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Optimized Lanthanum Ferrite-Based Cathodes for Anode-Supported SOFCs

Journal Article · · Electrochemical and Solid State Letters
DOI:https://doi.org/10.1149/1.1483156· OSTI ID:1423426
Three cathode compositions (La0.8Sr0.2FeO3-δ, La0.7Sr0.3Fe0.8Ni0.2O3-δ and LaNi0.6Fe0.4O3-δ) have been tested as SOFC cathodes at operating temperatures from 650 degrees C to 750 degrees C. Sintering temperatures were established for each cathode composition to provide optimized cell performance. La0.8Sr0.2FeO3-δ exhibited the highest power density (> 900 mW/cm2 at 750 degrees C and 0.7 V), and indicated excellent performance stability over a 300 hour period.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1423426
Report Number(s):
PNNL-SA-52069; AA6040000
Journal Information:
Electrochemical and Solid State Letters, Journal Name: Electrochemical and Solid State Letters Journal Issue: 7 Vol. 5; ISSN 1099-0062; ISSN ESLEF6
Publisher:
Electrochemical Society
Country of Publication:
United States
Language:
English

References (8)

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Oxygen permeability of LaFe1−xNixO3−δ solid solutions journal October 1999
Mixed ionic-electronic conductivity of La1−xSrxCo1−yFeyO3−δ perovskite-type oxides journal January 1988
Increased solid-oxide fuel cell power density using interfacial ceria layers journal June 1997
Sr- and Ni-Doped LaCoO[sub 3] and LaFeO[sub 3] Perovskites journal January 1998
Reactions between a zirconia-based electrolyte and LaCoO3-based electrode materials journal November 1997
Correlation between thermal expansion and oxide ion transport in mixed conducting perovskite-type oxides for SOFC cathodes journal December 2000
An investigation of LaNi1−xFexO3 as a cathode material for solid oxide fuel cells journal September 1999

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