Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries

Jiang, Yi; Deng, Ya-Ping; Fu, Jing; Lee, Dong Un; Liang, Ruilin; Cano, Zachary Paul; Liu, Yangshuai; Bai, Zhengyu; Hwang, Sooyeon; Yang, Lin; Su, Dong; Chu, Weiguo; Chen, Zhongwei

doi:10.1002/aenm.201702900

Title: Interpenetrating Triphase Cobalt-Based Nanocomposites as Efficient Bifunctional Oxygen Electrocatalysts for Long-Lasting Rechargeable Zn–Air Batteries

Journal Article · Wed Jan 31 00:00:00 EST 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201702900· OSTI ID:1425093

Jiang, Yi ^[1]; Deng, Ya-Ping ^[2]; Fu, Jing ^[2]; Lee, Dong Un ^[2]; Liang, Ruilin ^[2]; Cano, Zachary Paul ^[2]; Liu, Yangshuai ^[2]; Bai, Zhengyu ^[3]; Hwang, Sooyeon ^[4]; Yang, Lin ^[3]; Su, Dong ^[4]; Chu, Weiguo ^[5];

^[2]

National Center for Nanoscience and Technology, Beijing (China). CAS Key Lab. for Nanosystem and Hierarchical Fabrication. CAS Center for Excellence in Nanoscience; Univ. of Chinese Academy of Sciences, Beijing (China); Univ. of Waterloo, ON (Canada). Dept. of Chemical Engineering. Waterloo Inst. for Nanotechnology. Waterloo Inst. for Sustainable Energy
Univ. of Waterloo, ON (Canada). Dept. of Chemical Engineering. Waterloo Inst. for Nanotechnology. Waterloo Inst. for Sustainable Energy
Henan Normal Univ., Xinxiang (China). School of Chemistry and Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
National Center for Nanoscience and Technology, Beijing (China). CAS Key Lab. for Nanosystem and Hierarchical Fabrication. CAS Center for Excellence in Nanoscience; Univ. of Chinese Academy of Sciences, Beijing (China)

Rational construction of atomic-scale interfaces in multiphase nanocomposites is an intriguing and challenging approach to developing advanced catalysts for both oxygen reduction (ORR) and evolution reactions (OER). In this paper, a hybrid of interpenetrating metallic Co and spinel Co₃O₄ “Janus” nanoparticles stitched in porous graphitized shells (Co/Co₃O₄@PGS) is synthesized via ionic exchange and redox between Co²⁺ and 2D metal–organic-framework nanosheets. This strategy is proven to effectively establish highways for the transfer of electrons and reactants within the hybrid through interfacial engineering. Specifically, the phase interpenetration of mixed Co species and encapsulating porous graphitized shells provides an optimal charge/mass transport environment. Furthermore, the defect-rich interfaces act as atomic-traps to achieve exceptional adsorption capability for oxygen reactants. Finally, robust coupling between Co and N through intimate covalent bonds prohibits the detachment of nanoparticles. As a result, Co/Co₃O₄@PGS outperforms state-of-the-art noble-metal catalysts with a positive half-wave potential of 0.89 V for ORR and a low potential of 1.58 V at 10 mA cm^-2 for OER. Finally, in a practical demonstration, ultrastable cyclability with a record lifetime of over 800 h at 10 mA cm^-2 is achieved by Zn–air batteries with Co/Co₃O₄@PGS within the rechargeable air electrode.

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Research Organization:: Univ. of Waterloo, ON (Canada); National Center for Nanoscience and Technology, Beijing (China); Henan Normal Univ., Xinxiang (China); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE; Natural Sciences and Engineering Research Council of Canada (NSERC); National Natural Science Foundation of China (NSFC); 111 Project (China); Chinese Academy of Sciences (CAS)

Grant/Contract Number:: SC0012704; 21573083; D17007; XDA09040101

OSTI ID:: 1425093

Report Number(s):: BNL-203305-2018-JAAM; TRN: US1802042

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 15; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 200 works

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Metal–organic frameworks-based catalysts for electrochemical oxygen evolution Shi, Qiurong; Fu, Shaofang; Zhu, Chengzhou Materials Horizons, Vol. 6, Issue 4 https://doi.org/10.1039/c8mh01397g	journal	January 2019
Plasma-modified C-doped Co ₃ O ₄ nanosheets for the oxygen evolution reaction designed by Butler–Volmer and first-principle calculations Xu, Aoni; Dong, Chaofang; Wu, Angjian Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta11424b	journal	January 2019
Bimetallic NiCo/CNF encapsulated in a N-doped carbon shell as an electrocatalyst for Zn–air batteries and water splitting Gebremariam, Tesfaye Tadesse; Chen, Fuyi; Jin, Yachao Catalysis Science & Technology, Vol. 9, Issue 10 https://doi.org/10.1039/c9cy00266a	journal	January 2019
Confined Co ₉ S ₈ into a defective carbon matrix as a bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries Meng, Lu; Zhan, Ling; Jiang, Hongliang Catalysis Science & Technology, Vol. 9, Issue 20 https://doi.org/10.1039/c9cy01717h	journal	January 2019
Hierarchical Co ₃ O ₄ nanorods anchored on nitrogen doped reduced graphene oxide: a highly efficient bifunctional electrocatalyst for rechargeable Zn–air batteries Sanchez, Jaime S.; Maça, Rudi Ruben; Pendashteh, Afshin Catalysis Science & Technology, Vol. 10, Issue 5 https://doi.org/10.1039/c9cy02183c	journal	January 2020
N-Doped porous tremella-like Fe ₃ C/C electrocatalysts derived from metal–organic frameworks for oxygen reduction reaction Yang, Xinxin; Sun, Xiang; Rauf, Muhammad Dalton Transactions, Vol. 49, Issue 3 https://doi.org/10.1039/c9dt03923f	journal	January 2020
Heteroatom-doped nanoporous carbon initiated from bimetallic molecular framework micro-rods for supercapacitor electrodes Wang, Qiang; Liang, Hongwei; Wu, Dun RSC Advances, Vol. 9, Issue 31 https://doi.org/10.1039/c9ra02533b	journal	January 2019
Hierarchical tri-functional electrocatalysts derived from bimetallic–imidazolate framework for overall water splitting and rechargeable zinc–air batteries Ahn, Sung Hoon; Manthiram, Arumugam Journal of Materials Chemistry A, Vol. 7, Issue 14 https://doi.org/10.1039/c9ta01340g	journal	January 2019
Cu and Co nanoparticle-Co-decorated N-doped graphene nanosheets: a high efficiency bifunctional electrocatalyst for rechargeable Zn–air batteries Liu, Peitao; Hu, Yating; Liu, Xiaokai Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/c9ta02894c	journal	January 2019
Toward a new generation of low cost, efficient, and durable metal–air flow batteries Yu, Wentao; Shang, Wenxu; Tan, Peng Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta10658h	journal	January 2019
Metal-organic framework-derived structures for next-generation rechargeable batteries Shi, Wenhui; Xu, Xilian; Zhang, Lin Functional Materials Letters, Vol. 11, Issue 06 https://doi.org/10.1142/s1793604718300062	journal	December 2018
Tuning Interfacial Structures for Better Catalysis of Water Electrolysis Xiang, Rui; Peng, Lishan; Wei, Zidong Chemistry – A European Journal, Vol. 25, Issue 42 https://doi.org/10.1002/chem.201901168	journal	May 2019

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interpenetrating phases
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bifunctional electrocatalysts
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