High performance diesel oxidation catalysts using ultra-low Pt loading on titania nanowire array integrated cordierite honeycombs

Hoang, Son; Lu, Xingxu; Tang, Wenxiang; Wang, Sibo; Du, Shoucheng; Nam, Chang-Yong; Ding, Yong; Vinluan, Rodrigo D.; Zheng, Jie; Gao, Pu-Xian

doi:10.1016/j.cattod.2017.11.019

Title: High performance diesel oxidation catalysts using ultra-low Pt loading on titania nanowire array integrated cordierite honeycombs

Journal Article · Wed Nov 15 00:00:00 EST 2017 · Catalysis Today

DOI:https://doi.org/10.1016/j.cattod.2017.11.019· OSTI ID:1425004

Hoang, Son ^[1]; Lu, Xingxu ^[1]; Tang, Wenxiang ^[1]; Wang, Sibo ^[1]; Du, Shoucheng ^[1]; Nam, Chang-Yong ^[2]; Ding, Yong ^[3]; Vinluan, Rodrigo D. ^[4]; Zheng, Jie ^[4]; Gao, Pu-Xian ^[1]

Univ. of Connecticut, Storrs, CT (United States). Dept. of Materials Science and Engineering & Inst. of Materials Science
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Georgia Inst. of Technology, Atlanta, GA (United States). School of Materials Science and Engineering
Univ. of Texas-Dallas, Richardson, TX (United States). Dept. of Chemistry and Biochemistry

High performance of an ultra-low Pt loading diesel oxidation catalyst can be achieved by using a combination of novel nano-array structured support, precise control of ultrafine active Pt particles, and an addition of H₂ as a promoter into the exhausts. Highly stable mesoporous rutile TiO₂ nano-array was uniformly grown on three-dimensional (3-D) cordierite honeycomb monoliths using a solvothermal synthesis. Atomic layer deposition was employed for precise dispersion of ultrafine Pt particles (0.95 ± 0.24 nm) on TiO₂ nano-array with a Pt loading of 1.1 g/ft³. Despite low Pt loading, the Pt/TiO₂ nano-array catalyst shows impressive low-temperature oxidation reactivity, with the conversion of CO and total hydrocarbon (THC) reaching 50% at 224 and 285 °C, respectively, in the clean diesel combustion (CDC) simulated exhaust conditions. The excellent activity is attributed to the unique nano-array structure that promotes gas-solid interaction and ultra-small Pt particle dispersion that increase surface Pt atoms. We also demonstrate that addition of more H₂ into the exhaust can lower light-off temperature for CO and THC by up to ~60 °C and ~30 °C, respectively.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; EE0006854; CBET-1344792

OSTI ID:: 1425004

Report Number(s):: BNL-114850-2017-JAAM; TRN: US1801996

Journal Information:: Catalysis Today, Vol. 320; ISSN 0920-5861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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References (45)

Diesel Oxidation Catalysts Russell, April; Epling, William S. Catalysis Reviews, Vol. 53, Issue 4 https://doi.org/10.1080/01614940.2011.596429	journal	October 2011
Strontium-Doped Perovskites Rival Platinum Catalysts for Treating NO_x in Simulated Diesel Exhaust Kim, C. H.; Qi, G.; Dahlberg, K. Science, Vol. 327, Issue 5973, p. 1624-1627 https://doi.org/10.1126/science.1184087	journal	March 2010
Manganese Oxide Nanoarray-Based Monolithic Catalysts: Tunable Morphology and High Efficiency for CO Oxidation Chen, Sheng-Yu; Song, Wenqiao; Lin, Hui-Jan ACS Applied Materials & Interfaces, Vol. 8, Issue 12 https://doi.org/10.1021/acsami.6b00578	journal	March 2016
Low temperature propane oxidation over Co3O4 based nano-array catalysts: Ni dopant effect, reaction mechanism and structural stability Ren, Zheng; Wu, Zili; Song, Wenqiao Applied Catalysis B: Environmental, Vol. 180 https://doi.org/10.1016/j.apcatb.2015.04.021	journal	January 2016
Low-Temperature CO Oxidation over a Ternary Oxide Catalyst with High Resistance to Hydrocarbon Inhibition Binder, Andrew J.; Toops, Todd J.; Unocic, Raymond R. Angewandte Chemie International Edition, Vol. 54, Issue 45 https://doi.org/10.1002/anie.201506093	journal	September 2015
Development of Advanced Ultra-Low PGM DOC for BS VI DOC+CDPF+SCR System Nazarpoor, Zahra; Golden, Steve; Liu, Ru-Fen SAE International Journal of Materials and Manufacturing, Vol. 10, Issue 1 https://doi.org/10.4271/2017-26-0142	journal	January 2017
Low-Temperature ABC-Type Atomic Layer Deposition: Synthesis of Highly Uniform Ultrafine Supported Metal Nanoparticles Lu, Junling; Stair, Peter C. Angewandte Chemie International Edition, Vol. 49, Issue 14, p. 2547-2551 https://doi.org/10.1002/anie.200907168	journal	March 2010
Subnanometre platinum clusters as highly active and selective catalysts for the oxidative dehydrogenation of propane Vajda, Stefan; Pellin, Michael J.; Greeley, Jeffrey P. Nature Materials, Vol. 8, Issue 3 https://doi.org/10.1038/nmat2384	journal	February 2009
Size-dependent CO and propylene oxidation activities of platinum nanoparticles on the monolithic Pt/TiO ₂ –YO _x diesel oxidation catalyst under simulative diesel exhaust conditions Yang, Zhengzheng; Li, Jun; Zhang, Hailong Catalysis Science & Technology, Vol. 5, Issue 4 https://doi.org/10.1039/C4CY01384K	journal	January 2015
CO and H2 oxidation on a platinum monolith diesel oxidation catalyst Salomons, S.; Votsmeier, M.; Hayes, R. E. Catalysis Today, Vol. 117, Issue 4 https://doi.org/10.1016/j.cattod.2006.06.001	journal	October 2006
Enhancing the low temperature oxidation performance over a Pt and a Pt–Pd diesel oxidation catalyst Herreros, J. M.; Gill, S. S.; Lefort, I. Applied Catalysis B: Environmental, Vol. 147 https://doi.org/10.1016/j.apcatb.2013.10.013	journal	April 2014
Evaluation of H2 effect on NO oxidation over a diesel oxidation catalyst Azis, Muhammad Mufti; Auvray, Xavier; Olsson, Louise Applied Catalysis B: Environmental, Vol. 179 https://doi.org/10.1016/j.apcatb.2015.05.054	journal	December 2015
Investigation of Hydrogen Emissions in Partially Premixed Diesel Combustion Northrop, William F.; Vanderpool, Lucas M.; Madathil, Praveen V. Journal of Engineering for Gas Turbines and Power, Vol. 132, Issue 11 https://doi.org/10.1115/1.4001069	journal	August 2010
Hydrogen in Diesel Exhaust: Effect on Diesel Oxidation Catalyst Flow Reactor Experiments and Model Predictions Katare, Santhoji R.; Laing, Paul M. SAE International Journal of Fuels and Lubricants, Vol. 2, Issue 1 https://doi.org/10.4271/2009-01-1268	journal	April 2009
Robust 3-D configurated metal oxide nano-array based monolithic catalysts with ultrahigh materials usage efficiency and catalytic performance tunability Guo, Yanbing; Ren, Zheng; Xiao, Wen Nano Energy, Vol. 2, Issue 5 https://doi.org/10.1016/j.nanoen.2013.03.004	journal	September 2013
Monolithic catalysts as efficient three-phase reactors Nijhuis, T. A.; Kreutzer, M. T.; Romijn, A. C. J. Chemical Engineering Science, Vol. 56, Issue 3 https://doi.org/10.1016/S0009-2509(00)00294-3	journal	February 2001
Understanding low temperature oxidation activity of nanoarray-based monolithic catalysts: from performance observation to structural and chemical insights Du, Shoucheng; Tang, Wenxiang; Guo, Yanbing Emission Control Science and Technology, Vol. 3, Issue 1 https://doi.org/10.1007/s40825-016-0054-y	journal	December 2016
Monolithically Integrated Spinel M _x Co _{3− x} O ₄ (M=Co, Ni, Zn) Nanoarray Catalysts: Scalable Synthesis and Cation Manipulation for Tunable Low-Temperature CH ₄ and CO Oxidation Ren, Zheng; Botu, Venkatesh; Wang, Sibo Angewandte Chemie International Edition, Vol. 53, Issue 28 https://doi.org/10.1002/anie.201403461	journal	May 2014
Mobility Enhanced Photoactivity in Sol−Gel Grown Epitaxial Anatase TiO₂ Films Jung, Hyun Suk; Lee, Jung-Kun; Lee, Jaegab Langmuir, Vol. 24, Issue 6 https://doi.org/10.1021/la702379y	journal	February 2008
Titanium Dioxide (Anatase and Rutile): Surface Chemistry, Liquid–Solid Interface Chemistry, and Scientific Synthesis of Supported Catalysts Bourikas, Kyriakos; Kordulis, Christos; Lycourghiotis, Alexis Chemical Reviews, Vol. 114, Issue 19 https://doi.org/10.1021/cr300230q	journal	May 2014
Effect of yttria in Pt/TiO₂ on sulfur resistance diesel oxidation catalysts: enhancement of low-temperature activity and stability Yang, Zhengzheng; Zhang, Na; Cao, Yi Catal. Sci. Technol., Vol. 4, Issue 9 https://doi.org/10.1039/C4CY00424H	journal	January 2014
Improvement of catalytic activity and sulfur-resistance of Ag/TiO2–Al2O3 for NO reduction with propene under lean burn conditions Li, J.; Zhu, Y.; Ke, R. Applied Catalysis B: Environmental, Vol. 80, Issue 3-4 https://doi.org/10.1016/j.apcatb.2007.08.016	journal	May 2008
Dispersion, reduction and catalytic performance of CuO supported on ZrO2-doped TiO2 for NO removal by CO Sun, Chuanzhi; Zhu, Jie; Lv, Yuanyuan Applied Catalysis B: Environmental, Vol. 103, Issue 1-2 https://doi.org/10.1016/j.apcatb.2011.01.028	journal	March 2011
Vertically Aligned Single Crystal TiO₂ Nanowire Arrays Grown Directly on Transparent Conducting Oxide Coated Glass: Synthesis Details and Applications Feng, Xinjian; Shankar, Karthik; Varghese, Oomman K. Nano Letters, Vol. 8, Issue 11, p. 3781-3786 https://doi.org/10.1021/nl802096a	journal	November 2008
Visible Light Driven Photoelectrochemical Water Oxidation on Nitrogen-Modified TiO ₂ Nanowires Hoang, Son; Guo, Siwei; Hahn, Nathan T. Nano Letters, Vol. 12, Issue 1 https://doi.org/10.1021/nl2028188	journal	December 2011
Surface defects in drying paint films Kornum, L. O.; Raaschou Nielsen, H. K. Progress in Organic Coatings, Vol. 8, Issue 3 https://doi.org/10.1016/0300-9440(80)80019-1	journal	December 1980
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Sing, K. S. W. Pure and Applied Chemistry, Vol. 57, Issue 4, p. 603-619 https://doi.org/10.1351/pac198557040603	journal	January 1985
Effects of pore assembly architecture on catalyst particle tortuosity and reaction effectiveness Prachayawarakorn, S.; Mann, R. Catalysis Today, Vol. 128, Issue 1-2 https://doi.org/10.1016/j.cattod.2007.06.036	journal	October 2007
Calculation of the Optimal Macropore Size in Nanoporous Catalysts and Its Application to DeNO_x Catalysis Wang, Gang; Coppens, Marc-Olivier Industrial & Engineering Chemistry Research, Vol. 47, Issue 11 https://doi.org/10.1021/ie071550+	journal	May 2008
Mitigating Deactivation Effects through Rational Design of Hierarchically Structured Catalysts: Application to Hydrodemetalation Rao, Sanjeev M.; Coppens, Marc-Olivier Industrial & Engineering Chemistry Research, Vol. 49, Issue 21 https://doi.org/10.1021/ie1009487	journal	November 2010
Mass transport and catalytic activity in hierarchical/non-hierarchical and internal/external nanostructures: A novel comparison using 3D simulation Al-Halhouli, Mohammad; Kieninger, Jochen; Yurchenko, Olena Applied Catalysis A: General, Vol. 517 https://doi.org/10.1016/j.apcata.2016.02.030	journal	May 2016
Surface reactions during atomic layer deposition of Pt derived from gas phase infrared spectroscopy Kessels, W. M. M.; Knoops, H. C. M.; Dielissen, S. A. F. Applied Physics Letters, Vol. 95, Issue 1 https://doi.org/10.1063/1.3176946	journal	July 2009
Relation between Crystallite Size and Dispersion on Supported Metal Catalysts Borodziński, Andrzej; Bonarowska, Magdalena Langmuir, Vol. 13, Issue 21 https://doi.org/10.1021/la962103u	journal	October 1997
In situ d electron density of Pt particles on supports by XANES Ichikuni, Nobuyuki; Iwasawa, Yasuhiro Catalysis Letters, Vol. 20, Issue 1-2 https://doi.org/10.1007/BF00772600	journal	January 1993
Oxidation of NO with O ₂ on Pt(111) and Pt(321) Large Single Crystals ^† Smeltz, Andrew D.; Delgass, W. Nicholas; Ribeiro, Fabio H. Langmuir, Vol. 26, Issue 21 https://doi.org/10.1021/la101653x	journal	November 2010
Kinetics of carbon monoxide oxidation on single-crystal palladium, platinum, and iridium Berlowitz, Paul J.; Peden, Charles H. F.; Goodman, D. Wayne The Journal of Physical Chemistry, Vol. 92, Issue 18 https://doi.org/10.1021/j100329a030	journal	September 1988
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping Jones, J.; Xiong, H.; DeLaRiva, A. T. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf8800	journal	July 2016
Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms16100	journal	July 2017
The promotion of carbon monoxide oxidation by hydrogen on supported platinum catalyst Salomons, S.; Hayes, R. E.; Votsmeier, M. Applied Catalysis A: General, Vol. 352, Issue 1-2 https://doi.org/10.1016/j.apcata.2008.09.025	journal	January 2009
Kinetic Modeling Study of the Oxidation of Carbon Monoxide–Hydrogen Mixtures over Pt/Al₂O₃ and Rh/Al₂O₃ Catalysts Rankovic, Nikola; Nicolle, Andre; Berthout, David The Journal of Physical Chemistry C, Vol. 115, Issue 41 https://doi.org/10.1021/jp205476y	journal	September 2011
Experimental and kinetic study of NO oxidation on model Pt catalysts Bhatia, Divesh; McCabe, Robert W.; Harold, Michael P. Journal of Catalysis, Vol. 266, Issue 1 https://doi.org/10.1016/j.jcat.2009.05.020	journal	August 2009
Modeling the simultaneous oxidation of CO and H2 on Pt – Promoting effect of H2 on the CO-light-off Hauptmann, W.; Votsmeier, M.; Vogel, H. Applied Catalysis A: General, Vol. 397, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.02.031	journal	April 2011
Catalytically Active Rh Sub-Nanoclusters on TiO ₂ for CO Oxidation at Cryogenic Temperatures Guan, Hongling; Lin, Jian; Qiao, Botao Angewandte Chemie International Edition, Vol. 55, Issue 8 https://doi.org/10.1002/anie.201510643	journal	January 2016
Inverse hysteresis during the NO oxidation on Pt under lean conditions Hauptmann, W.; Votsmeier, M.; Gieshoff, J. Applied Catalysis B: Environmental, Vol. 93, Issue 1-2 https://doi.org/10.1016/j.apcatb.2009.09.008	journal	November 2009
Platinum oxide formation and reduction during NO oxidation on a diesel oxidation catalyst – Experimental results Hauff, K.; Tuttlies, U.; Eigenberger, G. Applied Catalysis B: Environmental, Vol. 123-124 https://doi.org/10.1016/j.apcatb.2012.04.008	journal	July 2012

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