Carboxylated Fullerene at the Oil/Water Interface

Li, Rongqiang; Chai, Yu; Jiang, Yufeng; Ashby, Paul D.; Toor, Anju; Russell, Thomas P.

doi:10.1021/acsami.7b07154

Carboxylated Fullerene at the Oil/Water Interface

Journal Article · Fri Apr 07 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b07154· OSTI ID:1421796

^[1]; Chai, Yu ^[2]; Jiang, Yufeng ^[3]; Ashby, Paul D. ^[4]; ^[5]; ^[6]

Huanghuai Univ., Zhumadian, Henan (China). College of Chemistry and Pharmaceutical Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Univ. of California, Berkeley, CA (United States). Dept. of Applied Science and Technology
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Science Division; Univ. of Massachusetts, Amherst, MA (United States). Polymer Science and Engineering Dept.; Beijing Univ. of Chemical Technology, Beijing (China). Beijing Advanced Innovation Center for Soft Matter Science and Engineering

The self-assembly of carboxylated fullerene with poly(styrene-b-2-vinylpyridine) (PS-b-P2VP) with different molecular weights, poly-2-vinylpyridine, and amine-terminated polystyrene, at the interface between toluene and water was investigated. For all values of the pH, the functionalized fullerene interacted with the polymers at the water/toluene interface, forming a nanoparticle network, reducing the interfacial tension. At pH values of 4.84 and 7.8, robust, elastic films were formed at the interface, such that hollow tubules could be formed in situ when an aqueous solution of the functionalized fullerene was jetted into a toluene solution of PS-b-P2VP at a pH of 4.84. Lastly, with variation of the pH, the mechanical properties of the fullerene/polymer assemblies can be varied by tuning the strength of the interactions between the functionalized fullerenes and the PS-b-P2VP.

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: AC02-05CH11231

OSTI ID:: 1421796

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 39 Vol. 9; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
assembly
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interface
nanoparticle surfactant

Carboxylated Fullerene at the Oil/Water Interface

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