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Methods and systems for utilizing carbide lime or slag

Patent ·
OSTI ID:1423456

Provided herein are methods comprising a) treating a slag solid or carbide lime suspension with an ammonium salt in water to produce an aqueous solution comprising calcium salt, ammonium salt, and solids; b) contacting the aqueous solution with carbon dioxide from an industrial process under one or more precipitation conditions to produce a precipitation material comprising calcium carbonate and a supernatant aqueous solution wherein the precipitation material and the supernatant aqueous solution comprise residual ammonium salt; and c) removing and optionally recovering ammonia and/or ammonium salt using one or more steps of (i) recovering a gas exhaust stream comprising ammonia during the treating and/or the contacting step; (ii) recovering the residual ammonium salt from the supernatant aqueous solution; and (iii) removing and optionally recovering the residual ammonium salt from the precipitation material.

Research Organization:
National Energy Technology Laboratory, Pittsburgh, PA, and Morgantown, WV (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0002472
Assignee:
CALERA CORPORATION (Moss Landing, CA)
Patent Number(s):
9,902,652
OSTI ID:
1423456
Country of Publication:
United States
Language:
English

References (16)

Chapter Ten - Production of Precipitated Calcium Carbonate from Steel Converter Slag and Other Calcium-Containing Industrial Wastes and Residues book January 2014
Synthesis of All Crystalline Phases of Anhydrous Calcium Carbonate journal May 2010
Strontium and aragonite-calcite precipitation journal January 2007
Hydration of high-calcium quicklime with methanol–water mixtures journal March 2003
Preparation of Calcium Carbonate Superfine Powder by Calcium Carbide Residue journal January 2012
A study of carbon dioxide absorption into aqueous monoethanolamine solution containing calcium nitrate in the gas–liquid reactive precipitation of calcium carbonate journal June 2002
Effect of flow rate and CO2 content on the phase and morphology of CaCO3 prepared by bubbling method journal April 2005
Formation of Vaterite by the Reaction of Calcium Methoxide with Aqueous Sodium Carbonate Solution journal April 1979
Reduced Limestone Consumption in Steel Manufacturing Using a Pseudo-catalytic Calcium Lixiviant journal June 2014
Indirect CO2 mineral sequestration by steelmaking slag with NH4Cl as leaching solution journal September 2011
Carbide lime and industrial hydrated lime characterization journal October 2009
Chemical kinetics modeling and process parameter sensitivity for precipitated calcium carbonate production from steelmaking slags journal June 2012
Post-combustion CO2 capture by aqueous ammonia: A state-of-the-art review journal July 2012
Influence of initial CaCl2 concentration on the phase and morphology of CaCO3 prepared by carbonation journal May 2006
Calcium carbonate phase transformations during the carbonation reaction of calcium heavy alkylbenzene sulfonate overbased nanodetergents preparation journal July 2011
Preliminary assessment of a method utilizing carbon dioxide and steelmaking slags to produce precipitated calcium carbonate journal February 2012

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