Photoelectron angular distributions from rotationally resolved autoionizing states of N2

Chartrand, A. M.; McCormack, E. F.; Jacovella, U.; Holland, D. M. P.; Gans, Berenger; Tang, Xiaofeng; Garcia, G. A.; Nahon, L.; Pratt, S. T.

doi:10.1063/1.5004538

Title: Photoelectron angular distributions from rotationally resolved autoionizing states of N₂

Journal Article · Fri Dec 08 00:00:00 EST 2017 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5004538· OSTI ID:1422406

Chartrand, A. M. ^[1];

^[2]; Jacovella, U. ^[3]; Holland, D. M. P. ^[4];

^[5]; Tang, Xiaofeng ^[6];

^[7]; Nahon, L. ^[7]; Pratt, S. T. ^[8]

Bryn Mawr College, Bryn Mawr, PA (United States)
Bryn Mawr College, Bryn Mawr, PA (United States); Bowdoin College , Brunswick, ME (United States)
ETH Zurich, Zurich (Switzerland)
Daresbury Lab., Cheshire (United Kingdom)
Univ. Paris-Sud, Univ. Paris-Saclay, Orsay (France)
Synchrotron Soleil, Gif-sur-Yvette (France); Chinese Academy of Sciences, Anhui (China)
Synchrotron Soleil, Gif-sur-Yvette (France)
Argonne National Lab. (ANL), Argonne, IL (United States)

The single-photon, photoelectron-photoion coincidence spectrum of N₂ has been recorded at high (~1.5 cm^-1) resolution in the region between the N₂⁺ X ²Σ_g⁺, v⁺ = 0 and 1 ionization thresholds by using a double imaging spectrometer and intense vacuum-ultraviolet light from the Synchrotron SOLEIL. This approach provides the relative photoionization cross section, the photoelectron energy distribution, and the photoelectron angular distribution as a function of photon energy. The region of interest contains autoionizing valence states, vibrationally autoionizing Rydberg states converging to vibrationally excited levels of the N₂⁺ X ²Σ_g⁺ ground state, and electronically autoionizing states converging to the N₂⁺ A ²Π and B ²Σ_u⁺ states. The wavelength resolution is sufficient to resolve rotational structure in the autoionizing states, but the electron energy resolution is insufficient to resolve rotational structure in the photoion spectrum. Here, a simplified approach based on multichannel quantum defect theory is used to predict the photoelectron angular distribution parameters, β, and the results are in reasonably good agreement with experiment.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1422406

Alternate ID(s):: OSTI ID: 1411991

Journal Information:: Journal of Chemical Physics, Vol. 147, Issue 22; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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Double-resonance studies of electronically autoionizing states of molecular nitrogen Sen, Ananya; Pratt, S. T. Molecular Physics, Vol. 117, Issue 21 https://doi.org/10.1080/00268976.2018.1544672	journal	January 2019
Double-resonance studies of electronically autoionizing states of molecular nitrogen Sen, Ananya; Pratt, S. T. Taylor & Francis https://doi.org/10.6084/m9.figshare.7618742	text	January 2019
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Title: Photoelectron angular distributions from rotationally resolved autoionizing states of N₂