Characterization of chromia scales formed in supercritical carbon dioxide

Pint, Bruce; Unocic, Kinga; Brese, Robert G.; Keiser, Jim

doi:10.1080/09603409.2017.1389371

Characterization of chromia scales formed in supercritical carbon dioxide

Conference · Sun Oct 01 04:00:00 EDT 2017

DOI:https://doi.org/10.1080/09603409.2017.1389371· OSTI ID:1424457

^[1]; ^[1]; Brese, Robert G. ^[1]; ^[1]

ORNL

Initial experimental work at 700°–800 °C is in progress to develop a lifetime model for supercritical CO2 (sCO2) compatibility for a 30-year lifetime of a >700 °C concentrated solar power system. Nickel-based alloys 282, 740H and 625 and Fe-based alloy 25 are being evaluated in 500-h cycles at 1 and 300 bar, and 10-h cycles in 1 bar industrial grade CO2. The alloys showed similar low rates of oxidation in 1 and 300 bar CO2 in 500-h cycles at 750 °C. However, in 10-h cycles, alloy 25 showed accelerated attack at 700° and 750 °C. Transmission electron microscopy scale cross-sections on alloy 25 after 1000 h at 700 °C in sCO2 and in air only showed a small row of carbides beneath the scale in the former environment. Similar characterisation was performed on alloys 625 and 282 after sCO2 exposure at 750 °C.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1424457

Country of Publication:: United States

Language:: English

References (33)

No authors listed Materials and Corrosion, Vol. 68, Issue 2, 117-265 https://doi.org/10.1002/maco.v68.2	journal	February 2017
The supercritical thermodynamic power cycle Feher, E. G. Energy Conversion, Vol. 8, Issue 2 https://doi.org/10.1016/0013-7480(68)90105-8	journal	September 1968
Sub-Scale Depletion and Enrichment Processes During High Temperature Oxidation of the Nickel Base Alloy 625 in the Temperature Range 900–1000 °C Chyrkin, A.; Huczkowski, P.; Shemet, V. Oxidation of Metals, Vol. 75, Issue 3-4 https://doi.org/10.1007/s11085-010-9225-3	journal	December 2010
Type 304 Stainless Steel vs Flowing CO ₂ At Atmospheric Pressure and 1100-1800F McCOY, H. E. CORROSION, Vol. 21, Issue 3 https://doi.org/10.5006/0010-9312-21.3.84	journal	March 1965
Testing and Analysis of Full-Scale Creep-Rupture Experiments on Inconel Alloy 740 Cold-Formed Tubing Shingledecker, J. P.; Pharr, G. M. Journal of Materials Engineering and Performance, Vol. 22, Issue 2 https://doi.org/10.1007/s11665-012-0274-4	journal	July 2012
No authors listed Materials Science Forum, Vol. 696 https://doi.org/10.4028/www.scientific.net/MSF.696	journal	September 2011
A review of thermodynamic cycles and working fluids for the conversion of low-grade heat Chen, Huijuan; Goswami, D. Yogi; Stefanakos, Elias K. Renewable and Sustainable Energy Reviews, Vol. 14, Issue 9, p. 3059-3067 https://doi.org/10.1016/j.rser.2010.07.006	journal	December 2010
Oxidation and carburizing of FBR structural materials in carbon dioxide Furukawa, Tomohiro; Rouillard, Fabien Progress in Nuclear Energy, Vol. 82 https://doi.org/10.1016/j.pnucene.2014.07.038	journal	July 2015
Corrosion and carburization behavior of chromia-forming heat resistant alloys in a high-temperature supercritical-carbon dioxide environment Lee, Ho Jung; Kim, Hyunmyung; Kim, Sung Hwan Corrosion Science, Vol. 99 https://doi.org/10.1016/j.corsci.2015.07.007	journal	October 2015
Corrosion of iron-, nickel-, and cobalt-base alloys in atmospheres containing carbon and oxygen Meier, G. H.; Coons, W. C.; Perkins, R. A. Oxidation of Metals, Vol. 17, Issue 3-4 https://doi.org/10.1007/BF00738385	journal	April 1982
Carburization of Fe-Cr Alloys During Oxidation in Dry Carbon Dioxide Fujii, C. T.; Meussner, R. A. Journal of The Electrochemical Society, Vol. 114, Issue 5 https://doi.org/10.1149/1.2426622	journal	January 1967
On the breakaway oxidation of Fe9Cr1Mo steel in high pressure CO2 Gong, Y.; Young, D. J.; Kontis, P. Acta Materialia, Vol. 130 https://doi.org/10.1016/j.actamat.2017.02.034	journal	May 2017
Chromium-depleted zones and the oxidation process in stainless steels Evans, H. E.; Hilton, D. A.; Holm, R. A. Oxidation of Metals, Vol. 10, Issue 3 https://doi.org/10.1007/BF00612157	journal	June 1976
Evaluation of NiCrAl Foil for a Concentrated Solar Power Application Pint, Bruce A.; Anderson, Bruce N.; Matthews, Wendy J. Volume 4: Ceramics; Concentrating Solar Power Plants; Controls, Diagnostics and Instrumentation; Education; Electric Power; Fans and Blowers https://doi.org/10.1115/GT2013-94939	conference	June 2013
Corrosion Behavior of Different Metallic Materials in Supercritical Carbon Dioxide at 550°C and 250 bars Rouillard, F.; Charton, F.; Moine, G. CORROSION, Vol. 67, Issue 9 https://doi.org/10.5006/1.3628683	journal	September 2011
The oxidation behaviour of the 9 % Cr steel P92in CO ₂ - and H ₂ O-rich gases relevant to oxyfuel environments Abellán, Javier Pirón; Olszewski, Tomasz; Meier, Gerald H. International Journal of Materials Research, Vol. 101, Issue 2 https://doi.org/10.3139/146.110271	journal	February 2010
Carburisation of ferritic Fe–Cr alloys by low carbon activity gases Gheno, Thomas; Monceau, Daniel; Zhang, Jianqiang Corrosion Science, Vol. 53, Issue 9 https://doi.org/10.1016/j.corsci.2011.05.013	journal	September 2011
Benchmarking supercritical carbon dioxide cycles against steam Rankine cycles for Concentrated Solar Power Cheang, V. T.; Hedderwick, R. A.; McGregor, C. Solar Energy, Vol. 113 https://doi.org/10.1016/j.solener.2014.12.016	journal	March 2015
Calculations of parabolic reaction rate constants Pieraggi, B. Oxidation of Metals, Vol. 27, Issue 3-4 https://doi.org/10.1007/BF00667057	journal	April 1987
Influence of chromium content on carburization of chromium-nickel-iron alloys in carbon dioxide Martin, W. R.; Weir, J. R. Journal of Nuclear Materials, Vol. 16, Issue 1 https://doi.org/10.1016/0022-3115(65)90087-5	journal	May 1965
Analysis of a novel solar energy-powered Rankine cycle for combined power and heat generation using supercritical carbon dioxide Zhang, X. R.; Yamaguchi, H.; Uneno, D. Renewable Energy, Vol. 31, Issue 12 https://doi.org/10.1016/j.renene.2005.09.024	journal	October 2006
Effect of Thermal Cycling on Compatibility in CO2 for Concentrated Solar Power Applications Brese, Robert G.; Keiser, James R.; Pint, Bruce A. Oxidation of Metals, Vol. 87, Issue 5-6 https://doi.org/10.1007/s11085-017-9762-0	journal	March 2017
Effect of Pressure and Thermal Cycling on Compatibility in CO2 for Concentrated Solar Power Applications Pint, Bruce A.; Brese, Robert G.; Keiser, James R. Volume 9: Oil and Gas Applications; Supercritical CO2 Power Cycles; Wind Energy https://doi.org/10.1115/GT2017-65066	conference	June 2017
Alloys SS316 and Hastelloy-C276 in Supercritical CO2 at High Temperature Olivares, R. I.; Young, D. J.; Marvig, P. Oxidation of Metals, Vol. 84, Issue 5-6 https://doi.org/10.1007/s11085-015-9589-5	journal	September 2015
Factors in the oxidation assessment of AISI type 310 steels in high pressure carbon dioxide Garrett, J. C. P.; Crook, J. T.; Lister, S. K. Corrosion Science, Vol. 22, Issue 1 https://doi.org/10.1016/0010-938X(82)90129-9	journal	January 1982
High-Performance Supercritical Carbon Dioxide Cycle for Next-Generation Nuclear Reactors Dostal, Vaclav; Hejzlar, Pavel; Driscoll, Michael J. Nuclear Technology, Vol. 154, Issue 3 https://doi.org/10.13182/NT154-265	journal	June 2006
Initial Assessment of Ni-Base Alloy Performance in 0.1 MPa and Supercritical CO2 Pint, B. A.; Keiser, J. R. JOM, Vol. 67, Issue 11 https://doi.org/10.1007/s11837-015-1661-8	journal	September 2015
FY-05 Second Quarter Report On Development of a Supercritical Carbon Dioxide Brayton Cycle: Improving PBR Efficiency and Testing Material Compatibility Oh, Chang https://doi.org/10.2172/911223	report	April 2005
High Efficiency and Low Cost of Electricity Generation from Fossil Fuels While Eliminating Atmospheric Emissions, Including Carbon Dioxide Allam, R. J.; Palmer, Miles R.; Brown, G. William Energy Procedia, Vol. 37 https://doi.org/10.1016/j.egypro.2013.05.211	journal	January 2013
Penetration of protective chromia scales by carbon Young, David J.; Nguyen, Thuan Dinh; Felfer, Peter Scripta Materialia, Vol. 77 https://doi.org/10.1016/j.scriptamat.2014.01.009	journal	April 2014
Supercritical CO2 Brayton cycles for solar-thermal energy Iverson, Brian D.; Conboy, Thomas M.; Pasch, James J. Applied Energy, Vol. 111 https://doi.org/10.1016/j.apenergy.2013.06.020	journal	November 2013
Microstructures of chromia scales grown in CO ₂ Nguyen, T. D.; Zhang, J. Q.; Young, D. J. Materials at High Temperatures, Vol. 32, Issue 1-2 https://doi.org/10.1179/0960340914Z.00000000056	journal	January 2015
Oxidation behaviour of cast Ni–Cr alloys in steam at 800°C Essuman, E.; Walker, L. R.; Maziasz, P. J. Materials Science and Technology, Vol. 29, Issue 7 https://doi.org/10.1179/1743284712Y.0000000103	journal	July 2013

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