Properties of Polyvinylpyrrolidone in a Deep Eutectic Solvent

Sapir, Liel; Stanley, Christopher B.; Harries, Daniel

doi:10.1021/acs.jpca.5b11927

Properties of Polyvinylpyrrolidone in a Deep Eutectic Solvent

Journal Article · Thu Mar 10 00:00:00 EST 2016 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory

DOI:https://doi.org/10.1021/acs.jpca.5b11927· OSTI ID:1424493

Sapir, Liel ^[1]; Stanley, Christopher B. ^[2]; Harries, Daniel ^[1]

Hebrew Univ. of Jerusalem (Israel). Inst. of Chemistry. The Fritz Haber Research Center
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Biology and Soft Matter Division

Deep eutectic solvents (DES) are mixtures of two or more components with high melting temperatures, which form a liquid at room temperature. These DES hold great promise as green solvents for chemical processes, as they are inexpensive and environmentally friendly. Specifically, they present a unique solvating environment to polymers that is different from water. In this paper, we use small angle neutron scattering to study the polymer properties of the common, water-soluble, polyvinylpyrrolidone (PVP) in the prominent DES formed by a 1:2 molar mixture of choline chloride and urea. We find that the polymer adopts a slightly different structure in DES than in water, so that at higher concentrations the polymer favors a more expanded conformation compared to the same concentration in water. Yet, the osmotic pressure of PVP solutions in DES is very similar to that in water, indicating that both solvents are of comparable quality and that the DES components interact favorably with PVP. Finally, the osmotic pressure measurements within this novel class of promising solvents should be of value toward future technological applications as well as for osmotic stress experiments in nonaqueous environments.

View Accepted Manuscript (DOE)

Research Organization:: Hebrew Univ. of Jerusalem (Israel); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Israel Academy of Sciences and Humanities; Leverhulme Trust (United Kingdom); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); United States-Israel Binational Science Foundation (BSF)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1424493

Journal Information:: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Issue: 19 Vol. 120; ISSN 1089-5639

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Use of Deep Eutectic Solvents in Polymer Chemistry–A Review Jablonský, Michal; Škulcová, Andrea; Šima, Jozef Molecules, Vol. 24, Issue 21 https://doi.org/10.3390/molecules24213978	journal	November 2019
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