Advanced Materials, Vol. 26, Issue 15 https://doi.org/10.1002/adma.201304683	journal	December 2013
Flexible Rechargeable Zinc-Air Batteries through Morphological Emulation of Human Hair Array Fu, Jing; Hassan, Fathy Mohamed; Li, Jingde Advanced Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adma.201600762	journal	May 2016
Nitrogen-Doped Co ₃ O ₄ Mesoporous Nanowire Arrays as an Additive-Free Air-Cathode for Flexible Solid-State Zinc-Air Batteries Yu, Minghao; Wang, Zhengke; Hou, Cheng Advanced Materials, Vol. 29, Issue 15 https://doi.org/10.1002/adma.201602868	journal	February 2017
Electrically Rechargeable Zinc-Air Batteries: Progress, Challenges, and Perspectives Fu, Jing; Cano, Zachary Paul; Park, Moon Gyu Advanced Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adma.201604685	journal	November 2016
Defect Engineering of Chalcogen-Tailored Oxygen Electrocatalysts for Rechargeable Quasi-Solid-State Zinc-Air Batteries Fu, Jing; Hassan, Fathy M.; Zhong, Cheng Advanced Materials, Vol. 29, Issue 35 https://doi.org/10.1002/adma.201702526	journal	July 2017
Cobalt Oxide and Cobalt-Graphitic Carbon Core-Shell Based Catalysts with Remarkably High Oxygen Reduction Reaction Activity Yu, Jie; Chen, Gao; Sunarso, Jaka Advanced Science, Vol. 3, Issue 9 https://doi.org/10.1002/advs.201600060	journal	April 2016
Formation of Single-Holed Cobalt/N-Doped Carbon Hollow Particles with Enhanced Electrocatalytic Activity toward Oxygen Reduction Reaction in Alkaline Media Guan, Bu Yuan; Yu, Le; Lou, Xiong Wen David Advanced Science, Vol. 4, Issue 10 https://doi.org/10.1002/advs.201700247	journal	July 2017
Metal-Air Batteries with High Energy Density: Li-Air versus Zn-Air Lee, Jang-Soo; Tai Kim, Sun; Cao, Ruiguo Advanced Energy Materials, Vol. 1, Issue 1, p. 34-50 https://doi.org/10.1002/aenm.201000010	journal	December 2010
Recent Progress in Non-Precious Catalysts for Metal-Air Batteries Cao, Ruiguo; Lee, Jang-Soo; Liu, Meilin Advanced Energy Materials, Vol. 2, Issue 7 https://doi.org/10.1002/aenm.201200013	journal	June 2012
Ultrathin Co ₃ O ₄ Layers with Large Contact Area on Carbon Fibers as High-Performance Electrode for Flexible Zinc-Air Battery Integrated with Flexible Display Chen, Xu; Liu, Bin; Zhong, Cheng Advanced Energy Materials, Vol. 7, Issue 18 https://doi.org/10.1002/aenm.201700779	journal	May 2017
Hierarchical Zn/Ni-MOF-2 Nanosheet-Assembled Hollow Nanocubes for Multicomponent Catalytic Reactions Zhang, Zhicheng; Chen, Yifeng; He, Su Angewandte Chemie, Vol. 126, Issue 46 https://doi.org/10.1002/ange.201406484	journal	July 2014
Hierarchical Tubular Structures Composed of Co ₃ O ₄ Hollow Nanoparticles and Carbon Nanotubes for Lithium Storage Chen, Yu Ming; Yu, Le; Lou, Xiong Wen David Angewandte Chemie, Vol. 128, Issue 20 https://doi.org/10.1002/ange.201600133	journal	April 2016
Pomegranate-Inspired Design of Highly Active and Durable Bifunctional Electrocatalysts for Rechargeable Metal-Air Batteries Li, Ge; Wang, Xiaolei; Fu, Jing Angewandte Chemie, Vol. 128, Issue 16 https://doi.org/10.1002/ange.201600750	journal	March 2016
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie, Vol. 128, Issue 36 https://doi.org/10.1002/ange.201604802	journal	August 2016
Mn _x O _y /NC and Co _x O _y /NC Nanoparticles Embedded in a Nitrogen-Doped Carbon Matrix for High-Performance Bifunctional Oxygen Electrodes Masa, Justus; Xia, Wei; Sinev, Ilya Angewandte Chemie International Edition, Vol. 53, Issue 32 https://doi.org/10.1002/anie.201402710	journal	June 2014
Hierarchical Zn/Ni-MOF-2 Nanosheet-Assembled Hollow Nanocubes for Multicomponent Catalytic Reactions Zhang, Zhicheng; Chen, Yifeng; He, Su Angewandte Chemie International Edition https://doi.org/10.1002/anie.201406484	journal	July 2014
Co@Co ₃ O ₄ Encapsulated in Carbon Nanotube-Grafted Nitrogen-Doped Carbon Polyhedra as an Advanced Bifunctional Oxygen Electrode Aijaz, Arshad; Masa, Justus; Rösler, Christoph Angewandte Chemie International Edition, Vol. 55, Issue 12 https://doi.org/10.1002/anie.201509382	journal	February 2016
Hierarchical Tubular Structures Composed of Co ₃ O ₄ Hollow Nanoparticles and Carbon Nanotubes for Lithium Storage Chen, Yu Ming; Yu, Le; Lou, Xiong Wen David Angewandte Chemie International Edition, Vol. 55, Issue 20 https://doi.org/10.1002/anie.201600133	journal	April 2016
Pomegranate-Inspired Design of Highly Active and Durable Bifunctional Electrocatalysts for Rechargeable Metal-Air Batteries Li, Ge; Wang, Xiaolei; Fu, Jing Angewandte Chemie International Edition, Vol. 55, Issue 16 https://doi.org/10.1002/anie.201600750	journal	March 2016
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604802	journal	August 2016
Highly Active and Durable Nanocrystal-Decorated Bifunctional Electrocatalyst for Rechargeable Zinc-Air Batteries Lee, Dong Un; Park, Moon Gyu; Park, Hey Woong ChemSusChem, Vol. 8, Issue 18 https://doi.org/10.1002/cssc.201500609	journal	August 2015
Self-Assembly of Spinel Nanocrystals into Mesoporous Spheres as Bifunctionally Active Oxygen Reduction and Evolution Electrocatalysts Lee, Dong Un; Li, Jingde; Park, Moon Gyu ChemSusChem, Vol. 10, Issue 10 https://doi.org/10.1002/cssc.201700369	journal	April 2017
Metal-Organic Framework-Derived Bamboo-like Nitrogen-Doped Graphene Tubes as an Active Matrix for Hybrid Oxygen-Reduction Electrocatalysts Li, Qing; Pan, Hengyu; Higgins, Drew Small, Vol. 11, Issue 12 https://doi.org/10.1002/smll.201402069	journal	November 2014
3D Ordered Mesoporous Bifunctional Oxygen Catalyst for Electrically Rechargeable Zinc-Air Batteries Park, Moon Gyu; Lee, Dong Un; Seo, Min Ho Small, Vol. 12, Issue 20 https://doi.org/10.1002/smll.201600051	journal	April 2016
Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications Zhang, Huabin; Nai, Jianwei; Yu, Le Joule, Vol. 1, Issue 1 https://doi.org/10.1016/j.joule.2017.08.008	journal	September 2017
High-performance non-spinel cobalt–manganese mixed oxide-based bifunctional electrocatalysts for rechargeable zinc–air batteries Liu, Xien; Park, Minjoon; Kim, Min Gyu Nano Energy, Vol. 20 https://doi.org/10.1016/j.nanoen.2015.11.030	journal	February 2016
Thermal decomposition of cobalt nitrato compounds: Preparation of anhydrous cobalt(II)nitrate and its characterisation by Infrared and Raman spectra Ehrhardt, Claus; Gjikaj, Mimoza; Brockner, Wolfgang Thermochimica Acta, Vol. 432, Issue 1 https://doi.org/10.1016/j.tca.2005.04.010	journal	July 2005
Environmentally-friendly and ultrasonic-assisted preparation of two-dimensional ultrathin Ni/Co-NO3 layered double hydroxide nanosheet for micro solid-phase extraction of phenolic acids from fruit juices Soltani, Roozbeh; Shahvar, Ali; Dinari, Mohammad Ultrasonics Sonochemistry, Vol. 40 https://doi.org/10.1016/j.ultsonch.2017.07.031	journal	January 2018
Chemistry of Multitudinous Active Sites for Oxygen Reduction Reaction in Transition Metal–Nitrogen–Carbon Electrocatalysts Artyushkova, Kateryna; Serov, Alexey; Rojas-Carbonell, Santiago The Journal of Physical Chemistry C, Vol. 119, Issue 46 https://doi.org/10.1021/acs.jpcc.5b07653	journal	November 2015
Integrated Hierarchical Cobalt Sulfide/Nickel Selenide Hybrid Nanosheets as an Efficient Three-dimensional Electrode for Electrochemical and Photoelectrochemical Water Splitting Hou, Yang; Qiu, Ming; Nam, Gyutae Nano Letters, Vol. 17, Issue 7 https://doi.org/10.1021/acs.nanolett.7b01030	journal	June 2017
Active Site Structures in Nitrogen-Doped Carbon-Supported Cobalt Catalysts for the Oxygen Reduction Reaction Qian, Yingdan; Liu, Zheng; Zhang, Hui ACS Applied Materials & Interfaces, Vol. 8, Issue 48 https://doi.org/10.1021/acsami.6b11927	journal	November 2016
Monoclinic ZIF-8 Nanosheet-Derived 2D Carbon Nanosheets as Sulfur Immobilizer for High-Performance Lithium Sulfur Batteries Jiang, Yi; Liu, Haiqiang; Tan, Xinghua ACS Applied Materials & Interfaces, Vol. 9, Issue 30 https://doi.org/10.1021/acsami.7b04432	journal	July 2017
Metal–Air Batteries: Will They Be the Future Electrochemical Energy Storage Device of Choice? Li, Yanguang; Lu, Jun ACS Energy Letters, Vol. 2, Issue 6, p. 1370-1377 https://doi.org/10.1021/acsenergylett.7b00119	journal	May 2017
Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening? Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R. Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar3002427	journal	April 2013
Metal-Free Catalysts for Oxygen Reduction Reaction Dai, Liming; Xue, Yuhua; Qu, Liangti Chemical Reviews, Vol. 115, Issue 11 https://doi.org/10.1021/cr5003563	journal	May 2015
Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications Wang, Haibo; Maiyalagan, Thandavarayan; Wang, Xin ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs200652y	journal	April 2012
Covalent Hybrid of Spinel Manganese–Cobalt Oxide and Graphene as Advanced Oxygen Reduction Electrocatalysts Liang, Yongye; Wang, Hailiang; Zhou, Jigang Journal of the American Chemical Society, Vol. 134, Issue 7 https://doi.org/10.1021/ja210924t	journal	February 2012
Strongly Coupled Inorganic/Nanocarbon Hybrid Materials for Advanced Electrocatalysis Liang, Yongye; Li, Yanguang; Wang, Hailiang Journal of the American Chemical Society, Vol. 135, Issue 6 https://doi.org/10.1021/ja3089923	journal	January 2013
Thermal Conversion of Core–Shell Metal–Organic Frameworks: A New Method for Selectively Functionalized Nanoporous Hybrid Carbon Tang, Jing; Salunkhe, Rahul R.; Liu, Jian Journal of the American Chemical Society, Vol. 137, Issue 4 https://doi.org/10.1021/ja511539a	journal	January 2015
In Situ Coupling of Strung Co ₄ N and Intertwined N–C Fibers toward Free-Standing Bifunctional Cathode for Robust, Efficient, and Flexible Zn–Air Batteries Meng, Fanlu; Zhong, Haixia; Bao, Di Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05046	journal	August 2016
General Oriented Formation of Carbon Nanotubes from Metal–Organic Frameworks Meng, Jiashen; Niu, Chaojiang; Xu, Linhan Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b01942	journal	June 2017
Highly Active and Durable Core–Corona Structured Bifunctional Catalyst for Rechargeable Metal–Air Battery Application Chen, Zhu; Yu, Aiping; Higgins, Drew Nano Letters, Vol. 12, Issue 4 https://doi.org/10.1021/nl2044327	journal	January 2012
Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts Cheng, Fangyi; Shen, Jian; Peng, Bo Nature Chemistry, Vol. 3, Issue 1 https://doi.org/10.1038/nchem.931	journal	December 2010
Advanced zinc-air batteries based on high-performance hybrid electrocatalysts Li, Yanguang; Gong, Ming; Liang, Yongye Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2812	journal	May 2013
Holey graphene frameworks for highly efficient capacitive energy storage Xu, Yuxi; Lin, Zhaoyang; Zhong, Xing Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5554	journal	August 2014
A general and scalable synthesis approach to porous graphene Zhou, Ding; Cui, Yi; Xiao, Pei-Wen Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5716	journal	September 2014
Phase and composition controllable synthesis of cobalt manganese spinel nanoparticles towards efficient oxygen electrocatalysis Li, Chun; Han, Xiaopeng; Cheng, Fangyi Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8345	journal	June 2015
A metal–organic framework-derived bifunctional oxygen electrocatalyst Xia, Bao Yu; Yan, Ya; Li, Nan Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.6	journal	January 2016
Co₃O₄ nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction Liang, Yongye; Li, Yanguang; Wang, Hailiang Nature Materials, Vol. 10, Issue 10, p. 780-786 https://doi.org/10.1038/nmat3087	journal	August 2011
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes Wang, Zhong-Li; Xu, Dan; Xu, Ji-Jing Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60248F	journal	January 2014
Recent advances in zinc–air batteries Li, Yanguang; Dai, Hongjie Chem. Soc. Rev., Vol. 43, Issue 15 https://doi.org/10.1039/C4CS00015C	journal	January 2014
Rapid synthesis of ultrathin, defect-free ZIF-8 membranes via chemical vapour modification of a polymeric support Shamsaei, Ezzatollah; Low, Ze-Xian; Lin, Xiaocheng Chemical Communications, Vol. 51, Issue 57 https://doi.org/10.1039/C5CC03537F	journal	January 2015
Metal–organic-framework-engaged formation of Co nanoparticle-embedded carbon@Co ₉ S ₈ double-shelled nanocages for efficient oxygen reduction Hu, Han; Han, Lei; Yu, Mengzhou Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02903A	journal	January 2016
Optimizing nanoparticle perovskite for bifunctional oxygen electrocatalysis Jung, Jae-Il; Risch, Marcel; Park, Seungkyu Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE03124A	journal	January 2016
Supramolecular gel-assisted synthesis of double shelled Co@CoO@N–C/C nanoparticles with synergistic electrocatalytic activity for the oxygen reduction reaction Wu, Zexing; Wang, Jie; Han, Lili Nanoscale, Vol. 8, Issue 8 https://doi.org/10.1039/C5NR07929B	journal	January 2016
A dual-metal–organic-framework derived electrocatalyst for oxygen reduction Guan, Bu Yuan; Yu, Le; (David) Lou, Xiong Wen Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02171A	journal	January 2016
Single crystalline pyrochlore nanoparticles with metallic conduction as efficient bi-functional oxygen electrocatalysts for Zn–air batteries Park, Joohyuk; Risch, Marcel; Nam, Gyutae Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE03046G	journal	January 2017
Recent progress and perspectives on bi-functional oxygen electrocatalysts for advanced rechargeable metal–air batteries Lee, Dong Un; Xu, Pan; Cano, Zachary P. Journal of Materials Chemistry A, Vol. 4, Issue 19 https://doi.org/10.1039/C6TA00173D	journal	January 2016
Metal–organic framework derived carbon-confined Ni ₂ P nanocrystals supported on graphene for an efficient oxygen evolution reaction Wang, Manman; Lin, Mengting; Li, Jiantao Chemical Communications, Vol. 53, Issue 59 https://doi.org/10.1039/C7CC03558F	journal	January 2017
Nickel–cobalt oxides supported on Co/N decorated graphene as an excellent bifunctional oxygen catalyst Hao, Yongchao; Xu, Yuqi; Liu, Junfeng Journal of Materials Chemistry A, Vol. 5, Issue 11 https://doi.org/10.1039/C7TA00299H	journal	January 2017
Electrochemical performance of annealed cobalt–benzotriazole/CNTs catalysts towards the oxygen reduction reaction Morozan, Adina; Jégou, Pascale; Jousselme, Bruno Physical Chemistry Chemical Physics, Vol. 13, Issue 48 https://doi.org/10.1039/c1cp23199e	journal	January 2011
Ionic liquid modified graphene nanosheets anchoring manganese oxide nanoparticles as efficient electrocatalysts for Zn–air batteries Lee, Jang-Soo; Lee, Taemin; Song, Hyun-Kon Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01942b	journal	January 2011
Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst Yang, Hong Bin; Miao, Jianwei; Hung, Sung-Fu Science Advances, Vol. 2, Issue 4 https://doi.org/10.1126/sciadv.1501122	journal	April 2016
Oxygen Reduction Characteristics of Heat-Treated Catalysts Based on Cobalt-Porphyrin Ion Complexes Okada, Tatsuhiro Journal of The Electrochemical Society, Vol. 145, Issue 3 https://doi.org/10.1149/1.1838350	journal	January 1998

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Unveiling dual-linkage 3D hexaiminobenzene metal–organic frameworks towards long-lasting advanced reversible Zn–air batteries Shinde, Sambhaji S.; Lee, Chi Ho; Jung, Jin-Young Energy & Environmental Science, Vol. 12, Issue 2 https://doi.org/10.1039/c8ee02679c	journal	January 2019
Metal–organic frameworks-based catalysts for electrochemical oxygen evolution Shi, Qiurong; Fu, Shaofang; Zhu, Chengzhou Materials Horizons, Vol. 6, Issue 4 https://doi.org/10.1039/c8mh01397g	journal	January 2019
An efficient carbon-based ORR catalyst from low-temperature etching of ZIF-67 with ultra-small cobalt nanoparticles and high yield Guo, Jian; Gadipelli, Srinivas; Yang, Yuchen Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta10925g	journal	January 2019
Plasma-modified C-doped Co ₃ O ₄ nanosheets for the oxygen evolution reaction designed by Butler–Volmer and first-principle calculations Xu, Aoni; Dong, Chaofang; Wu, Angjian Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta11424b	journal	January 2019
Bimetallic NiCo/CNF encapsulated in a N-doped carbon shell as an electrocatalyst for Zn–air batteries and water splitting Gebremariam, Tesfaye Tadesse; Chen, Fuyi; Jin, Yachao Catalysis Science & Technology, Vol. 9, Issue 10 https://doi.org/10.1039/c9cy00266a	journal	January 2019
Confined Co ₉ S ₈ into a defective carbon matrix as a bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries Meng, Lu; Zhan, Ling; Jiang, Hongliang Catalysis Science & Technology, Vol. 9, Issue 20 https://doi.org/10.1039/c9cy01717h	journal	January 2019
Hierarchical Co ₃ O ₄ nanorods anchored on nitrogen doped reduced graphene oxide: a highly efficient bifunctional electrocatalyst for rechargeable Zn–air batteries Sanchez, Jaime S.; Maça, Rudi Ruben; Pendashteh, Afshin Catalysis Science & Technology, Vol. 10, Issue 5 https://doi.org/10.1039/c9cy02183c	journal	January 2020
N-Doped porous tremella-like Fe ₃ C/C electrocatalysts derived from metal–organic frameworks for oxygen reduction reaction Yang, Xinxin; Sun, Xiang; Rauf, Muhammad Dalton Transactions, Vol. 49, Issue 3 https://doi.org/10.1039/c9dt03923f	journal	January 2020
Heteroatom-doped nanoporous carbon initiated from bimetallic molecular framework micro-rods for supercapacitor electrodes Wang, Qiang; Liang, Hongwei; Wu, Dun RSC Advances, Vol. 9, Issue 31 https://doi.org/10.1039/c9ra02533b	journal	January 2019
Hierarchical tri-functional electrocatalysts derived from bimetallic–imidazolate framework for overall water splitting and rechargeable zinc–air batteries Ahn, Sung Hoon; Manthiram, Arumugam Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/c9ta01340g	journal	January 2019
Cu and Co nanoparticle-Co-decorated N-doped graphene nanosheets: a high efficiency bifunctional electrocatalyst for rechargeable Zn–air batteries Liu, Peitao; Hu, Yating; Liu, Xiaokai Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/c9ta02894c	journal	January 2019
Toward a new generation of low cost, efficient, and durable metal–air flow batteries Yu, Wentao; Shang, Wenxu; Tan, Peng Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta10658h	journal	January 2019
Metal-organic framework-derived structures for next-generation rechargeable batteries Shi, Wenhui; Xu, Xilian; Zhang, Lin Functional Materials Letters, Vol. 11, Issue 06 https://doi.org/10.1142/s1793604718300062	journal	December 2018

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