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ElectroCat: DOE's approach to PGM-free catalyst and electrode R&D

Journal Article · · Solid State Ionics
 [1];  [1];  [2];  [3];  [4];  [5];  [1]
  1. Dept. of Energy (DOE), Washington DC (United States). Fuel Cell Technologies Office (FCTO)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
  5. National Renewable Energy Lab. (NREL), Golden, CO (United States). Chemistry and Nanoscience Center
+ Show Author Affiliations

The successful development of high-performance, durable platinum group metal-free (PGM-free) electrocatalysts and electrodes for polymer electrolyte membrane fuel cells (PEMFCs) will ultimately improve the cost-competiveness of fuel cells in a wide range of applications. This is considered to be a critical development especially for automotive fuel cell applications in order to bring the system cost of an automotive fuel cell system down to the $30/kW cost target set by the U.S. Department of Energy (DOE). The platinum group metal (PGM) electrocatalysts are a major contributor to the system cost. Addressing the technical challenges to PGM-free electrocatalyst and electrode development, therefore, represents one of DOE's most pressing research and development (R&D) priorities. ElectroCat was formed by the DOE as part of the Energy Materials Network (EMN) in early 2016, and shares with other EMN consortia the goal of decreasing the time to market for advanced materials related to clean energy technologies, in the context of increasing U.S. fuel cell electric vehicle (FCEV) manufacturing competitiveness. To accomplish this, the consortium performs core research and development and provides universities and companies streamlined access to the unique, world-class set of tools and expertise relevant to early-stage applied PGM-free catalyst R&D of the member national laboratories. Moreover, ElectroCat fosters a systematic methodology by which prospective catalysts and electrodes are prepared and analyzed rapidly and comprehensively using high-throughput, combinatorial methods. Catalyst discovery is augmented by theory as well as foundational electrocatalysis and materials knowledge at the participating national laboratories. Furthermore, ElectroCat has developed a data sharing framework, requisite of all EMN consortia, for disseminating its findings to the public via a searchable database, to further expedite incorporation of PGM-free electrocatalysts into next-generation fuel cells by advancing the general understanding of the PGM-free electrocatalyst field.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Fuel Cell Technologies Program (EE-3F); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division
Grant/Contract Number:
AC36-08GO28308; AC05-00OR22725; AC02-06CH11357
OSTI ID:
1424904
Report Number(s):
NREL/JA--5900-71058
Journal Information:
Solid State Ionics, Journal Name: Solid State Ionics Journal Issue: C Vol. 319; ISSN 0167-2738
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (28)

Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes journal October 2010
Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts journal January 2011
First-Principles Molecular Dynamics Study of Carbon Corrosion in PEFC Catalyst Materials journal August 2016
Recent development of efficient electrocatalysts derived from porous organic polymers for oxygen reduction reaction journal July 2017
Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells journal June 2017
Electrocatalysts for O2 reduction journal November 1984
Hybrid approach combining multiple characterization techniques and simulations for microstructural analysis of proton exchange membrane fuel cell electrodes journal March 2017
Linking structure to function: The search for active sites in non-platinum group metal oxygen reduction reaction catalysts journal November 2016
The recent progress and future of oxygen reduction reaction catalysis: A review journal March 2017
A Combined Probe-Molecule, Mössbauer, Nuclear Resonance Vibrational Spectroscopy, and Density Functional Theory Approach for Evaluation of Potential Iron Active Sites in an Oxygen Reduction Reaction Catalyst journal July 2017
The Priority and Challenge of High-Power Performance of Low-Platinum Proton-Exchange Membrane Fuel Cells journal March 2016
Resolving Electrode Morphology’s Impact on Platinum Group Metal-Free Cathode Performance Using Nano-CT of 3D Hierarchical Pore and Ionomer Distribution journal November 2016
Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction journal April 2013
Metal-Organic Framework as a Template for Porous Carbon Synthesis journal April 2008
Nitrogen-Doped Graphene-Rich Catalysts Derived from Heteroatom Polymers for Oxygen Reduction in Nonaqueous Lithium–O 2 Battery Cathodes journal October 2012
A New Fuel Cell Cathode Catalyst journal March 1964
A class of non-precious metal composite catalysts for fuel cells journal September 2006
Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells journal August 2011
Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells journal January 2015
Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks journal January 2017
Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells journal January 2011
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
A hard X-ray nanoprobe beamline for nanoscale microscopy journal September 2012
Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability journal January 2007
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells journal April 2009
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt journal April 2011
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst journal August 2017
Activation of Various Fe‐Based Precursors on Carbon Black and Graphite Supports to Obtain Catalysts for the Reduction of Oxygen in Fuel Cells journal January 1997

Cited By (13)

Iron‐Free Cathode Catalysts for Proton‐Exchange‐Membrane Fuel Cells: Cobalt Catalysts and the Peroxide Mitigation Approach journal December 2018
PGM‐Free Cathode Catalysts for PEM Fuel Cells: A Mini‐Review on Stability Challenges journal December 2018
Insights Into the Effect of Nickel Doping on ZIF‐Derived Oxygen Reduction Catalysts for Zinc−Air Batteries journal February 2019
A Review on Recent Progress in the Aspect of Stability of Oxygen Reduction Electrocatalysts for Proton‐Exchange Membrane Fuel Cell: Quantum Mechanics and Experimental Approaches journal June 2019
Platinum group metal-free catalysts boost cost competitiveness of fuel cell vehicles journal July 2019
Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation journal July 2019
Highly active atomically dispersed CoN 4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy journal January 2019
Metal–organic frameworks: a promising platform for constructing non-noble electrocatalysts for the oxygen-reduction reaction journal January 2019
Magnetic purification of non-precious metal fuel cell catalysts for obtaining atomically dispersed Fe centers journal January 2020
Performance of Polymer Electrolyte Fuel Cell Electrodes with Atomically Dispersed (AD) Fe-C-N ORR Catalyst journal January 2019
Impedance Spectroscopy Characterization of PEM Fuel Cells with Fe-N-C-Based Cathodes journal January 2019
Methanol-Tolerant M–N–C Catalysts for Oxygen Reduction Reactions in Acidic Media and Their Application in Direct Methanol Fuel Cells journal December 2018
Transition Metal–Nitrogen–Carbon (M–N–C) Catalysts for Oxygen Reduction Reaction. Insights on Synthesis and Performance in Polymer Electrolyte Fuel Cells journal February 2019

Figures / Tables (7)

Table 1(p. 4)table Table 1
Figure 1(p. 6)figure Figure 1
Figure 2(p. 9)figure Figure 2
Figure 3(p. 10)figure Figure 3
Figure 4(p. 12)figure Figure 4
Figure 5(p. 14)figure Figure 5
Figure 6(p. 16)figure Figure 6

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Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
MEA
PEMFC
PGM-free electrocatalysts
electrodes
oxygen reduction reaction